Results 21 to 30 of about 699 (152)

A Simple Way to Obtain a Decachloro Derivative of Cobalt Bis(dicarbollide)

open access: yesReactions, 2023
A simple synthetic way to obtain a decachloro derivative of cobalt bis(dicarbollide) has been found. The reaction of cesium salt of cobalt bis(dicarbollide) anion with aluminum chloride in chloroform under reflux conditions results in Cs[3,3′-Co(4,7,8,9 ...
Sergey A. Anufriev   +2 more
doaj   +1 more source

Synthesis and structural studies of metallacarboranes [PDF]

open access: yes, 2015
The properties of some new metallacarboranes are described in this thesis, along with the results of a study to determine structural patterns in compounds published by others.
Scott, Greig
core   +7 more sources

METALLABORANES AND METALLACARBORANES OF s-BLOCK ELEMENTS

open access: yesMain Group Metal Chemistry, 2000
Rana, Geeta   +3 more
doaj   +2 more sources

Blue Emitting Star-Shaped and Octasilsesquioxane-Based Polyanions Bearing Boron Clusters. Photophysical and Thermal Properties

open access: yesMolecules, 2020
High boron content systems were prepared by the peripheral functionalisation of 1,3,5-triphenylbenzene (TPB) and octavinylsilsesquioxane (OVS) with two different anionic boron clusters: closo-dodecaborate (B12) and cobaltabisdicarbollide (COSAN). TPB was
Justo Cabrera-González   +4 more
doaj   +1 more source

Asymmetric synthesis of metallacarboranes using a traceless chiral auxiliary

open access: yes, 2023
An asymmetric synthesis of chiral metallacarboranes using a traceless chiral N-tertbutylsulfinamide auxiliary is reported. Investigations of the stereoselectivity and mechanism of the unprecedented formation of the metallacarboranes with a planar chiral ...
Nie, Yong   +17 more
core   +1 more source

Novel main group metallacarboranes and their adducts - a synthetic and structural study [PDF]

open access: yes, 2009
This thesis describes the synthesis and characterisation of a number of novel main group metallacarboranes and the adducts that they form when treated with Lewis bases. The structures of these species are discussed in detail, focussing in particular on
Abram, Peter D.
core   +7 more sources

Boron Chemistry for Medical Applications

open access: yesMolecules, 2020
Boron compounds now have many applications in a number of fields, including Medicinal Chemistry. Although the uses of boron compounds in pharmacological science have been recognized several decades ago, surprisingly few are found in pharmaceutical drugs.
Fayaz Ali   +2 more
doaj   +1 more source

A Novel Transparent pH Sensor Based on a Nanostructured ITO Electrode Coated with [3,3′-Co(1,2-C2B9H11)2]-Doped Poly(pyrrole)

open access: yesProceedings, 2018
A novel transparent and nanostructured ion-sensitive electrode based on indium tin oxide (ITO) coated with cobaltbis(dicarbollide)-doped poly(pyrrole) (PPy) is presented in this work.
Raquel Pruna   +5 more
doaj   +1 more source

On the Aqueous Solution Behavior of C-Substituted 3,1,2-Ruthenadicarbadodecaboranes

open access: yesInorganics, 2019
3,1,2-Ruthenadicarbadodecaborane complexes bearing the [C2B9H11]2− (dicarbollide) ligand are robust scaffolds, with exceptional thermal and chemical stability. Our previous work has shown that these complexes possess promising anti-tumor activities
Marta Gozzi   +3 more
doaj   +1 more source

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