Mechanochemical synthesis of NaNbO3, KNbO3 and K0.5Na0.5NbO3 [PDF]
Mechanochemical synthesis of the K0.5Na0.5NbO3 solid solution (KNN) is studied. In order to explore the mechanochemical interactions between the constituents in the Na2CO3 - K2CO3 - Nb2O5 system, NaNbO3 and KNbO3 as the boundary compositions of the KNN ...
Rojac T., Kosec M., Malič B., Holc J.
doaj +3 more sources
Extending mechanochemical porphyrin synthesis to bulkier aromatics: tetramesitylporphyrin [PDF]
Aldehydes with bulky substituents in the ortho-positions have been historically difficult in porphyrin synthesis, presumably owing to steric hindrance around the reactive site.
Qiwen Su, Tamara D. Hamilton
doaj +2 more sources
Mechanochemical synthesis of inverse vulcanized polymers. [PDF]
Inverse vulcanization, a sustainable platform, can transform an industrial by-product, sulfur, into polymers with broad green applications such as heavy metal capture and recyclable materials. However, the process usually requires high temperatures (≥159
Yan P +6 more
europepmc +2 more sources
Mechanistic Insights into a Sustainable Mechanochemical Synthesis of Ettringite [PDF]
Mechanochemistry offers an environmentally benign and facile synthesis method for a variety of cement paste constituents. In addition, these methods can be used to selectively tune the properties of cement components.
Dr. Julia Stroh +4 more
doaj +2 more sources
Mechanochemical Suzuki polymerization for the synthesis of polyfluorenes [PDF]
Herein are reported the syntheses of poly(9,9-di-n-octylfluorenyl-2,7-diyl) (PF), poly(9,9-dioctylfluorene-alt-benzothiadiazole) (PFBT), and poly[(9,9-bis(3′-(N,N-dimethylamino)propyl)-2,7-fluorene)-alt-2,7-(9,9-dioctylfluorene)] (PFN) by employing ...
L. P. Tharika Nirmani +2 more
doaj +2 more sources
Activity enhancement of carbon nanofiber-based catalysts for CO2 methanation by mechanochemical synthesis [PDF]
Carbon nanofibers (CNFs) modified with CeO2 were employed as support for the synthesis of Ni catalysts for the CO2 methanation reaction. Two different preparation methods were investigated: incipient wetness impregnation and mechanochemical synthesis ...
Christian Di Stasi +5 more
doaj +2 more sources
Mechanochemical Synthesis of Fluorinated Imines [PDF]
A number of imines, including 12 new compounds, previously not reported in the literature, derived from variously fluorinated benzaldehydes and different anilines or chiral benzylamines were synthesized by a solvent-free mechanochemical method, which was
Karolina Ciesielska +3 more
doaj +2 more sources
Mechanochemical synthesis of PZT powders [PDF]
PZT ceramic powders were successfully prepared from the mixture of PbO, ZrO2 and TiO2 by mechanochemical synthesis in a planetary ball mill, under different milling conditions. Phase evolution during synthesis was monitored by X-ray diffraction analysis.
Z Brankovic, G Brankovic, M Cilense
exaly +2 more sources
Mechanochemical synthesis of fluoride-ion conducting glass and glass–ceramic in ZrF4–BaF2 binary system [PDF]
Fluoride glasses in the binary system ZrF4–BaF2 were prepared via mechanochemical treatment. The glass-forming region of the ZrF4–BaF2 system obtained using the mechanochemical method was wider than that obtained using the conventional melt-quenching ...
Kota Motohashi +5 more
doaj +2 more sources
The mechanochemical synthesis of polymers. [PDF]
Mechanochemistry – the utilization of mechanical forces to induce chemical reactions – is a rarely considered tool for polymer synthesis. It offers numerous advantages such as reduced solvent consumption, accessibility of novel structures, and the ...
Krusenbaum A +4 more
europepmc +2 more sources

