ChemistryEuropeThe rational design of group III metallocene catalysts for styrene polymerization remains a complex challenge due to intertwined steric and electronic effects that govern monomer coordination and insertion. A generative and interpretable machine learning
Stella Christodoulou +3 more
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Rapid kinetic evaluation of homogeneous single-site metallocene catalysts and cyclic diene: how do the catalytic activity, molecular weight, and diene incorporation rate of olefins affect each other? [PDF]
RSC Adv, 2021 Ali A +11 more
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A study of copolymerization of 1-hexene with 2,5-norbornadiene using metallocene catalysts
, 2004 Copolymerization of 1-hexene with a symmetrical diene, namely 2,5-norbornadiene was studied using four different metallocene catalysts. Copolymerization was found to occur exclusively through one of the two equally reactive endocyclic double bonds with ...
Sivaram, Swaminathan +1 more
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Sixtieth Anniversary of Ziegler-Natta Catalysts and Stereospecific Polymerization [PDF]
Kemija u Industriji, 2015 This review article highlights the history of the discoveries of organometallic catalysts and stereospecific polymerization of α-olefins, dienes and a number of vinyl monomers by Karl Ziegler and Giulio Natta sixty years ago, their developments and ...
Janović Z. , Veksli Z.
doaj
Preparation of Dinuclear Metallocene Complexes for High-Performance Supported Catalyst
, 2021 학위논문(석사)--아주대학교 일반대학원 :분자과학기술학과,2021. 21. Introduction 1 2. Results and Discussion 2 2.1 Preparation of dinuclear ansa-metallocene complexes 2 2.2 Preparation of supported catalysts and ethylene polymerization 6 2.3 Characterization of polymers 11 3 ...
배성문
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Metallocene-catalyzed ethene polymerization : long-chain branched polyethene [PDF]
, 2002 Long-chain branches and narrow molecular weight distribution is a novel structure combination in polyethene, which has only been possible to achieve with single-center catalysis.
Kokko, Esa
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Solution isomerization of commercial C2-symmetric metallocene catalysts [PDF]
, 2006 Thesis (MSc (Chemistry and Polymer Science))--University of Stellenbosch, 2006.This study concerns the investigation of the isomerization of different metallocene catalysts in solution, and the effects thereof on the microstructure of polypropylenes ...
Soltan, Omar
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28. Molecular Weight Distribution Control with Supported Metallocene Catalysts
, 1994 Several kinds of supported Cp(2)MeCl(2) (Me = Ti, Zr, Ht) catalysts were prepared with three different SiO2-supports; i.e., SiO2/MAO, SiO2/Al(C2H5)(3) and SiO2/(C2H5)MgCl.
Ihm, Son-Ki +5 more
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Immobilized Bis-Indenyl Ligands for Stable and Cost-Effective Metallocene Catalysts of Hydrogenation and Polymerization Reactions [PDF]
, 2012 Reactions of catalytic hydrogenations and polymerizations are widely used in industry for manufacture of fine chemicals, pharmaceuticals, and plastics.
Simerly, Thomas Max
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HeliyonThe adsorption process followed by photodegradation, adsorption-assisted photocatalysis, is an efficient way to achieve an enhanced overall removal of pollutants from wastewater.
Shadi Asgari +5 more
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