Modification of kitchen blenders into controllable laboratory mixers for mechanochemical synthesis of atomically thin materials [PDF]
, 2023 Graphene and related two-dimensional materials (2DMs) have shown promise across numerous technology areas including flexible electronics, energy storage and pollution remediation. Research into novel applications of these atomically thin materials relies
Jason, Stafford +2 more
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Mechanochemical Synthesis of Aspirin [PDF]
, 2022 Aspirin is one of the most popular pain reliever and anti-inflammatory drug used around the globe. In 1899, acetylsalicylic acid was patented as aspirin by Bayer pharmaceutical company. It is estimated that 40,000 metric tons aspirin being consumed each
Halim, Mohammad A. +1 more
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Mechanochemical Synthesis of Primary Amides [PDF]
The Journal of Organic Chemistry, 2021 Ball milling of aromatic, heteroaromatic, vinylic, and aliphatic esters with ethanol and calcium nitride afforded the corresponding primary amides in a transformation that was compatible with a variety of functional groups and maintained the integrity of a stereocenter α to carbonyl.
Jorge Gómez-Carpintero +3 more
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The mechanochemical synthesis of polymers
Chemical Society Reviews, 2022 Mechanochemistry enables solvent-free syntheses of even novel polymer structures without the need of monomer solubility.
Annika Krusenbaum +4 more
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Insights into the Mechanochemical Synthesis of MOF-74 [PDF]
Crystal Growth & Design, 2021 Mechanochemical synthesis has recently emerged as a scalable "green" approach for the preparation of MOFs, but current understanding of the underlying reaction mechanisms is limited. In this work, an investigation of the reaction pathway of the mechanochemical synthesis of MOF-74 from ZnO and 2,5-dihydroxyterephthalic acid (H4HDTA), using DMF as a ...
Jethro Beamish-Cook +3 more
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Mechanochemical Transformation of Planar Polyarene to Curved Fused-Ring System: Solid-Phase Synthesis of Corannulene [PDF]
, 2021 This work demonstrates that mechanochemical forces can successfully transform a planarpolyarene into a curved geometry by creating new C-C bonds along the rim of the molecular structure.In doing so, mechanochemistry does not require inert conditions or ...
Gabor, Báti +3 more
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Mechanochemical Synthesis of Extended Iptycenes [PDF]
Journal of the American Chemical Society, 2016 Iptycenes are intriguing compounds receiving considerable attention as a result of their rigid noncompliant three-dimensional architecture. The preparation of larger iptycenes is often problematic, as a result of their limited solubility and synthetic procedures involving multiple Diels-Alder reactions under harsh extended reaction conditions.
Zhao, Yanchuan +2 more
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Mechanochemical Synthesis of Mixed Metal, Mixed Linker GlassForming Metal–Organic Frameworks [PDF]
, 2020 Current methodologies to produce glass forming metal–organic frameworks (MOFs) rely on non-scalable solvothermal syntheses which have high energy requirements, relatively low yields and large tetratogenic solvent usage.
Alice, Bumstead +4 more
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Mechanochemical solid state synthesis of a bifunctional copper(I)/N-heterocyclic carbene complex and its catalytic activity in hydrogenative transformations [PDF]
, 2021 A sophisticated bifunctional catalyst bearing a copper(I)/N-heterocyclic carbene and a guanidine organocatalyst has been prepared by a mechanochemical synthesis in a ball mill.
Birte, Zimmermann +4 more
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Mechanochemistry: A Green Approach in the Preparation of Pharmaceutical Cocrystals
Pharmaceutics, 2021 Mechanochemistry is considered an alternative attractive greener approach to prepare diverse molecular compounds and has become an important synthetic tool in different fields (e.g., physics, chemistry, and material science) since is considered an ...
Mizraín Solares-Briones +8 more
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