Rapid determination of serum albumin partition coefficients using affinity chromatography
Sorption to serum albumin is essential for characterizing the distribution of chemicals in organisms. It impacts the concentration of the freely dissolved chemical in vivo and in vitro, and needs to be considered when effect concentrations at the target ...
Nadin Ulrich, Alexander Böhme
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How Water's Properties Are Encoded in Its Molecular Structure and Energies. [PDF]
How are water's material properties encoded within the structure of the water molecule? This is pertinent to understanding Earth's living systems, its materials, its geochemistry and geophysics, and a broad spectrum of its industrial chemistry. Water has
Brini, Emiliano +5 more
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Solubility data and solubility parameters of barnidipine in different pure solvents
Introduction: Solubility studies and obtaining physicochemical data on drugs in pure solvents belonging to different chemical classes are key to developing new drug formulations.
Mª Ángeles Peña-Fernández +3 more
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Novel methods for predicting gas–particle partitioning during the formation of secondary organic aerosol [PDF]
Several methods have been presented in the literature to predict an organic chemical's equilibrium partitioning between the water insoluble organic matter (WIOM) component of aerosol and the gas phase, Ki,WIOM, as a function of temperature. They include (
F. Wania +4 more
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Solvatochromism of 5-(4-substituted arylazo)-4-phenyl-6-methyl-3-cyano-2-pyridones
Eight 5-(4-substituted arylazo)-4-phenyl-6-methyl-3-cyano-2-pyridones were synthesized by reaction of benzoylacetone and arendiazonium salt, followed by condensation with cyanoacetamide. Absorption spectra of all azo pyridone dyes were recorded in twelve
Gordana S. Ušćumlić +1 more
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Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer [PDF]
Carbon supercapacitors, which are energy storage devices that use ion adsorption on the surface of highly porous materials to store charge, have numerous advantages over other power-source technologies, but could realize further gains if their electrodes
Chmiola, John +5 more
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The influence of the polarity of the solvent and hydrogen bonding on the electronic absorption spectra of some previously synthesized substituted 1,2,4-triazoline-3-thiones was studied.
Mirjana Jankulovska +4 more
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Comparing Protonolysis and Transmetalation Reactions: Microcalorimetric Studies of C–AuI Bonds in [AuRL] Complexes [PDF]
Producción CientíficaThe protonolysis of C–Au bonds in [AuRL] organometallic complexes has been studied by calorimetry for twelve R groups. The experimental data have been combined with DFT calculations to obtain Bond Dissociation Energy values (BDE).
Casares González, Juan Ángel +2 more
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Effect of hydrogen bonding and complexation with metal ions on the fluorescence of luotonin A [PDF]
Fluorescence characteristics of a biologically active natural alkaloid, luotonin A (LuA), were studied by steady-state and time-resolved spectroscopic methods.
Abraham +45 more
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Effect of base–acid properties of the mixtures of water with methanol on the solution enthalpy of selected cyclic ethers in this mixture at 298.15 K [PDF]
The enthalpies of solution of cyclic ethers: 1,4- dioxane, 12-crown-4 and 18-crown-6 in the mixture of water and methanol have been measured within the whole mole fraction range at T = 298.15 K.
A Wakisaka +56 more
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