Mechanochemical Suzuki polymerization for the synthesis of polyfluorenes
Green Chemistry Letters and Reviews, 2022 Herein are reported the syntheses of poly(9,9-di-n-octylfluorenyl-2,7-diyl) (PF), poly(9,9-dioctylfluorene-alt-benzothiadiazole) (PFBT), and poly[(9,9-bis(3′-(N,N-dimethylamino)propyl)-2,7-fluorene)-alt-2,7-(9,9-dioctylfluorene)] (PFN) by employing ...
L. P. Tharika Nirmani +2 more
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Magnetochemistry, 2020 The effects of mechanochemical synthesis and postsynthetic grinding on the spin crossover material [Fe(atrz)3](BF4)2 was examined in detail using a combination of X-ray diffraction, magnetometry, EXAFS and TEM.
Jed H. Askew +4 more
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Extending mechanochemical porphyrin synthesis to bulkier aromatics: tetramesitylporphyrin
Beilstein Journal of Organic Chemistry, 2019 Aldehydes with bulky substituents in the ortho-positions have been historically difficult in porphyrin synthesis, presumably owing to steric hindrance around the reactive site.
Qiwen Su, Tamara D. Hamilton
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Mechanistic Insights into a Sustainable Mechanochemical Synthesis of Ettringite
ChemistryOpen, 2019 Mechanochemistry offers an environmentally benign and facile synthesis method for a variety of cement paste constituents. In addition, these methods can be used to selectively tune the properties of cement components.
Dr. Julia Stroh +4 more
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Preparation of powder coatings on the surface of steel balls by mechanochemical synthesis
Қарағанды университетінің хабаршысы. Физика сериясы, 2020 This work presents the results of the study of tribological and corrosion properties of powder coatings based on VN, TiN, SiC and Cr2N obtained by mechanochemical synthesis on the surface of steel balls ShKh15.
Б.К. Рахадилов +4 more
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Fast synthesis of the polycrystalline materials on the base of Zn 3 V2 MoO11 and Zn 2.5 VMoO8 [PDF]
Processing and Application of Ceramics, 2009 In our study we applied two different techniques for the preparation of Zn3V2MoO11 and Zn2.5VMoO8 polycrystalline materials - melt quenching method (up-bottom) and mechanochemical synthesis (bottom- up).
Maya Markova-Velichkova, Reni Iordanova
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Mechanochemistry vs Conventional Solid-State Synthesis: A Sustainable Development Pathway [PDF]
MATEC Web of ConferencesThe shift to sustainable chemical manufacturing highlights the need for solid-state synthesis methods that minimize solvent use, energy consumption and environmental impact.
Chen Yinuo
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Mechanochemical activation of batch during fabrication of highly-porous cordierite materials based on natural oxide compounds [PDF]
Science of Sintering, 2006 Using X-ray diffraction analysis and infrared spectroscopy techniques, the effect of additives on phase composition variation during mechanochemical activation of a kaolin-containing cordierite batch was investigated.
Antsiferov V.N. +2 more
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Mechanochemical synthesis of an elusive fluorinated polyacetylene
Nature Chemistry, 2019 Polymer mechanochemistry has traditionally been employed to study the effects of mechanical force on one or two chemical bonds within a polymer. It is underexploited for the scalable synthesis of wholly new materials by activating bonds along the entire polymer, especially products inaccessible by other means. Herein we utilize polymer mechanochemistry
Benjamin R. Boswell +9 more
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Mechanochemical synthesis of poly(trimethylene carbonate)s: an example of rate acceleration
Beilstein Journal of Organic Chemistry, 2019 Mechanochemical polymerization is a rapidly growing area and a number of polymeric materials can now be obtained through green mechanochemical synthesis.
Sora Park, Jeung Gon Kim
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