Results 171 to 180 of about 657,314 (280)

A Ruthenium‐(Ph‐BPE) Catalyst for Asymmetric Alkynylation of Fluoral: Enantioselection From 1 of 12 Fluxional Stereogenic‐at‐Ruthenium Complexes

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 30, 20 July 2026.
The first enantioselective alkynylations of aqueous fluoral are described. These processes are catalyzed by an iodide‐bound ruthenium‐(Ph‐BPE)‐catalyst; an octahedral metal complex that can exist as 12 diastereomeric‐at‐metal isomers. Calculations reveal that 2 of 12 stereoisomeric complexes account for 99.9% of the Boltzmann population and that ...
Weijia Shen   +6 more
wiley   +1 more source

Iodine-Based Coordination Compounds: A Strategy Toward Antibiotic Potentiation. [PDF]

open access: yesInt J Mol Sci
Shepilov D   +10 more
europepmc   +1 more source

“Innocent” Electrolytes Can Influence Organic Electrosynthetic Selectivity

open access: yesChemElectroChem, Volume 13, Issue 14, 17 July 2026.
Organic electrosynthesis has emerged as a powerful strategy for leveraging inexpensive and abundant electricity in organic synthesis, but understanding the role of inert supporting electrolyte is largely unexplored. This article investigates cobalt‐based metal–carbon bond homolysis and elucidates how supporting electrolytes influence reaction rates ...
Zachary A. Nguyen   +7 more
wiley   +1 more source

Total Synthesis of Sacrolide A and Cytotoxic Evaluation

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 27, 17 July 2026.
Isolated from the edible cyanobacterium Aphanothece sacrum, sacrolide A is a highly potent antimicrobial and cytotoxic metabolite. Its total synthesis via a convergent strategy enabled accurate assessment of its effects on liver and colon cells, offering new insights into its bioactivity and potential health risks.
Priyanka Kataria   +7 more
wiley   +1 more source

Toward Sustainable Carbonylation Reactions Enabled by CO Surrogates in Green Solvents

open access: yesChemSusChem, Volume 19, Issue 13, 14 July 2026.
Carbonylation reactions offer a sustainable route to valuable carbonyl compounds. This review highlights methodologies that exploit carbonylative coupling to drastically enhance process sustainability, avoiding the direct use of CO through CO surrogates and promoting syntheses in green solvents potentially derived from renewable and sustainable sources.
Francesco Messa   +2 more
wiley   +1 more source

A Lithium Fluoride Interfacial Layer for Low-Voltage and Reliable Perovskite Memristors. [PDF]

open access: yesACS Appl Electron Mater
Pendyala NK   +5 more
europepmc   +1 more source

One‐Pot Depolymerization, Demethylation, and Phenolation of Lignin for Bioactive Polyphenol Production

open access: yesChemSusChem, Volume 19, Issue 13, 14 July 2026.
Low‐cost lignin was upgraded in an acidic lithium bromide (LiBr) solution via integrated depolymerization, demethylation, and phenolation to yield bioactive polyphenols with enhanced phenolic hydroxyl content. The resulting polyphenols exhibited strong antioxidant and antibacterial activities, along with low cytotoxicity and promising in vivo ...
Long Li   +9 more
wiley   +1 more source

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