Results 81 to 90 of about 27,706 (301)

Rational design of a polyoxometalate intercalated layered double hydroxide: highly efficient catalytic epoxidation of allylic alcohols under mild and solvent-free conditions [PDF]

open access: yes, 2016
Intercalation catalysts, owing to their modular and accessible gallery and unique interlamellar chemical environment, have shown wide application in various catalytic reactions.
Chen, Wei   +4 more
core   +1 more source

Tailoring Microstructure in Copper‐Based Conductive Metal–Organic Frameworks for Enhanced Chemiresistive Sensing and Uptake of Sulfur Dioxide

open access: yesAdvanced Functional Materials, EarlyView.
Precursor‐ and solvent‐mediated synthesis yields four Cu3(HHTP)2 morphologies with distinct physicochemical, sorption, and sensing properties toward SO2. Uptake capacities correlate with BET surface area, while sensing performance scales with particle aspect ratio.
Patrick Damacet   +5 more
wiley   +1 more source

Thermal Activation of Copper Oxide Based upon the Copper Hydrotalcites of the Type CuxZn6-xCr2(OH)16(CO3).4H2O [PDF]

open access: yes, 2003
A combination of DSC and high resolution DTG coupled to a gas evolution mass spectrometer has been used to study the thermal properties of a series of Cu/Zn hydrotalcites of formulae CuxZn6-xAl2(OH)16(CO3).4H2O where x varied from 6 to 0.
Ding, Zhe, Frost, Raymond
core   +2 more sources

Bimetallic Nanoreactor Activates cGAS‐STING Pathway via mtDNA Release for Cancer Metalloimmunotherapy

open access: yesAdvanced Functional Materials, EarlyView.
A bimetallic Mn–Ca nanoreactor (MCC) is developed as a non‐nucleotide STING nanoagonist for cancer metalloimmunotherapy. MCC induces Ca2+ overload and hydroxyl radical generation, resulting in mitochondrial damage and mtDNA release. The released mtDNA cooperates with Mn2+ to robustly activate cGAS–STING signaling.
Xin Wang Mo   +7 more
wiley   +1 more source

Photo-oxidation of EPDM/layered double hydroxides composites: Influence of layered hydroxides and stabilizers

open access: yeseXPRESS Polymer Letters, 2007
The photo-oxidation of ethylene propylene diene monomer (EPDM)/ layered double hydroxide (LDH) composites as well as EPDM/LDH with stabilizers is studied under accelerated UV irradiation (λ≥290 nm) at 60°C for different time intervals.
doaj   +1 more source

Modular polyoxometalate-layered double hydroxides as efficient heterogeneous sulfoxidation and epoxidation catalysts [PDF]

open access: yes, 2018
Selective sulfoxidation of sulfides and epoxidation of olefins are two types of important organic reactions and the corresponding products of sulfoxides, sulfones and epoxides are widely used as raw materials in industrial processes.
Al-Maksoud   +57 more
core   +1 more source

Tuning the Electronic Structure and Spin State of Fe─N─C Catalysts Using an Axial Oxygen Ligand and Fe Clusters for High‐Efficiency Rechargeable Zinc–Air Batteries

open access: yesAdvanced Functional Materials, EarlyView.
A FeN4─O/Clu@NC‐0.1Ac catalyst containing atomically‐dispersed FeN4─O sites (medium‐spin Fe2+) and Fe clusters delivered a half‐wave potential of 0.89 V for ORR and an overpotential of 330 mV at 10 mA cm−2 for OER in 0.1 m KOH. When the catalyst was used in a rechargeable Zn–air battery, a power density of 284.5 mW cm−2 was achieved with excellent ...
Yongfang Zhou   +8 more
wiley   +1 more source

Materiales laminares pilareados: preparación y propiedades

open access: yesQuímica Nova, 1999
The structure of several types of layered materials will be described. These include clays, layered double hydroxides, group IV metal phosphates and other layered materials. The preparation of the pillared materials and pillaring agents will be presented
Pergher Sibele B. C.   +2 more
doaj  

From Waste to Value: Conversion of Calcium Sulfate to Vaterite via Carbon Capture and Storage

open access: yesAdvanced Functional Materials, EarlyView.
This study introduces a new concept for carbon management that relies on the carbonation of industrial gypsum waste and yields phase‐pure vaterite at ambient conditions without any additives. The obtained vaterite is further shown to be a reactive material that develops compressive strength in aqueous suspensions like conventional cements.
Carlos Pimentel   +4 more
wiley   +1 more source

Layered double hydroxides for aluminium alloys corrosion resistance [PDF]

open access: yes, 2007
Layered Double Hydroxides (LDHμs), represented by the general formula [MII (1-x)MIIIx(OH)2[An-x/n].zH2O or [MIMIII2(OH)6[An-1/n].zH2O], where MI, MII, MIII are mono-, di- and tri-valent metal cations, are being researched as anion-exchange
Rangel, C. M., Travassos, Maria Antónia
core  

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