Triplet Excitons Unlock Electroluminescence from Insulating Lanthanide Nanocrystals for Light-Emitting Diode Applications [PDF]
Lanthanide nanocrystals hold exceptional promise for electroluminescence applications due to their unique optical properties. However, their intrinsic insulating character and localized 4f orbitals severely restrict carrier injection, thereby hindering ...
Wenkai Li, Wei Lian, Datao Tu
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Purpose of the study — to evaluate bone density at the femur fracture site with local introduction of preparations based on etidronate lanthanide ions and calcium in the experiment. Materials and Methods. The experiment included 45 male rats divided into
I. F. Akhtyamov +4 more
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Influence of Ce, Nd, Eu and Tm Dopants on the Properties of InSe Monolayer: A First-Principles Study
Doping of foreign atoms may substantially alter the properties of the host materials, in particular low-dimension materials, leading to many potential functional applications.
Zhi Xie, Limin Chen
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Imposing high-symmetry and tuneable geometry on lanthanide centres with chelating Pt and Pd metalloligands [PDF]
Exploitation of HSAB preferences allows for high-yield, one-pot syntheses of lanthanide complexes chelated by two Pd or Pt metalloligands, [MII(SAc)4]2− (SAc− = thioacetate, M = Pd, Pt).
Bendix, Jesper +5 more
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Blockade of current through single calcium channels by trivalent lanthanide cations. Effect of ionic radius on the rates of ion entry and exit. [PDF]
Currents flowing through single dihydropyridine-sensitive Ca2+ channels were recorded from cell-attached patches on C2 myotubes. In the presence of dihydropyridine agonist to prolong the duration of single-channel openings, adding micromolar ...
Lansman, JB
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Lanthanide cations have advantageous luminescence properties in the visible and in the near-infrared, such as high resistance to photobleaching which is a desirable property allowing long exposure of lanthanide compounds to excitation light ...
Stéphane Petoud
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[Tb4(OH)4]-Cuboid Complex Dianion Stabilized with Six Carboxylate Bridges and Four Diketonate Caps
A cubane-like complex dianion [Tb4(OH)4(tfa)6(hfac)4]2− was synthesized, accompanied by two counter cations of [Ni(hfac)(2pyIN)2]+, where Htfa, Hhfac, and 2pyIN stand for trifluoroacetic acid, 1,1,1,5,5,5-hexafluoropentane-2,4-dione, and 4,4,5,5 ...
Yoshiki Yamaguchi, Takayuki Ishida
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Synthesis, Crystal Structure and Photophysical Properties of Lanthanide Coordination Polymers of 4- 4-(9H-Carbazol-9-Yl)Butoxy Benzoate: The Effect of Bidentate Nitrogen Donors on Luminescence [PDF]
A new aromatic carboxylate ligand, 4-[4-(9H-carbazol-9-yl)butoxy]benzoic acid (HL), has been synthesized by the replacement of the hydroxyl hydrogen of 4-hydroxy benzoic acid with a 9-butyl-9H-carbazole moiety. The anion derived from HL has been used for
Cowley, Alan H. +3 more
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Open questions on bonding involving lanthanide atoms
In-depth understanding of the bonding characteristics of the lanthanide ions in contemporary lanthanide-based materials is mandatory for tailoring their properties for novel applications.
T. Vitova, P. W. Roesky, S. Dehnen
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Engineered ferritin for lanthanide binding [PDF]
Ferritin H-homopolymers have been extensively used as nanocarriers for diverse applications in the targeted delivery of drugs and imaging agents, due to their unique ability to bind the transferrin receptor (CD71), highly overexpressed in most tumor ...
Baiocco, Paola +13 more
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