Results 81 to 90 of about 12,941 (225)

Effect of Immobilization Methods on the Production of Polyethylene-cellulose Biocomposites via Ethylene Polymerization with Metallocene/MAO Catalyst

open access: yesBulletin of Chemical Reaction Engineering & Catalysis, 2020
Polyethylene-cellulose biocomposites were synthesized here via the ethylene polymerization with metallocene as a catalyst along with methylaluminoxane (MAO) as a cocatalyst.
Praonapa Tumawong   +2 more
doaj   +1 more source

Alargamento da distribuição de massa molar de polímeros sintetizados com catalisadores metalocênicos dual-site Broadening of molecular weight distribution of polymers synthesized by metallocene-based dual-site catalysts

open access: yesQuímica Nova, 2008
The main topics related to the use of dual-site catalysts in the production of polymers with broad molecular weight distribution are reviewed. The polymerization using dual-site catalysts is more economical and allows to produce a higher quality product ...
João H. Z. dos Santos   +3 more
doaj   +1 more source

Novel functionalized polyolefins as compatibilizers in polyolefin/polyamide 6 blends and polyethylene/metal hydroxide composites [PDF]

open access: yes, 2005
Ricinoloxazoline maleinate (OXA) was grafted by melt free radical grafting onto polyolefins and elastomers to produce new compatibilizers for polymer blends.
Hippi, Ulla
core  

metallocenes

open access: yes, 2014
Citation: 'metallocenes' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.M03865 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

The Chemistry of Subphthalocyanines: Synthetic Strategies for their Axial, Peripheral, and Remote Postfunctionalization

open access: yesChemistryEurope, Volume 4, Issue 1, January 2026.
From axial and peripheral reactivity to remote derivatization, the chemical versatility of subphthalocyanines (SubPcs) renders them ideal scaffolds for the design of advanced functional materials. This review assembles the synthetic toolbox, key reaction conditions, and future challenges in SubPc functionalization, guiding the development of next ...
Marta Gómez‐Gómez   +4 more
wiley   +1 more source

Polymerization of sterically hindered a-olefins with single-site group 4 metal catalyst precursors [PDF]

open access: yesPolyolefins Journal, 2016
A variety of group 4 metal catalytic systems (C2-symmetric {EBTHI}-, {SBI}-type zirconocene complexes (C2-1–4); C1-symmetric (C1-5–8) and Cs-symmetric (Cs-9) {Cp/Flu}-type zirconocene complexes; Cp*2ZrCl2 (Cp* 2-10)), half-metallocene complexes (CpTiCl3,
Gabriel Theurkauff   +6 more
doaj   +1 more source

An ab-initio converse NMR approach for pseudopotentials

open access: yes, 2010
We extend the recently developed converse NMR approach [T. Thonhauser, D. Ceresoli, A. Mostofi, N. Marzari, R. Resta, and D. Vanderbilt, J. Chem. Phys. \textbf{131}, 101101 (2009)] such that it can be used in conjunction with norm-conserving, non-local ...
Ceresoli, D.   +3 more
core   +1 more source

Kinetic Analysis and Optimization of Long Chain Branched Propylene Polymerization System [PDF]

open access: yes, 2014
A kinetic model has been proposed for a binary catalyst system with the available experimental data from the open literature, in which one catalyst produces polypropylene macromonomer, while the other catalyst attacks the macromonomers as side chains ...
Majumdar, S   +2 more
core   +2 more sources

Styrene Polymerization with Group III Metallocenes: A Generative and Interpretable Catalyst Design Strategy Combining Density Functional Theory and Machine Learning

open access: yesChemistryEurope, Volume 4, Issue 1, January 2026.
Machine‐learning methods are used to predict styrene binding energies and insertion barriers in a series of group III cationic catalysts. A generative algorithm based on these predicted data is provided to propose new catalysts. The rational design of group III metallocene catalysts for styrene polymerization remains a complex challenge due to ...
Stella Christodoulou   +3 more
wiley   +1 more source

Advanced Macromolecular Architectures via Inorganic Polymers

open access: yesMacromolecular Rapid Communications, Volume 47, Issue 2, 23 January 2026.
From linear chains to advanced macromolecular architectures, this review explores how innovations in inorganic polymers unlock new structural and functional capabilities. Emphasizing modern synthetic strategies and unique architectural designs, it highlights the emerging potential of main‐group element systems as next‐generation alternatives to ...
Edip Ajvazi   +3 more
wiley   +1 more source

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