Henri-Michaelis-Menten kinetics of reversible enzymic reactions, and the determination of rate constants from kinetic constants [PDF]
The Michaelis constants derived for two reversible uni-reactant - uni-product reaction models, given originally by Haldane, are corrected. In the direction starting with the reactant having the lower binding constant, the steady state is one in which the
Eric A. Barnsley
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Model Balancing: A Search for In-Vivo Kinetic Constants and Consistent Metabolic States [PDF]
Enzyme kinetic constants in vivo are largely unknown, which limits the construction of large metabolic models. Given measured metabolic fluxes, metabolite concentrations, and enzyme concentrations, these constants may be inferred by model fitting, but ...
Wolfram Liebermeister, Elad Noor
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Inverse numerical modeling for predicting kinetic rate constants in polyolefin pyrolysis based on product yield distribution for efficient plastic recycling [PDF]
The prediction of kinetic rate constants is a significant challenge in effective plastic pyrolysis recycling due to the wide range of generated byproducts, including char and aromatics. To address this challenge, an inverse numerical modeling methodology
Rao Adeel Un Nabi +4 more
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Comparison of Sulfur Dioxide Removal Reactions Kinetics by Na2CO3 and Other Different Sorbents from Coal-fired Power Plants [PDF]
This work deals with kinetic parameters estimation of Na2CO3+SO2 reaction employing sophisticated random pore model. The temperature of experiments ranges from 100 to 250 °C, and various SO2 concentrations are within 0.13–1.12 vol.%.
I. Omidi Bibalani, H. Ale Ebrahim
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Out-of-Equilibrium Measurements of Kinetic Constants on a Biosensor [PDF]
Conventional measurements of kinetic constants currently in use are performed at equilibrium and may require large volumes, especially at a low association rate constant kon. If the measurements are made out of equilibrium, the values obtained may be biased by dilution of the sample with the flow of the running buffer.
Mottin, Donatien +3 more
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The Gamma model is a novel approach to characterise the complex degradation dynamics taking place during anaerobic digestion. This three parameters model results from combining the first-order kinetic model and the Gamma distribution function. In contrast to conventional models, where the kinetic constant is considered invariant, the Gamma model allows
C. Da Silva +6 more
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Background PET imaging of 18F-fluorodeoxygucose (FDG) is used widely for tumour staging and assessment of treatment response, but the biology associated with FDG uptake is still not fully elucidated. We therefore carried out gene set enrichment analyses (
G. P. Ralli +11 more
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The antioxidant capability of scutellarein, a flavonoid extracted from different plants of the Scutellaria family, was computationally predicted by considering its reaction with the OOH radical in both lipid-like and water environments.
Maciej Spiegel +3 more
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Development of method for determination of the kinetics constants of coal char gasification in pore diffusion regimes [PDF]
In this paper, we developed a method for determining the kinetic constants of partially diffusion-controlled heterogeneous reactions in a porous sample of powder.
Remkunas Irina +2 more
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New Invariant Expressions in Chemical Kinetics
This paper presents a review of our original results obtained during the last decade. These results have been found theoretically for classical mass-action-law models of chemical kinetics and justified experimentally.
Gregory S. Yablonsky +3 more
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