Results 11 to 20 of about 9,360 (305)
Metal Preferences and Metallation [PDF]
The metal binding preferences of most metalloproteins do not match their metal requirements. Thus, metallation of an estimated 30% of metalloenzymes is aided by metal delivery systems, with ∼ 25% acquiring preassembled metal cofactors. The remaining ∼ 70% are presumed to compete for metals from buffered metal pools.
Foster, Andrew W. +2 more
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Metal–metal bonded compounds and metal clusters [PDF]
Preface.
Falvello, Larry R., Murillo, Carlos A.
openaire +2 more sources
Mechanically interlocked molecules (MIMs) possess unique architectures and non-traditional degrees of freedom that arise from well-defined topologies that are achieved through precise mechanical bonding.
Nathan D., Colley +6 more
core +1 more source
Skeletal Metalation of Lactams through Carbonyl-to-Nickel Exchange Logic
Classical metalation reactions such as the metal-halogen exchange are powerful tools to construct chemical bonds between two molecules. An analogous metal-carbon exchange strategy would provide a new entry into the direct structural remodeling of core ...
Patrick , Finkelstein +7 more
core +1 more source
Metal to Orthogonal Metal Transition* [PDF]
Orthogonal metal is a new quantum metallic state that conducts electricity but acquires no Fermi surface (FS) or quasiparticles, and hence orthogonal to the established paradigm of Landau’s Fermi-liquid (FL). Such a state may hold the key of understanding the perplexing experimental observations of quantum metals that are beyond FL ...
Chen, Chuang +3 more
openaire +3 more sources
In this study we report an affordable synthesis and preparation of an electrochemically exfoliated few-layer 2-dimensional (2D) SnS2 anode material of high cycling durability and demonstrate its performance on the example of alkali metal batteries.
Mariusz Radtke, Christian Hess
doaj +1 more source
Exploration of Bis(nickelation) of 1,1′-Bis(o-carborane)
The metalation of [Tl]2[1-(1′-3′,1′,2′-closo-TlC2B9H10)-3,1,2-closo-TlC2B9H10], with the smaller {Ni(dmpe)} fragment sourced from [Ni(dmpe)Cl2], is explored. The bis(metalated) products are obtained as a diastereoisomeric mixture.
Dipendu Mandal, Georgina M. Rosair
doaj +1 more source
Asymmetric synthesis of 2-substituted oxetan-3-ones via metalated SAMP/RAMP hydrazones [PDF]
2-Substituted oxetan-3-ones can be prepared in good yields and enantioselectivities (up to 84% ee) by the metalation of the SAMP/RAMP hydrazones of oxetan-3-one, followed by reaction with a range of electrophiles that include alkyl, allyl, and benzyl ...
Geden, Joanna V. +3 more
core +1 more source
The synthesis and characterization of two bulky ferrocenyl-functionalized amidinates and their lithium, potassium, rhodium(I), and iridium(I) complexes are reported. The ferrocenyl mono(amidine) [Fc{C(NDipp)(NHDipp)}] (1) (Fc = ferrocenyl; Dipp = 2,
Frank Breher (1842994) +9 more
core +2 more sources

