Results 91 to 100 of about 6,769 (240)

μ-Hexathiometadiphosphato-bis[(1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O)rubidium] acetonitrile disolvate

open access: yesActa Crystallographica Section E, 2013
The asymmetric unit of the title compound, [Rb2(P2S6)(C12H24O6)2]·2CH3CN, contains one half of an [Rb(18-crown-6)2]2[P2S6] unit and one acetonitrile solvent molecule. The [Rb(18-crown-6)]2[P2S6] unit is completed by inversion symmetry.
Flora Qarri   +2 more
doaj   +1 more source

Prism[5]MaxQ: A Sulfated Prism[5]Arene and Its Molecular Recognition Properties Toward a Panel of Quaternary Ammonium Guests

open access: yesChemistry – A European Journal, EarlyView.
We report the synthesis and characterization of a sulfated prism[5]arene host (Prism[5]MaxQ). Prism[5]MaxQ displays ultrahigh binding affinity (Ka up to 1012 M−1) toward hydrophobic (di)cations in phosphate‐buffered saline (PBS). The work positions Prism[5]MaxQ as a new member of the family of ultrahigh‐affinity hosts poised for use as a sequestrant in
Emmanuel A. Bazan‐Bergamino   +1 more
wiley   +1 more source

Anion Recognition and Sensing by a New Macrocyclic Dinuclear Copper(II) Complex: A Selective Receptor for Iodide [PDF]

open access: yes, 2016
A macrocyclic dinuclear copper complex, [Cu2II(1)Br3(H2O)]Br, has been synthesized and characterized by X-ray crystallography, in which the macrocycle is folded to form a bowl-shaped cavity.
Md. Alamgir Hossain (1371456)   +4 more
core   +3 more sources

Exploring Calixarene‐Based Pseudorotaxane Architectures: Threading Ammonium Axles With an Exo‐Rim π‐Functionalized Calix[6]Arene Macrocycle

open access: yesChemistry – A European Journal, EarlyView.
This research presents a novel 1,4‐π‐functionalized calix[6]arene with enhanced interactions with dialkylammonium axles. We investigate threading behavior in CDCl3, highlighting how exo‐rim π‐functionalization affects binding affinity and stereoselectivity.
Veronica Iuliano   +7 more
wiley   +1 more source

Host-Guest Complexations of Amine Boranes and Isoelectronic/Isostructural Quaternary Alkylammonium Cations by Cucurbit[7]uril in Aqueous Solution

open access: yesHeteroatom Chemistry, 2019
The host-guest complexation of six amine boranes (R3NBH3) by the macrocyclic host molecule cucurbit[7]uril (CB[7]) in aqueous solution has been investigated using 1H and 11B NMR spectroscopy.
Mona A. Gamal-Eldin, Donal H. Macartney
doaj   +1 more source

Metal‐Ion Regulated Light‐Free Z→E Isomerization of Azobenzene Glycomacrocycle

open access: yesChemistry – A European Journal, EarlyView.
Metal ion‐catalyzed Z→E isomerization of photoswitchable azobenzene glycomacrocycle: A new azobenzene‐based glycomacrocycle is capable of forming a 1:1 complex with divalent metal ions in both E‐ and Z‐isomers. The complexes undergo light‐free Z→E isomerization in a timescale spanning from seconds to weeks.
Yang Zhou   +4 more
wiley   +1 more source

Macrocyclic Diacetylene-Terthiophene Cocrystal: Molecular Self-Assembly, Topochemical Polymerization, and Energy Transfer [PDF]

open access: yes, 2020
The macrocyclic structure offers direction-control self-assembly to generate columnar supramolecular architectures with a guest molecule-accessible interior cavity.
김영미
core   +1 more source

Benzo[c][1,2,5]Thiadiazole Linkers Enhance the Effectiveness of Cavity‐Containing Supramolecular Photocatalysts

open access: yesChemistry – A European Journal, EarlyView.
Seven novel supramolecular photosensitizers based on benzo[c][1,2,5]thiadiazole (BTZ) tethered to calix[4]arene (C[4]) scaffolds are reported with facile, scalable, and selective syntheses. Their abilities to produce singlet oxygen have been tested through the photo‐oxidation of α‐terpinene.
Leonardo Amicosante   +6 more
wiley   +1 more source

MoloVol : an easy-to-use tool for calculating cavity volumes and surfaces [PDF]

open access: yes, 2021
Cavities are a ubiquitous feature of chemical structures encountered in various fields ranging from supramolecular chemistry to molecular biology.
Maglic, Jasmin   +2 more
core  

Synthesis, Physicochemical Characteristics, Self‐Assembly and Encapsulation Ability of per‐Ethylene‐Glycol‐Functionalized Resorcin[4]Arenes and Their Molecular Capsules: On the Road to Liquid Capsules

open access: yesChemistry – A European Journal, EarlyView.
Per‐ethylene‐glycol (EG)‐functionalized resorcin[4]arenes containing 12, 16, and 20 EG groups namely compounds 1d, 1e, and 1f, respectively, were prepared and found to self‐assemble, in organic solvents, into hexameric capsules. These capsules are more dynamic than the ones prepared based on alkyl substituted resorcin[4]arenes.
Gangadhara Angajala   +3 more
wiley   +1 more source

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