Trimetallaborides as starting points for the syntheses of large metal-rich molecular borides and clusters [PDF]
, 2016 Treatment of an anionic dimanganaborylene complex ([{Cp(CO)2Mn}2B]–) with coinage metal cations stabilized by a very weakly coordinating Lewis base (SMe2) led to the coordination of the incoming metal and subsequent displacement of dimethylsulfide in the
Braunschweig, Holger +7 more
core +1 more source
What Can We Learn from the Crystal Structures of Metallacarboranes?
Crystals, 2017 The determination of the molecular structures of metallacarboranes by X-ray diffraction remains critical to the development of the field, in some cases being the only viable way in which the overall architecture and the isomeric form of the molecule can ...
Alan J. Welch
doaj +1 more source
Water soluble organometallic small molecules as promising antibacterial agents: synthesis, physical–chemical properties and biological evaluation to tackle bacterial infections [PDF]
, 2022 This work was supported by the Spanish Ministerio de Economia y Competitividad (PID2019-106832RB-100, and SAF2017-82261-P grant cofounded by the European Regional Development Fund) and the Generalitat de Catalunya (2017SGR1720). J. A. M.
Bennour, Ines +2 more
core +1 more source
Metallacarboranes: New Synthetic Strategies and Structural Patterns [PDF]
ChemInform, 2006 AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Narayan S. Hosmane, John A. Maguire
openaire +1 more source
Boron clusters (ferrabisdicarbollides) shaping the future as radiosensitizers for multimodal (chemo/radio/PBFR) therapy of glioblastoma [PDF]
, 2022 Glioblastoma multiforme (GBM) is the most common and fatal primary brain tumor, and is highly resistant to conventional radiotherapy and chemotherapy. Therefore, the development of multidrug resistance and tumor recurrence are frequent.
Aguilella, Vicente +3 more
core +1 more source
Metallacarborane‐Based Nanostructures: A Carbon‐Wired Planar Octagon [PDF]
Angewandte Chemie International Edition, 2003 A planar C16B8 octagonal macrocycle that incorporates four identical metallacarborane units, linked by four diethynyl chains, has been prepared from a monomeric cobaltacarborane through a designed multistep synthesis (see picture). The air-stable molecule undergoes stepwise electrochemical reduction in TH F solution to generate tuono-, di-, and ...
Yao, H. +4 more
openaire +4 more sources
Reduction-induced facile isomerisation of metallacarboranes:synthesis and crystallographic characterisation of 4-Cp-4,1,2-closo-CoC2B9H11 [PDF]
, 2015 One-electron reduction of 3-Cp-3,1,2-closo-CoC2B9H11 followed by heating to reflux in DME (b.p. 85 °C) induces isomerisation to 4-Cp-4,1,2-closo-CoC2B9H11.
Man, Wing Y. +2 more
core +1 more source
On the Aqueous Solution Behavior of C-Substituted 3,1,2-Ruthenadicarbadodecaboranes
Inorganics, 2019 3,1,2-Ruthenadicarbadodecaborane complexes bearing the [C2B9H11]2− (dicarbollide) ligand are robust scaffolds, with exceptional thermal and chemical stability. Our previous work has shown that these complexes possess promising anti-tumor activities
Marta Gozzi +3 more
doaj +1 more source
What's Next for First Row Fluorometallacycles?
Angewandte Chemie, Volume 136, Issue 41, October 7, 2024.Key roles for fluorometallacycles in first row metal complex‐catalyzed reactions are summarized and several future prospects identified. Abstract Hydrocarbon‐derived metallacycles have been identified as key intermediates in a host of catalyzed transformations of unsaturated organic substrates.
R. Tom Baker, Loïc P. Mangin
wiley +2 more sources
Enhanced conductivity of sodium versus lithium salts. Sodium metallacarboranes as electrolyte [PDF]
, 2017 [EN] The development of new types of ion conducting materials is one of the most important challenges in the field of energy. Lithium salt polymer electrolytes have been the most convenient, and thus the most widely used in the design of the new ...
Andrio, Andreu +4 more
core +1 more source