Reaction kinetic behaviour and cycling stability of the 2LiBH4–MgH2 reactive hydride composite (Li-RHC) are experimentally determined and analysed as a basis for the design and development of hydrogen storage tanks. In addition to the determination
Julian Jepsen +11 more
doaj +1 more source
The influence of the solvent on organic reactivity. Part II. Hydroxylic solvent effects on the reaction rates of diazodiphenylmethane with 2-(2-substituted cyclohex-1-enyl)acetic and 2-(2-substituted phenyl)acetic acids [PDF]
The rate constants for the reaction of diazodiphenylmethane with 2-(2-substituted cyclohex-1-enyl)acetic acids and 2-(2-substituted phenyl)acetic acids, previously determined in seven hydroxylic solvents, were correlated using the total solvatochromic ...
VERA V. KRSTIC +2 more
doaj
The reactivity of a,b-unsaturated carboxylic acids. Part XVI. The kinetics of the reaction of cycloalkenylcarboxylic and cycloalkenylacetic acids with diazodiphenylmethane in various alcohols [PDF]
The rate constants for the reaction of diazodiphenylmethane with 1-cyclopentenecarboxylic, 1-cycloheptenecarboxylic, cyclopent-1-enylacetic and cyclohept-1-enylacetic acids were determined in eight alcohols at 30°C using the appropriate UV-spectroscopic ...
VERA V. KRSTIC +2 more
doaj
Connecting the kinetics and energy landscape of tRNA translocation on the ribosome. [PDF]
Functional rearrangements in biomolecular assemblies result from diffusion across an underlying energy landscape. While bulk kinetic measurements rely on discrete state-like approximations to the energy landscape, single-molecule methods can project the ...
Paul C Whitford +3 more
doaj +1 more source
Nocturnal nitrogen oxides at a rural mountain-site in south-western Germany [PDF]
A new, two-channel instrument for simultaneous NO3 and N2O5 monitoring was used to make the first comprehensive set of nocturnal NOx measurements (NO, NO2, NO3 and N2O5) at the Taunus Observatory, a rural mountain site (Kleiner Feldberg) in South-western
Fischer, Horst +15 more
core +1 more source
Heavy hydrogen in the stratosphere [PDF]
We report measurements of the deuterium content of molecular hydrogen (H2) obtained from a suite of air samples that were collected during a stratospheric balloon flight between 12 and 33 km at 40º N in October 2002. Strong deuterium enrichments of up to
Rhee, T.S. +10 more
core +1 more source
Thermoluminescence of zircon: a kinetic model [PDF]
The mineral zircon, ZrSiO4, belongs to a class of promising materials for geochronometry by means of thermoluminescence (TL) dating. The development of a reliable and reproducible method for TL dating with zircon requires detailed knowledge of the ...
Hartog, H.W. den, +11 more
core +1 more source
Estimation of kinetic rates of MAP kinase activation from experimental data [PDF]
Mathematical model is an important tool in systems biology to study the dynamics of biological systems inside the cell. One of the significant challenges in systems biology is the lack of kinetic rates that should be measured in experiments or estimated ...
Tianhai Tian, Tian, T.
core +1 more source
The Ile181Asn variant of human UDP‐xylose synthase (hUXS1), associated with a short‐stature genetic syndrome, has previously been reported as inactive. Our findings demonstrate that Ile181Asn‐hUXS1 retains catalytic activity similar to the wild‐type but exhibits reduced stability, a looser oligomeric state, and an increased tendency to precipitate ...
Tuo Li +2 more
wiley +1 more source
Comparison between electron and neutron Compton scattering studies
We compare two techniques: Electron Compton Scattering (ECS) and neutron Compton scattering (NCS) and show that using certain incident energies, both can measure the atomic kinetic energy of atoms in molecules and solids.
Moreh Raymond +2 more
doaj +1 more source

