Metallacarborane Synthons for Molecular Construction—Oligofunctionalization of Cobalt Bis(1,2-dicarbollide) on Boron and Carbon Atoms with Extendable Ligands [PDF]
Molecules, 2023 The exploitation of metallacarboranes’ potential in various fields of research and practical applications requires the availability of convenient and versatile methods for their functionalization with various functional moieties and/or linkers of ...
Krzysztof Śmiałkowski +2 more
doaj +2 more sources
Synthesis of Bis(Carboranyl)amides 1,1′-μ-(CH2NH(O)C(CH2)n-1,2-C2B10H11)2 (n = 0, 1) and Attempt of Synthesis of Gadolinium Bis(Dicarbollide) [PDF]
Molecules, 2021 Bis(carboranyl)amides 1,1′-μ-(CH2NH(O)C(CH2)n-1,2-C2B10H11)2 (n = 0, 1) were prepared by the reactions of the corresponding carboranyl acyl chlorides with ethylenediamine.
Yasunobu Asawa +7 more
doaj +2 more sources
Boron in Diet and Medicine: Mechanisms of Delivery and Detection [PDF]
PharmaceuticalsBoron is a trace element with multifaceted chemical and biological properties that underpin its emerging relevance in human health and medicinal chemistry.
Dorota Bartusik-Aebisher +4 more
doaj +2 more sources
Synthesis of Polyhedral Borane Cluster Fused Heterocycles via Transition Metal Catalyzed B-H Activation [PDF]
Molecules, 2020 Aromatic heterocycles are ubiquitous building blocks in bioactive natural products, pharmaceutical and agrochemical industries. Accordingly, the carborane-fused heterocycles would be potential candidates in drug discovery, nanomaterials ...
Ke Cao +7 more
doaj +2 more sources
Assessment of Carrier-Free Metallacarboranes for Targeted Radiation Therapies PBFT and BNCT: Comparative Cellular Effects and Dosimetry Studies with [o-FESAN]− in Breast Cancer Cells [PDF]
PharmaceuticalsBackground: Ferrabis(dicarbollide) ([o-FESAN]−) in combination with proton–boron fusion therapy (PBFT) or boron neutron capture therapy (BNCT) are promising alternative radiation modalities for the treatment of breast cancer. The aim of this study was to
Salvatore Di Maria +13 more
doaj +2 more sources
Unravelling physical and radiobiological effects of proton boron fusion reaction with anionic metallacarboranes ([o-COSAN]-) in breast cancer cells [PDF]
EJNMMI ResearchBackground Protons, which are considered low-LET (Linear Energy Transfer) radiation, have an average RBE (relative biological effectiveness) of 1.1, with a range from 0.7 to 1.6.
Ana Belchior +12 more
doaj +2 more sources
Enhancing Boron Neutron Capture Therapy (BNCT) with Materials Based on COSAN-Functionalized Nanoparticles [PDF]
PharmaceuticalsBackground/Objectives: Boron neutron capture therapy (BNCT) is a promising approach for selectively targeting and destroying malignant cells using 10B isotopes.
Albert Ferrer-Ugalde +7 more
doaj +2 more sources
A Simple Way to Obtain a Decachloro Derivative of Cobalt Bis(dicarbollide)
Reactions, 2023 A simple synthetic way to obtain a decachloro derivative of cobalt bis(dicarbollide) has been found. The reaction of cesium salt of cobalt bis(dicarbollide) anion with aluminum chloride in chloroform under reflux conditions results in Cs[3,3′-Co(4,7,8,9 ...
Sergey A. Anufriev +2 more
doaj +1 more source
METALLABORANES AND METALLACARBORANES OF s-BLOCK ELEMENTS
Main Group Metal Chemistry, 2000 Rana, Geeta +3 more
doaj +2 more sources
Counterion-Induced Aggregation of Metallacarboranes
The Journal of Physical Chemistry C, 2022 The model of counterion-induced metallacarborane aggregation in water was verified on sodium bis(1,2-dicarbollide), one of the most studied examples of metallacarboranes. This case study introduces a novel approach in anionic boron cluster self-assembly that resembles the behavior of polyoxometalate nanoions.
Žiga Medoš +7 more
openaire +1 more source