Chemistry – A European Journal, EarlyView.The influence of head‐to‐tail cyclization, as well as the effect of ring expansion with an additional glycine on lanmodulin‐inspired peptides on the structure and lanthanide (Ln)‐binding behavior was investigated. While the decrease of structural flexibility can indeed increase the Ln affinity and peptide pre‐organization, it does not lead to an ...
Sophie M. Gutenthaler‐Tietze +6 more
wiley +1 more source
Mid-infrared detection through ligand-driven local heating in lanthanide-doped nanoparticles. [PDF]
Nat CommunWang CW +6 more
europepmc +1 more source
Heterovalent, Homometallic Rings: Synthesis, Optical, and EPR Studies of {TiIV7TiIII} Complexes
Chemistry – A European Journal, EarlyView.A new class of heterovalent, homometallic complexes is reported, based on cyclic {TiIV7TiIII} cores with oxide and carboxylate bridges between nearest neighbors. The clusters show Class II mixed‐valent behavior at room temperature, but are valence localized at low temperature.
Selena J. Lockyer +8 more
wiley +1 more source
Lanthanide ion-doped carbon dots (Ln-CDs) as fluorescent nanoprobes: a review. [PDF]
RSC AdvKayani KF, Hamarawf RF.
europepmc +1 more source
Chemistry – A European Journal, EarlyView.We report a cellular membrane‐targeted europium(III) probe, Eu.Chol, that enables selective, time‐resolved detection of peroxynitrite (ONOO−) at the cell membrane interface. Eu.Chol demonstrates efficient incorporation into liposomes and Jurkat cells, with minimal response to H2O2, establishing a modular platform for subcellular ONOO− sensing ...
Jamie Webb +6 more
wiley +1 more source
Transferable Semiempirical Models for Judd-Ofelt Parameters and Multiphonon Relaxation in Eu<sup>3+</sup> Complexes: Toward an Experiment-Free Luminescence Design. [PDF]
J Comput ChemNeto CMB +5 more
europepmc +1 more source
A Cyclic {NiII8DyIII4} Cluster Where the DyIII Moments Are Organized by the Transition Metal Spins
Chemistry – A European Journal, EarlyView.The synthesis, structural characterisation, and magnetic properties of a cyclic Ni8Dy4 coordination cluster are reported. Ab initio CASSCF and DFT calculations help rationalize the shape of the microSQUID hysteresis and the competing magnetic interactions within the compound. ABSTRACT A series of [Ni8Ln4(CO3)4(L)8(NO3)2(H2O)8 (MeOH)4](NO3)2 (Ln = Dy (1)
Imon J. Dutta +7 more
wiley +1 more source
Theoretical framework for engineering Boltzmann luminescent nanothermometry. [PDF]
Light Sci ApplYang M, Zhang H, Zhang F.
europepmc +1 more source
Multivalent RNA‐Cleaving Agents on a Cubic Octameric Silsesquioxane Core
Chemistry – A European Journal, EarlyView.RNA‐cleaving agents on a cubic octameric silsesquioxane core were synthesized and characterized. Several catalytic systems of these structures were screened using hexaribonucleotide models. The best systems were then further used to study their catalytic efficiency in cleaving a HER2 mRNA model sequence. The induced cleavage sites were also determined.
Hanni Haapsaari, Iris Tuomi, Pasi Virta
wiley +1 more source
Tracing the <i>In Vivo</i> Fate of Polystyrene Nanoplastics via a Lanthanide Copolymerization Labeling Strategy. [PDF]
Environ Health (Wash)Shen J +8 more
europepmc +1 more source