Results 61 to 70 of about 596,435 (207)

Bioorthogonal metal-free click-ligation of cRGD-pentapeptide to alginate [PDF]

open access: yes, 2012
Click reactions have become very common and powerful ligation techniques, of which 1,3-dipolar cycloadditions have most frequently been employed. Since metal-mediated cycloadditions are incompatible in biomedical applications due to toxicity issues ...
Dräger, Gerald   +2 more
core   +2 more sources

3D graphene paper-based tandem metal-free thin-film supercapacitors with integrated 200 V output

open access: yesInternational Journal of Extreme Manufacturing
The development of high-voltage tandem thin-film supercapacitors (TFSCs) has been limited by the issues such as expensive electrode materials, indispensable commercial separators and metal current collectors, and complex manufacturing processes.
Huilong Liu   +9 more
doaj   +1 more source

Gravitational fragmentation in turbulent primordial gas and the initial mass function of Population III stars [PDF]

open access: yes, 2010
We report results from numerical simulations of star formation in the early universe that focus on the dynamical behavior of metal-free gas under different initial and environmental conditions.
Bromm, Volker   +3 more
core   +2 more sources

METAL FREE PROSTHODONTICS

open access: yesannals and essences of dentistry, 2011
Metal free or All –ceramic restorations are the term for restorations consisting solely of ceramics without any metal support. They are highly esthetic.
openaire   +1 more source

Covalent Organic Frameworks with Molecular Electronic Modulation as Metal‐Free Electrocatalysts for Efficient Hydrogen Peroxide Production

open access: yesSmall Structures, 2023
Tuning the electronic property of active center to balance the adsorption ability and reactivity of oxygen is essential for achieving 2e− oxygen reduction reaction (ORR) for electrocatalytic synthesis of hydrogen peroxide (H2O2), still represents a grand
Shaoda Huang   +9 more
doaj   +1 more source

Metal‐Free Intermolecular Aminoarylation of Alkynes

open access: yesAngewandte Chemie, 2017
AbstractA metal‐free aminoarylation of internal alkynes is described, yielding tetrasubstituted enaminoates. The transformation proceeds in good to excellent yields through a tandem conjugate addition/Smiles rearrangement involving aryl and heteroaryl sulfonamides.
Pauline T. G. Rabet   +2 more
openaire   +4 more sources

Metal-Free Flat Lens Using Negative Refraction by Nonlinear Four-wave Mixing

open access: yes, 2014
A perfect lens with unlimited resolution has always posed a challenge to both theoretical and experimental physicists. Recent developments in optical meta-materials promise an attractive approach towards perfect lenses using negative refraction to ...
Cao, Jianjun   +4 more
core   +1 more source

DABCO- and DBU-promoted one-pot reaction of N-sulfonyl ketimines with Morita–Baylis–Hillman carbonates: a sequential approach to (2-hydroxyaryl)nicotinate derivatives

open access: yesBeilstein Journal of Organic Chemistry, 2018
An intriguing DABCO-catalyzed and DBU-promoted one-pot synthesis of an important class of (2-hydroxyaryl)pyridine derivatives bearing a carboxylate or a nitrile group suitably placed at C3 position of the aza-ring has been achieved in acceptable chemical
Soumitra Guin   +3 more
doaj   +1 more source

Sustainable, Oxidative, and Metal‐Free Annulation

open access: yesChemistry – A European Journal, 2017
AbstractAnnulation has received steadily growing interest in the interplay with the increasing emphasis towards selective C−H bond functionalization reactions. Metal‐free oxidative annulation through functionalization of inert and abundant C−H bonds offers great improvements in terms of atom‐ and step‐economics as well as reduced waste production under
Luis Bering   +2 more
openaire   +4 more sources

Persulfate-Promoted Carbamoylation/Cyclization of Alkenes: Synthesis of Amide-Containing Quinazolinones

open access: yesMolecules
The incorporation of amide groups into biologically active molecules has been proven to be an efficient strategy for drug design and discovery. In this study, we present a simple and practical method for the synthesis of amide-containing quinazolin-4(3H)-
Jia-Jun Tang   +4 more
doaj   +1 more source

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