Results 71 to 80 of about 88,281 (294)

Multicolor upconversion luminescence of dye-coordinated Er3+ at the interface of Er2O3 and CaF2 nanoparticles

open access: yesScience and Technology of Advanced Materials, 2019
Multicolor upconversion luminescence of Er3+ was successfully enhanced by optimizing the interface in dye-coordinated nanoparticles with a core/shell structure.
Ayumi Ishii   +5 more
doaj   +1 more source

Co-reduction of aluminium and lanthanide ions in molten fluorides : application to cerium and samarium extraction from nuclear waste [PDF]

open access: yes, 2009
This work concerns the method of co-reduction process with aluminium ions in LiF–CaF2 medium (79–21 mol.%) on tungsten electrode for cerium and samarium extraction.
Chamelot, Pierre   +3 more
core   +2 more sources

Color Routing and Beam Steering of Single‐Molecule Emission with a Spherical Silicon Nanoantenna

open access: yesAdvanced Functional Materials, EarlyView.
We experimentally demonstrate broadband directional emission from single molecules using a single spherical silicon nanoparticle assembled via DNA origami. By varying nanoparticle (NP) size and emitter position, we achieve unidirectional emission, beam steering, and color routing at the nanoscale, revealing modal interference as the underlying ...
María Sanz‐Paz   +9 more
wiley   +1 more source

Lanthanide-Mediated Dephosphorylation Used for Peptide Cleavage during Solid Phase Peptide Synthesis

open access: yesMolecules, 2013
Lanthanide(III) ions can accelerate the hydrolysis of phosphomonoesters and phosphodiesters in neutral aqueous solution. In this paper, lanthanide-mediated dephosphorylation has been applied in aqueous media as an orthogonal cleavage condition that can ...
Byunghee Yoo, Mark D. Pagel
doaj   +1 more source

Effective-Hamiltonian parameters for \emph{ab initio} energy-level calculations of SrCl$_{2}$:Yb$^{2+}$ and CsCaBr$_{3}$:Yb$^{2+}$

open access: yes, 2013
Calculated energy levels from recent \emph{ab initio} studies of the electronic structure of SrCl$_{2}$:Yb$^{2+}$ and CsCaBr$_{3}$:Yb$^{2+}$ are fitted with a semi-empirical "crystal-field" Hamiltonian, which acts within the model space $4f^{14} + 4f^{13}
Barandiaran, Z.   +5 more
core   +1 more source

Interaction of a symmetrical α,α',δ,δ'-Tetramethyl-cucurbit[6]uril with Ln³⁺ : potential applications for isolation of lanthanides [PDF]

open access: yes, 2016
The interaction of a symmetrical α,α′,δ,δ′-tetramethyl-cucurbit[6]uril (TMeQ[6]) with a series of lanthanide cations (Ln³⁺) was investigated in neutral water and in acidic solution.
Gao, Zhong-Zheng   +9 more
core   +2 more sources

Photon Avalanching Nanoparticles: The Next Generation of Upconverting Nanomaterials?

open access: yesAdvanced Functional Materials, EarlyView.
This Perspective outlines the mechanistic foundations that enable photon‐avalanche (PA) behavior in lanthanide nanomaterials and contrasts them with emerging application spaces and forward‐looking design strategies. By bridging threshold engineering, energy‐transfer dynamics, and materials engineering, we provide a coherent roadmap for advancing the ...
Kimoon Lee   +7 more
wiley   +1 more source

Halide‐Dependent Photoluminescence and Heavy‐Atom Effects in Low‐Melting Organic–Inorganic Manganese Halides

open access: yesAdvanced Functional Materials, EarlyView.
Two pyridinium‐based ionic liquid templated hybrid manganese halides, (C4Py)2[MnCl4] and (C4Py)2[MnBr4], display similar bulk structures but show significantly different photoluminescence behaviors due to the bromine heavy‐atom effect. Their stable local Mn environments remain intact even in the molten state, allowing applications such as luminescence ...
Biswajit Bhattacharyya   +22 more
wiley   +1 more source

Synergistic Ligand Engineering Suppresses Dye Aggregation Quenching and Photobleaching in Lanthanide Upconversion Nanoparticles

open access: yesAggregate
Near‐infrared cyanine dyes are widely employed for sensitizing lanthanide upconversion luminescence (UCL), but generally suffer from aggregation‐caused quenching (ACQ) and photobleaching. Herein, we report a ligand engineering strategy utilizing pyridine‐
Shiqi Yu   +10 more
doaj   +1 more source

Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H2O)(CH3COO)(P2W17O61)}2]16−

open access: yesMolecules, 2020
Reaction of the trilacunary Wells−Dawson anion {α-P2W15O56}12− with ErIII ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type structure [{Er(H2O)(CH3COO)(P2W17O61)}2]16− (1).
Masooma Ibrahim   +6 more
doaj   +1 more source

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