Results 131 to 140 of about 88,281 (294)

Genetic code expansion for chemosensing and chemical actuation of biological functions

open access: yesBulletin of the Korean Chemical Society, EarlyView.
Genetic code expansion (GCE) broadens the chemical repertoire for precise control of protein function in biological systems. This review highlights GCE‐based sensing and actuating systems that operate through selective interactions between noncanonical amino acids and chemical triggers.
Jieun Bae, Dong‐Hyun Kim, Minseob Koh
wiley   +1 more source

Real‐time biosensing of Parkinson's disease biomarkers via NIR‐activated upconversion nanoparticles

open access: yesBMEMat, EarlyView.
Schematic illustration of the luminescence resonance energy transfer‐driven core‐shell‐shell UCNPs (cssUCNPs@Fluo4) nanoprobe for simultaneous monitoring of Ca²⁺‐temperature dynamics in Parkinson's disease models. Abstract Parkinson's disease (PD) is a progressive neurodegenerative disorder with incompletely understood pathophysiology, necessitating ...
Jialin Liu   +9 more
wiley   +1 more source

Methods and Applications of Lanthanide/Transition Metal Ion-Doped Luminescent Materials

open access: yesMolecules
Lanthanide/transition metal-doped luminescent materials are advanced materials with broad application potential. This type of material achieves control and optimization of luminescence performance by introducing lanthanide/transition metal ions into the ...
Xiaoyi Chen   +7 more
doaj   +1 more source

Superior CO2 Conversion Performance by Er‐Doped BiOCl Nanosheets Through Synergistic Photocatalytic Memory Effect and Er‐Doping

open access: yesCarbon Energy, EarlyView.
Er‐doping and the photocatalytic memory effect through visible‐light irradiation synergistically reconstruct internal electronic states of ultrathin Er‐doped BiOCl nanosheets and generate stable oxygen vacancies. Light absorption, charge carrier separation, and CO2 adsorption capability are subsequently enhanced, leading to a significant increase in ...
Lizhen Lu   +8 more
wiley   +1 more source

Beyond Activity: The Unified Framework of the Sabatier Principle to Guide Rational Design of Durable and Active Electrocatalysts

open access: yesCarbon Energy, EarlyView.
In this review, a unified framework of the Sabatier principle is applied to a diverse range of catalytic and electrocatalytic systems for advanced clean energy technologies, with a particular focus on the oxygen reduction reaction (ORR). This approach will guide the design and development of highly active and stable catalysts for fuel cells ...
Wanying Zhang   +6 more
wiley   +1 more source

A [3]Rotaxane Containing {Ti7Ga} Rings Linking CuII: Synthesis, Structure, and Spectroscopic Studies

open access: yesChemistry – A European Journal, EarlyView.
Extended hybrid inorganic‐organic [2]‐ and [3]‐rotaxanes are reported based on heterometallic rings with threads that link CuII complexes; the crystal structures are reported, and the solution behavior is investigated by double electron electron resonance spectroscopy methods.
Selena J. Lockyer   +7 more
wiley   +1 more source

Distinct Ligand‐ and Metal‐Centered Phosphorescence in a Terbium Carbazolyl Complex

open access: yesChemistry – A European Journal, EarlyView.
Terbium and lanthanum carbazolide complexes show two distinct modes of luminescence: Strongly temperature‐dependent narrow‐line terbium emission could be induced. In addition, both the terbium and the lanthanum complexes show broad‐line interligand emission processes with excited states of microsecond life‐time.
Xiaofei Sun   +9 more
wiley   +1 more source

Insights into coordination and ligand trends of lanthanide complexes from the Cambridge Structural Database

open access: yesScientific Reports
Understanding lanthanide coordination chemistry can help develop new ligands for more efficient separation of lanthanides for critical materials needs.
Shicheng Li   +2 more
doaj   +1 more source

Self‐Assembled Luminescent Au(I)–Adamantylamine Coordination Polymer Needles With Thermoresponsive Optical Properties

open access: yesChemistry – A European Journal, EarlyView.
A self‐assembled hydrophobic and red phosphorescent Au(I) coordination polymer (CP) was synthesized under mild conditions. Single‐crystal X‐ray diffraction (XRD) demonstrated linear Au(I) chains stabilized by aurophilic and hydrogen bonding interactions.
Miguel Justo‐Tirado   +4 more
wiley   +1 more source

Morphological Control of Aurophilic Chains of Gold(I) Dithiolate Dimers With Alkali and Alkali Earth Cations

open access: yesChemistry – A European Journal, EarlyView.
Luminescent coordination polymers of Group 1 (Li, K, Cs) and 2 (Mg─Ba) cations with gold(I) iso‐maleonitriledithiolate ({Au2[S2C = C(CN)2]}2−) units were prepared; 1‐D aurophilic chains are present in all cases. The structures strongly depend on cation charge and size, with N‐cyano coordination observed in the Gp 1 and larger Gp 2 cations. Increasingly
Jefferson A. Pells   +2 more
wiley   +1 more source

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