Results 51 to 60 of about 430,530 (226)

One‐Pot Formation of Large Macrocycles with Modifiable Peripheries and Internal Cavities

open access: yesAngewandte Chemie International Edition, 2009
AbstractThe shape of things to come: Aromatic oligohydrazide macrocycles with planar backbones enforced by three‐center hydrogen bonds are formed in high yield from monomeric diacid chlorides and dihydrazides. Macrocycles consisting of six meta‐linked pyridine and benzene residues have an internal cavity of about 10 Å diameter, while those with ...
Ferguson, Joseph S.   +5 more
openaire   +3 more sources

Ultra‐Radiostable Covalent Conformationally Interlocked Networks Enabling a Universal Radiometal‐Labeling Platform for Cancer Radioembolization

open access: yesAdvanced Science, EarlyView.
Conjugated poly(imide dioxime)‐based microspheres establish a radiometal coordination‐driven conformational interlocked network with ultra‐high radiostability. This platform enables low‐temperature, multi‐radionuclide labeling for SPECT/PET/MRI imaging and radionuclide therapy. Mechanistic insights from EXAFS and DFT reveal enhanced stability, while in
Xiao Xu   +10 more
wiley   +1 more source

A Linear Chain of Water Molecules Accommodated in a Macrocyclic Nanotube Channel

open access: yes, 2016
A macrocyclic tetramer of 2-phenyl-1,3,4-oxadiazole was synthesized, and its self-assembly was investigated. The macrocycle was stacked to form a one-dimensional (1D) columnar structure containing water molecules.
Katsuya Sako (2398243)   +8 more
core   +2 more sources

Macrocyclic Chiral Receptors toward Enantioselective Recognition of Naproxen

open access: yes, 2016
A macrocyclic receptor based on a bischromenylurea and an α,α‘-(o,o‘-dialkyl)diphenyl-p-xylylenediamine spacer provides a C2 chiral cavity to associate carboxylates by H-bonds.
Silvia González (259583)   +5 more
core   +1 more source

Synthetic macrocyclic Ionophores [PDF]

open access: yes, 1989
14-Crown-4 derivatives bearing either one or two oxymethyl, benzyl- oxymethyl, methoxycarbonylmethyl or carbamoylmethyl substituents have been prepared in an attempt to obtain selective ionophores for lithiumions. Complexation has been monitored by IR,
Nicholson, Patrick Edmund
core  

New metal organic frameworks incorporating the ditopic macrocyclic ligand dipyridyldibenzotetraaza[14]annulene

open access: yes, 2011
The synthesis and crystal structures of three new metal organic frameworks of type [Zn(L-2H)](n) (1), {[ZnLCl2](CH3CN)(0.5)(DMF)(0.5)(H2O)(0.5)}(n) (2) and {[CdL (DMF)(NO3)(2)]center dot DMF}(n) (3), all based on the dipyridyl-derivatised macrocycle ...
Parkin, A.   +23 more
core   +1 more source

Porphyrin‐Based Porous Materials for Antibacterial Applications

open access: yesAdvanced Science, EarlyView.
Porphyrin‐based porous materials have excellent photophysical properties and tunable structures for high‐efficiency antibacterial therapy. This review comprehensively discusses the structural design strategies and synthetic pathways of the four main types of porphyrin‐based porous materials, summarizes their cross‐domain antimicrobial applications, and
Xiao‐Xue Liang   +4 more
wiley   +1 more source

Advances in the synthesis and applications of macrocyclic polyamines

open access: yesRoyal Society Open Science
Macrocyclic polyamines constitute a significant class of macrocyclic compounds that play a pivotal role in the realm of supramolecular chemistry. They find extensive applications across diverse domains including industrial and agricultural production ...
Yongguang Gao   +5 more
doaj   +1 more source

Cyclodextrin: A prospective nanocarrier for the delivery of antibacterial agents against bacteria that are resistant to antibiotics

open access: yesHeliyon, 2023
Supramolecular chemistry introduces us to the macrocyclic host cyclodextrin, which has a hydrophobic cavity. The hydrophobic cavity has a higher affinity for hydrophobic guest molecules and forms host-guest complexation with non-covalent interaction ...
Pranoy Saha, Md Rajdoula Rafe
doaj   +1 more source

Inherently Chiral Macrocyclic Oligothiophenes: Easily Accessible Electrosensitive Cavities with Outstanding Enantioselection Performances [PDF]

open access: yesChemistry – A European Journal, 2014
AbstractLinear conjugated oligothiophenes of variable length and different substitution pattern are ubiquitous in technologically advanced optoelectronic devices, though limitations in application derive from insolubility, scarce processability and chain‐end effects. This study describes an easy access to chiral cyclic oligothiophenes constituted by 12
F. Sannicolò   +13 more
openaire   +6 more sources

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