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ELECTRONIC STRUCTURE AND CHEMICAL BOND IN KN3 AND KSCN CRYSTALS
Журнал структурной химии, 2015Crystal structure parameters, band spectra, distribution maps of the toal and partial electron densities of KN3 and KSCN are calculated from the first principles using the density functional method and the general properties and distinctions in the band spectra are analyzed. The groups of balance subbands are qualitatively similar; in the upper valence
N. G. Kravchenko, A. S. Poplavnoi
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Far infrared spectroscopy of the phase transition in KSCN
Ferroelectrics, 1990Abstract Polarized reflectivity and transmissivity of KSCN were measured in the spectral range 6–650 cm−1 and temperature region 15–430 K. The absorption at ν < 100 cm−1 for temperatures down to 100-200 K is several times greater than it would follow from t fit of the reflectivity to a sum of classical oscillators.
S. Kamba +5 more
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Computer simulation of diffuse scattering from KSCN crystal
Phase Transitions, 1996Abstract The diffuse scattering functions for two-dimensional model of KSCN crystal has been studied by the moleculx-dynamics simulation technique. We show that below the tetragonal orthorhombic phase transition the width of the diffuse peak remains temperature independent, although its intensity increases when the temperature approaches Tc from below.
Z. Łodziana, K. Parlński
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2D 39K NMR study of the phase transition in KSCN
Solid State Communications, 1995Abstract Two-dimensional (2D) “separation of interactions” 39K 1 2 → −1 2 NMR measurements of KSCN show that the line broadening around and above Tc is purely homogeneous. The disordering process above Tc is thus of dynamic and not of static origin.
R. Blinc +5 more
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Birefringence study of the 415 K phase transition in KSCN
Journal of Physics: Condensed Matter, 1990KSCN shows an order-disorder phase transition at 415 K. Accurate measurements of the birefringence in the temperature range from room temperature to 420 K support the validity of the Ising model with volume-dependent interactions. The temperature dependence of the birefringence is well correlated with the structural changes as predicted by the ...
A Fuith, J Kroupa
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Chemischer Informationsdienst, 1975
AbstractDie Löslichkeit von wasserfreiern Na‐thiosulfat in nicht wäßrigen Lösungsmitteln wird untersucht.
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AbstractDie Löslichkeit von wasserfreiern Na‐thiosulfat in nicht wäßrigen Lösungsmitteln wird untersucht.
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ChemInform Abstract: The Electrochemistry of Chromium(III) in Molten KSCN.
Chemischer Informationsdienst, 1986AbstractThe reduction of Cr3+ in molten KSCN (200°C) is quasi‐reversible, with a formal rate constant of 4‐7·10‐4cm s‐1.
R. J. POTTER, D. J. SCHIFFRIN
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Solution growth of large, high quality KSCN crystals
Journal of Crystal Growth, 1989Abstract Acetone turned out to be a proper solvent for the growth of large high quality KSCN crystals. A method for the purification of the solution is described together with an experimental set-up for the growth. The habit of the crystals is significantly different for crystals grown out of acetone and out of methanol.
A. Fuith, T. Streuselberger, H. Warhanek
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The Induction by Complement of a Change in KSCN-Dissociable Red Cell Membrane Lipids
The Journal of Immunology, 1976Abstract During complement lysis of antibody-sensitized sheep erythrocytes (EA) there was a larger loss of membrane phospholipids than during lysis elicited by hypotonic buffer. In addition, membranes prepared from complement-lysed EA had a marked reduction in KSCN (2.4 M)-dissociable membrane cholesterol and phospholipids, as compared ...
E B, Giavedoni, A P, Dalmasso
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Dynamic Acoustic Anomalies in KSCN Near the Improper Ferroelastic Phase Transition
Ferroelectrics, 2005The tensor of the elastic stiffness constants Cij of potassium thiocyanate (KSCN) has been measured in the temperature range 290 K to 420 K, including the order-disorder phase transition at 415 K, by the ultrasonic pulse echo overlap method at frequencies f = 20 MHz.
Schranz, Wilfried +3 more
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