Results 51 to 60 of about 699 (152)

All‐Inorganic Polyoxometalates Act as Superchaotropic Membrane Carriers

Advanced Materials, Volume 36, Issue 1, January 4, 2024.
Inorganic anions of the polyoxometalate type display a new biological activity: They efficiently transport cationic peptides across lipidic and cellular membranes. This function is related to their superchaotropic nature, resulting in strong and concomitant interactions with peptides and lipids.
Andrea Barba‐Bon, Nadiia I. Gumerova, Elias Tanuhadi, Maryam Ashjari, Yao Chen, Annette Rompel, Werner M. Nau   +6 more
wiley   +1 more source

Isolation of a Nonicosahedral Intermediate in the Isomerization of an Icosahedral Metallacarborane

Angewandte Chemie International Edition in English, 1997
AbstractFor corrigendum see DOI:10.1002/anie ...
Dunn, S, Rosair, G, Thomas, R, Weller, A, Welch, A   +4 more
openaire   +1 more source

Expanding the Range of Bioorthogonal Tags for Multiplex Stimulated Raman Scattering Microscopy. [PDF]

Angew Chem Int Ed Engl, 2023
Murphy N, Tipping WJ, Braddick HJ, Wilson LT, Tomkinson NCO, Faulds K, Graham D, Farràs P.   +7 more
europepmc   +1 more source

The first supraicosahedrai p-block metallacarboranes

, 2002
Reaction of Na2[7,9-C2B10H12] or its C-dimethyl analogue with SnCl2 in THF affords 4,1,6-closo-SnC2B10H12 or 1,6-Me2-4,1,6-closo-SnC2B10H10 respectively, the first 13-vertex metallacarboranes involving p-block metals; spectroscopic, structural and ...
Ellis, David; id_orcid, Rosair, Georgina M., Giles, Barry T., Macgregor, Stuart A., Welch, Alan J., Wilson, Neil Martin, Boyd, Alan Stephen Frank   +6 more
core  

Functional sidearm promoted electron-transfer reactions: A new route to metallacarboranes incorporating the η⁷-arachno-carboranyl ligands

, 2005
Reactions of [nido-(Me2NCH2CH2CH 2)RC2B10H10]-Na2 (R = H, MeOCH2CH2, Me2NCH2CH2) with ZrCl4-(THF)2 or SmI2(THF)x gave unprecedentedly metallacarboranes with η7-arachno-carboranyl ligands, in which the heteroatom-containing pendant sidearms are both ...
Chan, Hoi Shan, Cheung, Mak Shuen, Bi, Siwei, Lin, Zhenyang, Xie, Zuowei   +4 more
core   +1 more source

Functional Sidearm Promoted Electron-Transfer Reactions:  A New Route to Metallacarboranes Incorporating the η⁷-arachno-Carboranyl Ligands

, 2016
Reactions of [nido-(Me2NCH2CH2)RC2B10H10]Na2 (R = H, MeOCH2CH2, Me2NCH2CH2) with ZrCl4(THF)2 or SmI2(THF)x gave unprecedentedly metallacarboranes with η7-arachno-carboranyl ligands, in which the heteroatom-containing pendant sidearms are both ...
Hoi-Shan Chan (2184111), Zhenyang Lin (1463215), Siwei Bi (1692427), Mak-Shuen Cheung (2661019), Zuowei Xie (1425799)   +4 more
core   +2 more sources

Nickel(II) and Palladium(II) Complexes with η⁵:κ¹(N)-Coordinated Dicarbollide Ligands Containing Pendant Pyridine Group. [PDF]

Int J Mol Sci, 2023
Semyonov DK, Stogniy MY, Anufriev SA, Timofeev SV, Suponitsky KY, Sivaev IB.   +5 more
europepmc   +1 more source

Synthesis, structure, and bonding of d0/f(n) metallacarboranes incorporating the η7-carboranyl ligand

, 2000
Treatment of 1,2-(C6H5CH2)2-1,2-C2B10H10 with excess Na or Li metal in THF followed by reaction with MC13 in the presence of excess alkali metal gave novel 13-vertex closo-metallacarboranes {[(C6H5CH2)2C2B10H10]M(THF)}2{Na(THF)3}2·2THF (M = Dy (1), Y (2),
Yang, Q, Xie, Z, Chui, K, Mak, TCW, Lam, Wai Han, Lam, WH, Chui, Kwoli, Mak, Thomas C.W., Lin, Zhenyang, Yang, Qingchuan, Lin, Z, Xie, Zuowei   +11 more
core   +1 more source

Tetracarbon Metallacarboranes 10

, 1981
The preferred structure of 12-vertex, 28-electron (nido) polyhedral cages, which contain two skeletal electrons beyond the 26 required for a regular closo icosahedral system and which have thus far been found in at least seven different structural ...
Maynard, Richard B., Sinn, Ekkehard, Grimes, Russell N.   +2 more
core   +1 more source

Design of HIV Protease Inhibitors Based on Inorganic Polyhedral Metallacarboranes

, 2016
HIV protease (HIV PR) is a primary target for anti-HIV drug design. We have previously identified and characterized substituted metallacarboranes as a new class of HIV protease inhibitors.
Jiří Brynda (1265043), Martin Lepšík (1265016), Petr Cígler (1265037), Václav Šícha (1625518), Pavlína Řezáčová (1265025), Jaromír Plešek (1265022), Jan Konvalinka (273840), Irena Sieglová (2162062), Juraj Sedláček’ (2335384), Pavel Hobza (1279320), Jindřich Fanfrlík (1265010), Vladimír Král (1265013), Milan Kožíšek (1265034), Heike Oberwinkler (146871), Klára Grantz Šašková (1265040), Bohumír Grüner (1265019), Jan Řezáč (1279317), Hans-Georg Kräusslich (1416865), Jana Pokorná (1265031)   +18 more
core   +1 more source