Mechanochemical Suzuki polymerization for the synthesis of polyfluorenes
Herein are reported the syntheses of poly(9,9-di-n-octylfluorenyl-2,7-diyl) (PF), poly(9,9-dioctylfluorene-alt-benzothiadiazole) (PFBT), and poly[(9,9-bis(3′-(N,N-dimethylamino)propyl)-2,7-fluorene)-alt-2,7-(9,9-dioctylfluorene)] (PFN) by employing ...
L. P. Tharika Nirmani +2 more
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The Mechanochemical Fries Rearrangement: Manipulating Isomer Ratios in the Synthesis of p-Hydroxyacetophenone at Different Scales [PDF]
Here, we present the first mechanochemical Fries rearrangement for the industrially important synthesis of para hydroxyacetophenone, inside a ball mill and a twin-screw extruder.
Viktoria, Pietryga +5 more
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The effects of mechanochemical synthesis and postsynthetic grinding on the spin crossover material [Fe(atrz)3](BF4)2 was examined in detail using a combination of X-ray diffraction, magnetometry, EXAFS and TEM.
Jed H. Askew +4 more
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Mechanochemical Synthesis of Phosphonate-based Proton Conducting Metal Organic Frameworks [PDF]
The rational design of new type of water stable metal–organic frameworks (MOFs) as promising proton-conductors has attracted great attention owing to their applications in proton-exchange membrane fuel cells (PEMFC). Herein, we report the mechanochemical
Franziska , Emmerling +3 more
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Mechanochemical Synthesis of Boroxine-linked Covalent Organic Frameworks [PDF]
We report a rapid, room-temperature mechanochemical synthesis of 2- and 3-dimensional boroxine covalent organic frameworks (COFs), enabled by using trimethylboroxine as a dehydrating additive to overcome the hydrolytic sensitivity of boroxine-based COFs.
Xavier, Ottenwaelder +6 more
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Mechanochemical Synthesis of Zero-Dimensional Metal Halide Perovskites
In this work, we directly demonstrate solid-state synthesis of zero-dimensional metal halide perovskites by mechanochemical synthesis. Three representative zero-dimensional perovskites, Cs4PbBr6, Cs2SnBr6, and Cs3Cu2I5, were synthesized with high purity ...
Lee, Takhee +5 more
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Optimization of the mechanochemical synthesis of several distinct compounds. [PDF]
Mechanochemical synthesis, as used in this work, is the mechanical milling of reagents to drive reaction. It is often considered a greener alternative to traditional solution-based methods of synthesis.
Williams, Joseph Ryan
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Mechanistic Insights into a Sustainable Mechanochemical Synthesis of Ettringite
Mechanochemistry offers an environmentally benign and facile synthesis method for a variety of cement paste constituents. In addition, these methods can be used to selectively tune the properties of cement components.
Dr. Julia Stroh +4 more
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Preparation of powder coatings on the surface of steel balls by mechanochemical synthesis
This work presents the results of the study of tribological and corrosion properties of powder coatings based on VN, TiN, SiC and Cr2N obtained by mechanochemical synthesis on the surface of steel balls ShKh15.
Б.К. Рахадилов +4 more
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Fast synthesis of the polycrystalline materials on the base of Zn 3 V2 MoO11 and Zn 2.5 VMoO8 [PDF]
In our study we applied two different techniques for the preparation of Zn3V2MoO11 and Zn2.5VMoO8 polycrystalline materials - melt quenching method (up-bottom) and mechanochemical synthesis (bottom- up).
Maya Markova-Velichkova, Reni Iordanova
doaj

