Results 61 to 70 of about 10,921 (198)

Tuning Amorphous‐Crystalline Catalytic Interfaces by Mechanochemistry: Cu‐Based Metallic Glasses Coupled with Ceria for CO Oxidation

open access: yesAdvanced Materials, EarlyView.
Ball‐milling Cu‐based metallic glasses with ceria creates a unique nanostructure where metallic glass particles are wrapped by CeO2 nanoparticles. The intimate integration triggers copper state reorganization during reaction and aging, boosting CO oxidation and COPrOx activity.
Maahin Mirzay‐Shahim   +17 more
wiley   +1 more source

The Dynamic Energy Band Model of Contact‐Separation and Sliding Mode Triboelectric Charging of Polymers at the Metal‐Polymer Interface

open access: yesAdvanced Science, EarlyView.
Triboelectric charge generation at polymer‐metal interfaces arises from the interplay of intra‐ and inter transformation reactions of mechanochemically generated species, physical properties of polymers, environmental conditions. The direction and the magnitude of electron transfer between metal and polymer are dynamically governed by the relative ...
Sunay Dilara Ekim   +4 more
wiley   +1 more source

Mechanochemical modification of the composition and structure of plant raw materials to control the combustion of alternative fuel

open access: yesMATEC Web of Conferences, 2017
The possibilities of mechanochemistry in processing of renewable lignocellulose raw material into solid kinds of biofuel are demonstrated in this work. A review of lignocellulose raw materials promising for our country is presented.
Bychkov Aleksey   +4 more
doaj   +1 more source

Plasticity of hydrogen bond networks regulates mechanochemistry of cell adhesion complexes

open access: yes, 2014
Mechanical forces acting on cell adhesion receptor proteins regulate a range of cellular functions by formation and rupture of non-covalent interactions with ligands.
Chakrabarti, Shaon   +2 more
core   +1 more source

Mechanistic and kinetic insight into spontaneous cocrystallisation of isoniazid and benzoic acid [PDF]

open access: yes, 2015
Solid-state cocrystallisation is of contemporary interest, because it offers an easy and efficient way to produce cocrystals, which are recognized as prospective pharmaceutical materials.
Fabian, Laszlo   +5 more
core   +1 more source

Modular Generation of Alkyl Selenyl Radicals for the Synthesis of Alkyl Selenides via a Mechanochemical Approach

open access: yesAdvanced Science, EarlyView.
We present a mechanochemical, radical‐mediated hydroselenation of alkenes under ambient conditions. This method modularly generates alkyl selenyl radicals from elemental selenium and alkyl (pseudo)halides, utilizing PhSiH3 and H2O as hydrogen atom donors, with the water likely originating from the air and/or trace water present in the reagents ...
Xiaochun He   +8 more
wiley   +1 more source

Mechanochemistry: Fundamental Principles and Applications

open access: yesAdvanced Science
Mechanochemistry is an emerging research field at the interface of physics, mechanics, materials science, and chemistry. Complementary to traditional activation methods in chemistry, such as heat, electricity, and light, mechanochemistry focuses on the ...
Liang Dong   +4 more
doaj   +1 more source

Mechanochemistry of the kinesin-1 ATPase [PDF]

open access: yes, 2016
Kinesins are P-loop NTPases that can do mechanical work. Like small G-proteins, to which they are related, kinesins execute a program of active site conformational changes that cleaves the terminal phosphate from an NTP substrate.
Cross, R. A.
core   +1 more source

Mechanochemical activation of zinc and application to Negishi cross-coupling [PDF]

open access: yes, 2018
A form independent activation of zinc, concomitant generation of organozinc species and engagement in a Negishi cross‐coupling reaction via mechanochemical methods is reported.
Browne, Duncan L.   +3 more
core   +4 more sources

A Mechanochemical Kolbe–Schmitt Reaction: Catechol Carboxylation Provides Building Blocks for Renewable Plasticizers

open access: yesAngewandte Chemie, Volume 138, Issue 12, 16 March 2026.
A mechanochemical Kolbe–Schmitt reaction of disodium catecholate enables the synthesis of mono‐ and dicarboxylated catechols at low temperature and CO2 pressure. Directly derivatizing the resulting carboxylic acid and phenolic moieties in the obtained mixture provides plasticizer blends with efficiencies competitive to commercial benchmarks.
Dries De Vos   +9 more
wiley   +2 more sources

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