Results 171 to 180 of about 3,360 (286)

Mechanochemically assembled organometallic complexes: a mechanistic study. [PDF]

Chem Sci
Hamdouna L, Pisanò G, Rankin AGM, Trébosc J, Falivene L, Ritacco I, Devos O, Delevoye L, Roussel P, Caporaso L, Cavallo L, Nolan SP, Lafon O, Cazin CSJ.   +13 more
europepmc   +1 more source

Phase‐Field Simulation for the Microstructural Evolution of CuPb2F6 During Defluorination

physica status solidi (a), Volume 223, Issue 11, 10 June 2026.
A CALPHAD‐coupled phase‐field model uncovers how discharge rate and nucleation density control Cu nanoparticle formation in CuPb2F6 cathodes. Faster kinetics produce finer particles governed by concentration gradients, enhancing reversible capacity.
Shangping Zhu, Hiroshi Akamine, Yusuke Nagahata, Takeshi Tojigamori, Hidenori Miki, Kousuke Noi, Satoshi Iikubo   +6 more
wiley   +1 more source

Experimental Isolation of Single Impact, Cumulative Energy, Aging, and Liquid-Assisted Grinding Effects in Mechanochemical Reactions. [PDF]

Angew Chem Int Ed Engl
Templ J, Borchardt L.
europepmc   +1 more source

Bayesian Optimization of Solvent‐Free Thermal Amidation via Reactive Extrusion

Chemistry – A European Journal, Volume 32, Issue 22, 9 June 2026.
Thermal amidation between a carboxylic acid and an amine was successfully conducted in an extruder in the absence of solvent, coupling agent, or catalyst, relying on an adapted Bayesian Optimization protocol. Active pharmaceutical ingredient moclobemide was synthesized on a larger scale, achieving excellent yield and low Process Mass Intensity (PMI ...
Matthieu Lavayssiere, Xavier Bantreil, Frédéric Lamaty   +2 more
wiley   +1 more source

Catalytic High-Speed Reactive Extrusion for Polyethylene Mechanochemical Upcycling. [PDF]

ChemSusChem
Jamalzadeh M, Masembe P, Pujari H, Keller L, Borja MG, Monwar MM, Cui L, Hallac B, Schwendemann D, Sobkowicz MJ.   +9 more
europepmc   +1 more source

Mechanochemical Hydrodeoxygenations

European Journal of Organic Chemistry, Volume 29, Issue 22, 9 June 2026.
A silver‐catalyzed mechanochemical hydrodeoxygenation with triethylsilane as reductant allows to convert ketones to the corresponding methylene derivatives in good yields after a short reaction time. Selected examples show that also alcohols, ethers, and sulfoxides can react. In this work, a mechanochemical hydrodeoxygenation (HDO) was developed. Using
Lena M. Hanek, Carsten Bolm
wiley   +1 more source

Pre-Activation as a Route for Tuning the Kinetics of Mechanochemical Transformations. [PDF]

Angew Chem Int Ed Engl
Heinekamp C, Palmer TM, Al-Sabbagh D, May A, Prinz C, Michalik S, Michalchuk AAL, Emmerling F.   +7 more
europepmc   +1 more source

Silent Partners in the Mill: Unveiling the Role of Additives in Mechanochemical Synthesis. [PDF]

Chemistry
Breinsperger J, Podlesnik N, Mele F, Schnürch M.   +3 more
europepmc   +1 more source

Mechanically Assisted PO, PN, and PS Bonds Formation

Advanced Synthesis &Catalysis, Volume 368, Issue 11, 3 June 2026.
We present a general mechanochemical strategy for constructing PO, PN, and PS bonds via solvent‐free reactions of phosphoryl chlorides with O‐, N‐, and S‐nucleophiles. The method operates under mild conditions, shows broad substrate scope, and affords phosphates, phosphoramidates, and thiophosphates efficiently, providing a sustainable platform for ...
Camilo Morales‐Manrique, Mónica Rey‐Montaño, Daniela Torres‐Ruiz, Carlos Bermudez‐Gonzalez, Diego Gamba‐Sánchez   +4 more
wiley   +1 more source

Amorphous-to-crystalline transformation: a mechanochemical pathway to imine-linked covalent organic frameworks.

RSC Mechanochem
Brown N, Nailwal Y, Blair T, Alsudairy Z, Zhang Q, Kennedy K, Liu Y, Li X.   +7 more
europepmc   +1 more source