Results 81 to 90 of about 45,379 (303)

Neodymium‐Doped Nanocrystals for Sensing Cellular Temperature at the Nanoscale

Advanced Optical Materials, EarlyView.
Neodymium‐doped NaYF4 nanocrystals are engineered as bright, biocompatible nanothermometers for intracellular temperature mapping. Their ratiometric near‐infrared emission enables highly sensitive, nanoscale thermal readouts in living cells. Combined with gold nanostars for photothermal therapy, they reveal pronounced subcellular heating heterogeneity ...
Maria Bravo, Sandra Krzyzowska, Shelly Yang, Dingchen Wen, Jana Zielinski, Farsai Taemaitree, Samantha Zaman, Alastair Stewart, Susana Rocha, Paul Mulvaney, Hiroshi Uji‐i, Beatrice Fortuni, Sam Brooke, James Hutchison   +13 more
wiley   +1 more source

Bayesian‐Optimized Dual‐Mode Luminescence‐Based Optical Thermometry Enabled by Negative Thermal Expansion in Lu2(MoO4)3:Yb–Er–Tm Phosphor

Advanced Optical Materials, EarlyView.
A Bayesian optimization framework identifies the ideal composition for Lu2(MoO4)3:Yb–Er–Tm phosphors with minimal experimental trials. By leveraging the host's negative thermal expansion, the material achieves remarkable thermal quenching compensation.
Reiko Furukawa, Takuya Hasegawa, Tong Fang, Saneyuki Ohno, Tomoyo Goto, Yasushi Sato, Ayahisa Okawa, Shu Yin   +7 more
wiley   +1 more source

Synergistic Ligand Engineering Suppresses Dye Aggregation Quenching and Photobleaching in Lanthanide Upconversion Nanoparticles

Aggregate
Near‐infrared cyanine dyes are widely employed for sensitizing lanthanide upconversion luminescence (UCL), but generally suffer from aggregation‐caused quenching (ACQ) and photobleaching. Herein, we report a ligand engineering strategy utilizing pyridine‐
Shiqi Yu, Datao Tu, Fei Zhao, Fei Du, Yun Xing, Qingyan Liu, Xiaoying Shang, Renfu Li, Zhi Xie, Qian Liu, Xueyuan Chen   +10 more
doaj   +1 more source

Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H₂O)(CH₃COO)(P₂W₁₇O₆₁)}₂]¹⁶⁻

Molecules, 2020
Reaction of the trilacunary Wells−Dawson anion {α-P2W15O56}12− with ErIII ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type structure [{Er(H2O)(CH3COO)(P2W17O61)}2]16− (1).
Masooma Ibrahim, Ananya Baksi, Yan Peng, Firas Khalil Al-Zeidaneen, Israël M. Mbomekallé, Pedro de Oliveira, Christopher E. Anson   +6 more
doaj   +1 more source

Molecular neurochemistry of the lanthanides [PDF]

Synapse, 2019
AbstractLanthanides, once termed rare‐earth elements, are not as sparce in the environment as their traditional name suggests. Mean litospheric concentrations are in fact comparable to the physiologically fundamental elements such as iodine, cobalt, and selenium.
Artur Pałasz, Yolanda Segovia, Rafał Skowronek, John J. Worthington   +3 more
openaire   +4 more sources

Circularly Polarized Red‐NIR Emission With High Dissymmetry Factor From Achiral [Mo6I8(OCOC2F5)6]2− Cluster Anion Embedded in a Bent‐Core Liquid Crystal Host

Advanced Optical Materials, EarlyView.
Associating a chiral bent core liquid crystal molecule, that self‐assembles into helical nanofilaments, with an achiral red‐NIR phosphorescent octahedral molybdenum cluster produces a hybrid material exhibiting efficient red‐NIR circularly polarized emission under UV excitation.
Jeanne Rebours, Shamima Akhter, Md Kamrul Hasan, Serge Paofai, Maria Amela‐Cortes, Marianne Estelle Prévôt, Yann Molard   +6 more
wiley   +1 more source

Lanthanide-Promoted Reactions of Aldehydes and Amine Hydrochlorides in Aqueous Solution. Synthesis of 2,3-Dihydropyridinium and Pyridinium Derivatives

, 2016
Lanthanide-Promoted Reactions of Aldehydes and Amine Hydrochlorides in Aqueous Solution.
Johnny Ramirez (3003618), Li-Bing Yu (3038598), Jun Li (6494), Peng George Wang (256049), Depu Chen (2518024), Simon G. Bott (2464285)   +5 more
core   +1 more source

Antenna Effect in Halogen‐Containing ZnSm Coordination Compounds: Utilizing Colorimetry for a Room‐Temperature Tunable Ratiometric Molecular Thermometer

Advanced Science, EarlyView.
The ZnSm‐Cl dinuclear molecular complex was synthesized through a simple one‐pot method. ZnL and Sm3+ exhibit complementary temperature‐dependent emission As the temperature increases, a noticeable color difference of ZnSm‐Cl can be observed within the room temperature range of 253‐333 K.
Ye Xia, Yingshan Xue, Feng Pan, Ai Wang, Hong Huang, Zhenxing Li, Bing‐Wu Wang, Song Gao   +7 more
wiley   +1 more source

Weathered granites and soils harbour microbes with lanthanide-dependent methylotrophic enzymes

BMC Biology
Background Prior to soil formation, phosphate liberated by rock weathering is often sequestered into highly insoluble lanthanide phosphate minerals. Dissolution of these minerals releases phosphate and lanthanides to the biosphere.
Marcos Y. Voutsinos, Jacob A. West-Roberts, Rohan Sachdeva, John W. Moreau, Jillian F. Banfield   +4 more
doaj   +1 more source

A New Customizable Surfactant LLPS Strategy for Sustainable and Highly Efficient Radioactive Metal Ion Separation

Advanced Science, EarlyView.
A diluent‐free, customizable liquid–liquid phase separation (LLPS) platform enables highly efficient radioactive metal ion extraction and stripping. By encapsulating hydrophobic extractants into an ionic surfactant‐rich condensed phase, this LLPS system leverages synergistic electrostatic and coordination interactions.
Ruihan Yan, Yifu Hu, Wentao Wang, Zhi Cao, Meiwen Cao, Weifang Zheng, Guoan Ye, Taihong Yan   +7 more
wiley   +1 more source