Measurements, errors, and negative kinetic energy [PDF]
An analysis of errors in measurement yields new insight into the penetration of quantum particles into classically forbidden regions. In addition to ``physical" values, realistic measurements yield ``unphysical" values which, we show, can form a ...
Daniel Rohrlich +10 more
core +4 more sources
Fundamental Material Properties of the 2LiBH4-MgH2 Reactive Hydride Composite for Hydrogen Storage: (II) Kinetic Properties [PDF]
Reaction kinetic behaviour and cycling stability of the 2LiBH4–MgH2 reactive hydride composite (Li-RHC) are experimentally determined and analysed as a basis for the design and development of hydrogen storage tanks. In addition to the determination
Julian Jepsen +11 more
doaj +9 more sources
Bulk-Effect-Free Method for Binding Kinetic Measurements Enabling Small-Molecule Affinity Characterization [PDF]
Allison M. Marn +2 more
doaj +2 more sources
Reactivity of cyclohex-1-enylcarboxylic and 2-methylcyclohex-1-enylcarboxylic acids with diazodiphenylmethane in aprotic solvents [PDF]
Rate constants for the reaction of diazodiphenylmethane with cyclohex-1-enylcarboxylic acid and 2-methylcyclohex-1-enylcarboxylic acid were determined in nine aprotic solvents, as well as in seven protic solvents, at 30°C using the appropriate UV ...
VERA V. KRSTIC +2 more
doaj +3 more sources
The kinetics of the reactions of 2-substituted nicotinic acids with diazodiphenylmethane in various alcohols [PDF]
The rate constants of 2-substituted nicotinic acids in reaction with diazodiphenylmethane (DDM) in eight alcohols at 30ºC have been determined. In order to explain the obtained results through solvent effects, the second order reaction rate constants (k)
MILICA M. MISIC-VUKOVIC +3 more
doaj +3 more sources
Critical Comparison of the Superoxide Dismutase-like Activity of Carbon Antioxidant Nanozymes by Direct Superoxide Consumption Kinetic Measurements. [PDF]
Wu G +8 more
europepmc +2 more sources
The influence of the solvent on organic reactivity. Part II. Hydroxylic solvent effects on the reaction rates of diazodiphenylmethane with 2-(2-substituted cyclohex-1-enyl)acetic and 2-(2-substituted [PDF]
The rate constants for the reaction of diazodiphenylmethane with 2-(2-substituted cyclohex-1-enyl)acetic acids and 2-(2-substituted phenyl)acetic acids, previously determined in seven hydroxylic solvents, were correlated using the total solvatochromic ...
Nikolić Jasmina B. +2 more
doaj +1 more source
The reactivity of α,β-unsaturated carboxylic acids. Part XVI. The kinetics of the reaction of cycloalkenecarboxylic and cycloalkenylacetic acids with diazodiphenylmethane in various alcohols [PDF]
The rate constants for the reaction of diazodiphenylmethane with 1-cyclopentenecarboxylic, 1-cycloheptenecarboxylic, cyclopent-1-enylacetic and cyclohept-1-enylacetic acids were determined in eight alcohols at 30 ºC using the appropriate UV-spectroscopic
Ušćumlić Gordana S. +2 more
doaj +1 more source
Ultrasonic on-line spectrophotometric system for reaction kinetic measurements; pp. 52–57 [PDF]
A unique ultrasonic online spectrophotometric system for kinetic measurements of homogeneous polar reactions under ultrasound was developed. The setup consists of an ultrasonic bath, an HPLC UV/Vis detector, an HPLC pump, a refrigerated heating ...
Sander Piiskop +2 more
doaj +1 more source
To clarify the mechanism of liberation in the comminution process of electronic scrap (e-scrap), we attempted to express the degree of liberation by first-order kinetic equation related to impact energy.
Takuya TATSUMOTO +5 more
doaj +1 more source

