Results 51 to 60 of about 8,204 (174)

Stimuli-Responsive Thiomorpholine Oxide-Derived Polymers with Tailored Hydrophilicity and Hemocompatible Properties

open access: yesMolecules, 2022
Thermo-responsive hydrophilic polymers, including those showing tuneable lower critical solution temperature (LCST), represent a continuous subject of exploration for a variety of applications, but particularly in nanomedicine.
Laura Vasilica Arsenie   +6 more
doaj   +1 more source

Tuning the critical solution temperature of polymers by copolymerization [PDF]

open access: yes, 2015
We study statistical copolymerization effects on the upper critical solution temperature (CST) of generic homopolymers by means of coarse-grained Langevin dynamics computer simulations and mean-field theory.
Chudoba, Richard   +3 more
core   +3 more sources

Thermodynamic Limits to Molecular Doping in Conjugated Polymers: A Perspective on Phase Behavior and Miscibility

open access: yesAdvanced Materials, EarlyView.
Molecular doping of conjugated polymers is fundamentally constrained by thermodynamic phase behavior. This Perspective reframes doping efficiency and stability in terms of miscibility limits, binodals, and solvus boundaries, highlighting the role of effective interaction parameters and charge transfer.
Somayeh Kashani   +10 more
wiley   +1 more source

Lower critical solution temperature versus volume phase transition temperature in thermoresponsive drug delivery systems

open access: yeseXPRESS Polymer Letters, 2011
One of the most subtle problem in the characterization of thermoresponsive polymers is the evaluation of the relationship between the lower critical solution temperature (LCST) of the linear polymer and the volume phase transition temperature (VPTT) of ...
doaj   +1 more source

Hydrophobic-electrostatic balance driving the LCST offset aggregation-redissolution behavior of N-alkylacrylamide-based ionic terpolymers [PDF]

open access: yes, 2010
A series of random terpolymers composed of N-isopropylacrylamide (NIPAAm), 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS), and N-tert-butylacrylamide (NTBAAm) monomers were synthesized by free radical polymerization.
López Pérez, Paula M.   +5 more
core   +1 more source

Performance enhancement of aqueous ionic liquids with lower critical solution temperature (LCST) behavior through ternary mixtures [PDF]

open access: yesJournal of Materials Chemistry A
Mixtures of two thermally responsive ionic liquids (ILs) in water exhibiting phase separation above a lower critical solution temperature (LCST) demonstrate a synergy that enhances the osmotic strength and lowers the LCST compared to binary mixtures.
Ahmed Mahfouz   +3 more
openaire   +2 more sources

Plasmonic Nanomachines: Creating Local Potential Gradients and Motions

open access: yesAdvanced Materials, EarlyView.
Plasmonic nanomachines can generate optical, thermal, and chemical potential gradients to drive directional rectilinear, rotational, and twisting motions at the nanometer scale. The integration of multimodal plasmonic forces with functional materials and programmed structural distortions enables precise spatiotemporal actuation, thereby providing a ...
Yoonhee Kim   +3 more
wiley   +1 more source

Temperature Driven Transformation in Dextran-Graft-PNIPAM/Embedded Silver Nanoparticle Hybrid System

open access: yesInternational Journal of Polymer Science, 2019
During the last decade, stimuli-responsible polymers based on poly(N-isopropylacrylamide) having conformational transition in the range of physiological temperature have been discussed as novel drug delivery nanosystems.
V. Chumachenko   +8 more
doaj   +1 more source

Solvent-induced micelle formation in a hydrophobic interaction model

open access: yes, 2004
We investigate the aggregation of amphiphilic molecules by adapting the two-state Muller-Lee-Graziano model for water, in which a solvent-induced hydrophobic interaction is included implicitly.
A. Ben-Naim   +12 more
core   +1 more source

Nanomaterial Integration at Liquid–Liquid Interfaces for Green Catalysis

open access: yesAdvanced Materials, EarlyView.
Functional nanomaterials assembled at liquid–liquid interfaces create dual‐role platforms serving as emulsion stabilizers and catalytic sites, offering enhanced reaction kinetics with improved catalyst recovery and recyclability. This review examines design strategies, structure‐performance relationships, and industrial implementation prospects of ...
Bokgi Seo   +6 more
wiley   +1 more source

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