Chemistry – A European Journal, EarlyView.Systematic studies of a series of new 3d–4f tetranuclear complexes revealed that the ferromagnetically coupled [Mn3Gd] complex exhibits large magnetic entropy changes, especially at higher temperatures and under lower magnetic fields. ABSTRACT A series of 3d‐4f heterometallic tetranuclear complexes, (TEA)[Mn3Gd(L)3(NO3)4(CH3CN)2] ([Mn3Gd]), (TEA)[Mn3La(
Takuya Shiga +6 more
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Role of cavitation on the dissolution of lanthanide oxides in nitric acid. [PDF]
Ultrason SonochemLahiri S, Ghosh A, Bhardwaj RL.
europepmc +1 more source
Chemistry – A European Journal, EarlyView.This work presents the synthesis and characterization of chiral dipicolinamide push–pull fluorophores. While possessing similar photophysical properties in solution, their solvent‐annealed thin films exhibit unexpected, nonreciprocal chiroptical activity in both absorption and emission, including a complete inversion of the chiroptical profile upon ...
Filippo Petri +3 more
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Persilylated and Related Silyl Anion‐Induced Synthesis of Group 3–10 Metal–Silyl Complexes
Chemistry – A European Journal, EarlyView.Persilylated and related silyl anions serve as powerful tools for constructing metal–silyl complexes across group 3–10 elements. Their strong σ‐donating ability and steric bulk stabilize low‐coordinate, reactive species and enable unique bonding motifs.
Yusuke Sunada
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Observation of high ionic (Li<sup>+</sup> and Na<sup>+</sup>) conductivity in novel hybrid membranes based on 2D lanthanide MOFs. [PDF]
RSC AdvPotdar A +4 more
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Chemistry – A European Journal, EarlyView.Analysis of x‐ray absorption spectra of U(VI) and U(V) oxides indicates an important role of U 5f−O$5f-\rm{O}$ 2p$2p$ charge transfer for increasing the 5f$5f$ occupancy and thereby affecting the ground state properties. ABSTRACT The 5f$5f$ states were probed in ThO2$\rm{ThO}_2$ and U(VI) and U(V) oxides using x‐ray absorption spectroscopy at the ...
Johan R. Vegelius +2 more
wiley +1 more source
Tailoring Photonic Landscape: Nanoengineering Empowers NIR-II Lanthanide Luminescence for Versatile Biomedical Applications. [PDF]
Small MethodsChen ZH, Cheng Z, Xue Y, Zhang H.
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A Solid‐Phase Approach to Chiral C2‐Substituted Cyclen and DOTA‐Like Lanthanoid Ligands
Chemistry – A European Journal, EarlyView.Chiral C2‐substituted cyclen derivatives have been designed and synthesized from chiral cyclic peptoids. Their conversion into the corresponding DOTA‐type ligands opens new avenues for the development of high‐relaxivity MRI contrast agents. ABSTRACT Magnetic resonance imaging (MRI) is a powerful diagnostic modality that relies on Gd+3‐based contrast ...
Rosaria Schettini +9 more
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Magnetic ordering and its influence on X‐ray spectroscopies
Major Reference Works, Page 163-168., 2023 International Tables for Crystallography is the definitive resource and reference work for crystallography and structural science.
Each of the eight volumes in the series contains articles and tables of data relevant to crystallographic research and to applications of crystallographic methods in all sciences concerned with the ...
Gerrit van der Laan +3 more
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EcoEnergy, EarlyView.This review summarizes a descriptor‐guided framework for linking theoretical calculations, in situ/operando characterization, synthesis regulation, and application screening in functional materials. Emphasis is placed on dynamic structure–property relationships that enable low‐cost material design with enhanced activity, stability, and environmental ...
Yanyu Jin +9 more
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