Results 81 to 90 of about 4,159,820 (313)

Columbus Free Press subscription letter [PDF]

open access: yes, 1990
Form letter encouraging subscription to and financial support for the Columbus Free Press, dated January 1990 as the publication was celebrating its 20th anniversary. The Columbus Free Press began as a bi-weekly publication in Columbus, Ohio, in 1970.
Columbus Free Press (Publisher)
core  

Metal- and Hydride-Free Pentannulative Reductive Aldol Reaction [PDF]

open access: yes, 2018
Traditionally, the reductive aldol reaction is a metal-catalyzed and hydride-promoted coupling between enones and aldehydes. We present a phosphine-mediated diastereoselective intramolecular reductive aldol reaction of α-substituted dienones and ...
Lona Dutta (6083462)   +2 more
core   +1 more source

DABCO- and DBU-promoted one-pot reaction of N-sulfonyl ketimines with Morita–Baylis–Hillman carbonates: a sequential approach to (2-hydroxyaryl)nicotinate derivatives

open access: yesBeilstein Journal of Organic Chemistry, 2018
An intriguing DABCO-catalyzed and DBU-promoted one-pot synthesis of an important class of (2-hydroxyaryl)pyridine derivatives bearing a carboxylate or a nitrile group suitably placed at C3 position of the aza-ring has been achieved in acceptable chemical
Soumitra Guin   +3 more
doaj   +1 more source

Covalent Organic Frameworks with Molecular Electronic Modulation as Metal‐Free Electrocatalysts for Efficient Hydrogen Peroxide Production

open access: yesSmall Structures, 2023
Tuning the electronic property of active center to balance the adsorption ability and reactivity of oxygen is essential for achieving 2e− oxygen reduction reaction (ORR) for electrocatalytic synthesis of hydrogen peroxide (H2O2), still represents a grand
Shaoda Huang   +9 more
doaj   +1 more source

Metal Free Phosphorus Butterfly Compounds

open access: yesEuropean Journal of Inorganic Chemistry, 2020
AbstractMetal‐free organophosphorus are demanded compounds due to their interesting properties in a variety of applications, spanning from fine to material chemistry. Unfortunately, their synthesis is very challenging, requiring a precise design of the reaction conditions to avoid the conspicuous formation of undesired products.
Franco Scalambra, Antonio Romerosa
openaire   +2 more sources

Evolutionarily divergent DUF4465 domains have a common vitamin B12‐binding function

open access: yesFEBS Open Bio, EarlyView.
We show that DUF4465 family proteins, widespread across bacteria from gut microbiomes, hydrothermal vents, and soil, share a common vitamin B12‐binding function. These augmented β‐jellyroll proteins bind vitamin B12 via extended loops. Our findings establish sequence‐diverse DUF4465 proteins as a widespread class of B12‐binding proteins, highlighting ...
Charlea Clarke   +4 more
wiley   +1 more source

Photochemical Doyle-Kirmse Reaction – a Metal-Free Route to Allenes [PDF]

open access: yes, 2019
This report describes metal-free, blue light-induced [2,3]-sigmatropic rearrangement of sulfonium ylides generated from donor/acceptor diazoalkanes and propargyl sulfides.
Katarzyna, Rybicka-Jasińska   +3 more
core   +1 more source

Persulfate-Promoted Carbamoylation/Cyclization of Alkenes: Synthesis of Amide-Containing Quinazolinones

open access: yesMolecules
The incorporation of amide groups into biologically active molecules has been proven to be an efficient strategy for drug design and discovery. In this study, we present a simple and practical method for the synthesis of amide-containing quinazolin-4(3H)-
Jia-Jun Tang   +4 more
doaj   +1 more source

Metal-free syn-dioxygenation of alkenes [PDF]

open access: yesOrganic & Biomolecular Chemistry, 2013
Reactions employing inexpensive reagents from sustainable sources and with low toxicity are becoming increasingly desirable from an academic and industrial perspective. A fascinating example of a synthetic transformation that requires development of alternative procedures is the osmium catalysed dihydroxylation.
Rawling, Michael, Tomkinson, Nick
openaire   +5 more sources

Mass spectrometry based identification of AMP‐O‐Tris generated by Thermococcus onnurineus Cas10

open access: yesFEBS Open Bio, EarlyView.
Isolated Thermococcus onnurineus Cas10 generates the noncanonical ATP‐derived product AMP‐O‐Tris while in Tris‐containing buffer as identified via mass spectrometry, revealing relaxed nucleophile selectivity under isolated conditions. These findings suggest that multiprotein Csm complex assembly restricts Cas10 reactivity toward canonical cyclic ...
Su‐Jin Lee   +6 more
wiley   +1 more source

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