Supramolecular Terbium-Threonine Chiral Emitters with Tunable Circularly Polarized Luminescence as Anticounterfeiting-Ink for Autonomous Data Encryption. [PDF]
A one‐pot, aqueous, and scalable method for synthesizing chiral lanthanide supramolecular emitters using terbium and threonine is reported. The aqueous solution of these chiral emitters displays the following features: (i) 100 % transparency, (ii) tunable luminescence and CPL, and (iii) a pH feedback loop that controls the “on‐off” states of ...
Sekhar PMA +5 more
europepmc +2 more sources
Phosphine Coordination to Ce, Nd, Np, and Pu in ArBiAMPtBu-Supported Complexes and Their 2H and 13C Isotopologues. [PDF]
A dianionic ligand designed to encourage metal‐phosphine coordination—bis((3,5‐dimethylphenyl)amidomethyl)tertbutylphosphine (ArBiAMPtBu)—was employed in the synthesis of paramagnetic complexes of Ce, Nd, Np, and Pu, producing MI(ArBiAMPtBu)(thf)3.
Gray NAG +9 more
europepmc +2 more sources
Lanthanide cations have advantageous luminescence properties in the visible and in the near-infrared, such as high resistance to photobleaching which is a desirable property allowing long exposure of lanthanide compounds to excitation light ...
Stéphane Petoud
doaj +1 more source
Synthesis, structure, semiconductive and photoluminescent properties of [{Eu(NC5H4COOH)3(H2O)2}(1.5ZnCl4)•(2H2O)]n [PDF]
A novel bimetallic 4f–3d metal-isonicotinic acid inorganic–organic hybrid complex [{Eu(NC5H4COOH)3(H2O)2}(1.5ZnCl4)•(2H2O)]n (1) was synthesized via a hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction.
YA-PING XU +3 more
doaj +3 more sources
The use of a robust optical signaling probe with a high signal-to-noise ratio is important in the development of immunoassays. Lanthanide chelates are a promising material for this purpose, which provide time-resolved luminescence (TRL) due to their ...
Ka Ram Kim +6 more
doaj +1 more source
Crystal structure of a new europium(III) compound based on thiopheneacrylic acid
A europium(III) coordination compound based on thiopheneacrylic acid (Htpa), triaquatris[3-(thiophen-2-yl)prop-2-enoato-κ2O,O′]europium(III)–3-(thiophen-2-yl)prop-2-enoic acid (1/3), [Eu(C7H5O2S)3(H2O)3]·3C7H6O2S or [Eu(tpa)3(H2O)3]·3(Htpa) (1), where ...
Suwadee Jiajaroen +3 more
doaj +1 more source
Phosphoserine for the generation of lanthanide-binding sites on proteins for paramagnetic nuclear magnetic resonance spectroscopy [PDF]
Pseudocontact shifts (PCSs) generated by paramagnetic lanthanide ions provide valuable long-range structural information in nuclear magnetic resonance (NMR) spectroscopic analyses of biological macromolecules such as proteins, but labelling proteins site-
S. Mekkattu Tharayil +5 more
doaj +1 more source
A Periplasmic Lanthanide Mediator, Lanmodulin, in Methylobacterium aquaticum Strain 22A
Methylobacterium and Methylorubrum species oxidize methanol via pyrroloquinoline quinone-methanol dehydrogenases (MDHs). MDHs can be classified into two major groups, Ca2+-dependent MDH (MxaF) and lanthanide (Ln3+)-dependent MDH (XoxF), whose expression ...
Yoshiko Fujitani +2 more
doaj +1 more source
A polyhedral oligomeric silsesquioxanes (POSS) modified 8-hydroxyquinoline derivative (denoted as Q-POSS) was synthesized and used as a ligand to coordinate with lanthanide ions to obtain a series of lanthanide complexes Ln(Q-POSS)3 (Ln = Er3+, Yb3+, Nd3+
Qingrui Zhang +5 more
doaj +1 more source
Bis(η5-cyclopentadienyl)(2-{[(2-methoxyphenyl)imino]methyl}phenolato-κ3O,N,O′)terbium
The air- and moisture-sensitive title compound, [Tb(C5H5)2(C14H12NO2)], was synthesized from tris(cyclopentadienyl)(tetrahydrofuran)terbium and 2-{[(2-methoxyphenyl)imino]methyl}phenol. Each Tb atom is coordinated by two cyclopentadienyl ligands in an η5-
Mikhail E. Minyaev +3 more
doaj +1 more source

