Results 51 to 60 of about 410,888 (329)

On the intrinsic dynamic nature of the rigid UiO-66 metal-organic framework [PDF]

open access: yes, 2018
UiO-66 is a showcase example of an extremely stable metal-organic framework, which maintains its structural integrity during activation processes such as linker exchange and dehydration.
Caratelli, Chiara   +6 more
core   +2 more sources

Selective nitrogen adsorption via backbonding in a metal-organic framework with exposed vanadium sites. [PDF]

open access: yes, 2020
Industrial processes prominently feature π-acidic gases, and an adsorbent capable of selectively interacting with these molecules could enable important chemical separations1-4.
Colombo, Valentina   +12 more
core   +3 more sources

Origamic metal-organic framework toward mechanical metamaterial

open access: yesNature Communications, 2023
Origami, known as paper folding has become a fascinating research topic recently. Origami-inspired materials often establish mechanical properties that are difficult to achieve in conventional materials.
Eunji Jin   +10 more
doaj   +1 more source

Diffusion of Small Molecules in Metal Organic Framework Materials

open access: yes, 2012
Ab initio simulations are combined with in situ infrared spectroscopy to unveil the molecular transport of H$_2$, CO$_2$, and H$_2$O in the metal organic framework MOF-74-Mg.
Canepa, Pieremanuele   +3 more
core   +1 more source

Synthesis and characterization of ZnBTC-based MOFs: effect of solvents and salt

open access: yesChimica Techno Acta, 2022
In this work, we studied the optimization of synthetic approaches to creating structurally modified metal-organic frameworks under various synthesis conditions.
Maria V. Timofeeva, Andrey N. Yankin
doaj   +1 more source

Mapping the evolution of mitochondrial complex I through structural variation

open access: yesFEBS Letters, EarlyView.
Respiratory complex I (CI) is crucial for bioenergetic metabolism in many prokaryotes and eukaryotes. It is composed of a conserved set of core subunits and additional accessory subunits that vary depending on the organism. Here, we categorize CI subunits from available structures to map the evolution of CI across eukaryotes. Respiratory complex I (CI)
Dong‐Woo Shin   +2 more
wiley   +1 more source

Magnetoelastic coupling in the cobalt adipate metal-organic framework from quasi-harmonic lattice dynamics [PDF]

open access: yes, 2015
Magnetic interactions in hybrid materials are poorly understood compared to those in purely inorganic materials. The high flexibility of many metal-organic systems introduces a strong temperature dependence of the magnetic exchange interactions owing to ...
Canepa   +23 more
core   +2 more sources

Flexible metal–organic frameworks

open access: yesChem. Soc. Rev., 2014
Advances in flexible and functional metal-organic frameworks (MOFs), also called soft porous crystals, are reviewed by covering the literature of the five years period 2009-2013 with reference to the early pertinent work since the late 1990s. Flexible MOFs combine the crystalline order of the underlying coordination network with cooperative structural ...
Schneemann, Andreas   +5 more
openaire   +4 more sources

By dawn or dusk—how circadian timing rewrites bacterial infection outcomes

open access: yesFEBS Letters, EarlyView.
The circadian clock shapes immune function, yet its influence on infection outcomes is only beginning to be understood. This review highlights how circadian timing alters host responses to the bacterial pathogens Salmonella enterica, Listeria monocytogenes, and Streptococcus pneumoniae revealing that the effectiveness of immune defense depends not only
Devons Mo   +2 more
wiley   +1 more source

Selective gas capture via kinetic trapping

open access: yes, 2016
Conventional approaches to the capture of CO_2 by metal-organic frameworks focus on equilibrium conditions, and frameworks that contain little CO_2 in equilibrium are often rejected as carbon-capture materials. Here we use a statistical mechanical model,
Kundu, Joyjit   +3 more
core   +1 more source

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