Results 201 to 210 of about 21,892 (259)
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Alkali-metal alkylberyllium alkoxides
Journal of the Chemical Society, Dalton Transactions, 1974Three series of alkali-metal t-butoxyberyllate complexes are described, including MBe(OBut)3(M = Li, Na, K, Rb, or Cs), [MEtBe(OBut)2]2(M = Li or Na), and [MEt2Be(OBut)]2(M = Na or K). The series MBe(OBut)3 is formed from MOBut and Be(OBut)2, from Na2BeH4 and ButOH, or from K and Be(OBut)2 in ButOH.
Richard A. Andersen, Geoffrey E. Coates
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Metal oxide alkoxide (trialkylsilyloxide) polymers
Coordination Chemistry Reviews, 1967openaire +3 more sources
COORDINATION COMPLEXES OF METAL ALKOXIDES: PART I. METAL ALKOXIDE – HYDRAZINE COMPLEXES
Canadian Journal of Chemistry, 1962The field of metal alkoxide coordination compounds is surveyed briefly. The preparation of moderately stable complexes of hydrazine with aluminum isopropoxide, titanium ethoxide, titanium isopropoxide, and zirconium isopropoxide is described. Some reactions of these new complexes are reported.
M. S. Bains, D. C. Bradley
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COORDINATION COMPLEXES OF METAL ALKOXIDES: PART II. METAL ALKOXIDE – ETHYLENEDIAMINE COMPLEXES
Canadian Journal of Chemistry, 1962Some complexes of titanium isopropoxide, titanium ethoxide, aluminum isopropoxide, tantalum isopropoxide, and zirconium isopropoxide with ethylenediamine (en) are described. Two complexes of titanium isopropoxide with ethylenediamine, i.e. Ti(OPri)4,en and Ti2(OPri)8,en, were established by cryoscopic, X-ray powder photograph, and phase rule studies ...
M. S. Bains, D. C. Bradley
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Spermine adducts of metal alkoxides
Monatshefte für Chemie - Chemical Monthly, 2012Reaction of spermine with M(OiPr)4 (M = Ti, Zr) in toluene solution results in the formation of crystalline coordination polymers [M2(OiPr)8(C10H26N4)]∞. In these compounds, only the terminal primary amino groups are coordinated to the metal centers. The adducts are stabilized by intramolecular hydrogen bonds.
Stefan O. Baumann +4 more
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Metal-Oxygen-Metal' Ring Formation in Metal Alkoxide Systems
Phosphorus, Sulfur, and Silicon and the Related Elements, 1997Salient features of the work carried out during the last few years on the alkoxide ring systems with chelating alcohols such as alkoxyalcohols, aminoalcohols, phosphino alcohols, glycols as well as monofunctional alcohols, are discussed.
Ram Mehrotra, Anirudh Singh
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Nature, 1965
THE polymeric co-ordination compounds are important in inorganic chemistry. Structural studies of these compounds have recently revealed the presence of cyclic and macromolecular1 structural types, which previously were counted as the distinguishing features of organic chemistry.
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THE polymeric co-ordination compounds are important in inorganic chemistry. Structural studies of these compounds have recently revealed the presence of cyclic and macromolecular1 structural types, which previously were counted as the distinguishing features of organic chemistry.
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Pyrolysis of metal alkoxides. I. Thermal stability of some zirconium alkoxides
Journal of Applied Chemistry, 1959AbstractThe thermal stabilities of Zr(OEt)4, Zr(OPrf)4, Zr(OBut)4 and Zr(OC5H11‐tert.)4 have been studied in an all‐glass apparatus under constant pressure at various temperatures and pressures. Most work was carried out on the tertiary alkoxides and these exhibited an induction period which was very sensitive to traces of oxygen or the products of ...
D. C. Bradley, M. M. Faktor
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