Results 31 to 40 of about 4,754 (185)

Thermodynamic Limits to Molecular Doping in Conjugated Polymers: A Perspective on Phase Behavior and Miscibility

open access: yesAdvanced Materials, EarlyView.
Molecular doping of conjugated polymers is fundamentally constrained by thermodynamic phase behavior. This Perspective reframes doping efficiency and stability in terms of miscibility limits, binodals, and solvus boundaries, highlighting the role of effective interaction parameters and charge transfer.
Somayeh Kashani   +10 more
wiley   +1 more source

Reversible Thermoassociation of Water-Soluble Polymers Thermoassociation réversible de polymères hydrosolubles

open access: yesOil & Gas Science and Technology, 2006
In various industrial fields, water soluble polymers are commonly used as thickening agents to control the reology of aqueous fluids. Nevertheless, their properties are weakened as the temperature increases. In order to overcome this problem, the concept
L'alloret F.   +3 more
doaj   +1 more source

Thermoregulated Coacervation, Metal-Encapsulation and Nanoparticle Synthesis in Novel Triazine Dendrimers

open access: yesMolecules, 2016
The synthesis and solubility behaviors of four generation five (G5) triazine dendrimers are studied. While the underivatized cationic dendrimer is soluble in water, the acetylated and propanoylated derivatives undergo coacervation in water upon ...
Fermín Ramírez-Crescencio   +7 more
doaj   +1 more source

Stimuli‐Responsive Hierarchical Structuring Controls Survival and Programs Hydrogelation of Supramolecular Metallofibers

open access: yesAdvanced Materials, EarlyView.
Aqueous Zn(II) Salphen metallofibers decorated with PNIPAM undergo reversible, multi‐stimuli‐responsive hierarchical bundling. This higher‐order structuring kinetically stabilizes the otherwise fragile assemblies against dilution, acidic hydrolysis, and transmetallation, enables selective sorting of responsive fibers, and programs hydrogelation at ...
Merlin R. Stühler   +5 more
wiley   +1 more source

Interionic bonding in aqueous phosphonium ionic liquid solutions exhibiting LCST behavior with high phase separation temperatures

open access: yesJournal of Ionic Liquids
Phosphonium-derived ionic liquids have emerged as a powerful class of thermoresponsive materials with sought after Lower Critical Solution Temperature (LCST) phase separation with applications across a broad range of fields.
Eva M. Gulotty   +5 more
doaj   +1 more source

Bioinspired Adaptive Surfaces for Intelligent Liquid Manipulation: Progressing From Passive and Active to Hybrid Strategies

open access: yesAdvanced Materials, EarlyView.
This review examines passive, active, and hybrid liquid manipulation strategies, highlighting hybrid approaches as an emerging route to reconcile energy efficiency with adaptive control. By actively reconstructing passive surfaces to store programmable interfacial energy, hybrid systems enable flexible yet low‐power liquid transport, with perspectives ...
Jiaqi Miao   +3 more
wiley   +1 more source

Plasma Polymerization of SnOxCy Organic-Like Films and Grafted PNIPAAm Composite Hydrogel with Nanogold Particles for Promotion of Thermal Resistive Properties

open access: yesMicromachines, 2016
In this study, a new type of temperature sensor device was developed. The circular electrode of the thermally sensitive sensor was modified with tetramethyltin (TMT) and O2 plasma to form a thin SnOxCy conductive layer on the electrode surface.
Chin-Yen Chou   +4 more
doaj   +1 more source

Stimuli-Responsive Thiomorpholine Oxide-Derived Polymers with Tailored Hydrophilicity and Hemocompatible Properties

open access: yesMolecules, 2022
Thermo-responsive hydrophilic polymers, including those showing tuneable lower critical solution temperature (LCST), represent a continuous subject of exploration for a variety of applications, but particularly in nanomedicine.
Laura Vasilica Arsenie   +6 more
doaj   +1 more source

Performance enhancement of aqueous ionic liquids with lower critical solution temperature (LCST) behavior through ternary mixtures [PDF]

open access: yesJournal of Materials Chemistry A
Mixtures of two thermally responsive ionic liquids (ILs) in water exhibiting phase separation above a lower critical solution temperature (LCST) demonstrate a synergy that enhances the osmotic strength and lowers the LCST compared to binary mixtures.
Ahmed Mahfouz   +3 more
openaire   +2 more sources

Soft Skins With Reversible Thickness Morphing: Materials, Mechanisms, and Applications

open access: yesAdvanced Materials, EarlyView.
Evolution of electronic skin (e‐skin) technologies toward adaptive, multifunctional soft skins. Phase I highlights early rigid and discrete sensory interfaces. Phase II shows the transition toward flexible, stretchable, and large‐area e‐skin. Phase III captures the emergence of computational e‐skin.
Oliver Ozioko   +2 more
wiley   +1 more source

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