A Suzuki Coupling Based Route to 2,2'-Bis(2-indenyl)biphenyl Derivatives [PDF]
Because of the promising performance in olefin polymerization of 2,2'-bis(2-indenyldiyl)biphenyl zirconium dichloride, we developed a new and broadly applicable route to 2,2'-bis(2-indenyl)biphenyl derivatives.
Arts, Henricus J., +5 more
core +3 more sources
Anionic Fe(I) sandwich complex bearing a π‐phenol ligand with a trifluoroborate substituent with an effective O−H bond dissociation free energy at 40.7 kcal/mol in tetrahydrofuran is prepared, which acts as a proton‐coupled electron transfer reagent for the reduction of organic substrates as well as a Mo(IV) nitride complex, leading to the formation of
Yoshiaki Tanabe +3 more
wiley +1 more source
Enantiopure Ferrocene-Based Planar-Chiral Iridacycles:Stereospecific Control of Iridium-Centred Chirality [PDF]
Reaction of [IrCp*Cl-2](2) with ferrocenylimines (Fc=NAr, Ar=Ph, p-MeOC6H4) results in ferrocene C-H activation and the diastereoselective synthesis of half-sandwich iridacycles of relative configuration S-p*,R-Ir*.
Albrecht +78 more
core +1 more source
Enantioselective synthesis and application to the allylic imidate rearrangement of amine-coordinated palladacycle catalysts of cobalt sandwich complexes [PDF]
The reaction of (η5-(N,N-dimethylaminomethyl)cyclopentadien-yl)(η4-tetraphenylcyclobutadiene)cobalt with sodium tetrachloropalladate and (R)-N-acetylphenylalanine gave planar chiral palladacycle di-μ-chloridebis[(η5-(Sp)-2-(N,N-dimethylaminomethyl ...
Cassar, Doyle J. +5 more
core +1 more source
Polymerization of Allyltrimethylisilane and 4-Methyl-1-Pentene by Using Metallocene Catalysts. [PDF]
Wang W, Ren M, Hou L, Qu S, Li X, Guo Z.
europepmc +1 more source
MAO- and Borate-Free Activating Supports for Group 4 Metallocene and Post-Metallocene Catalysts of α-Olefin Polymerization and Oligomerization. [PDF]
Nifant'ev IE +4 more
europepmc +1 more source
Carbon nanotube and nanofiber growth on Zn based catalysts [PDF]
In this study, acetylene gas was delivered to a catalyst network consists of NaCl-support and Zn nanoparticles in a temperature range of 500-700°C by means of a chemical vapor deposition (CVD).
Dumanli, Ahu Gumrah +3 more
core
Harvesting and Electron-Exchange Energy Transfer by d0 Metallocene-based Organized Systems [PDF]
The present contribution will provide an up-to-date overview of novel experimental and theoretical (de-rived quantum-chemically) knowledge on photonics of group IV metallocene-based systems, also with re-spect to their prominent use in catalysis and ...
Loukova, G.V.
core
The main topics related to the use of dual-site catalysts in the production of polymers with broad molecular weight distribution are reviewed. The polymerization using dual-site catalysts is more economical and allows to produce a higher quality product ...
João H. Z. dos Santos +3 more
doaj +1 more source
Polymerization kinetics of bicyclic olefins and mechanism with symmetrical ansa-metallocene catalysts associated with active center count: relationship between their activities and structure and activation path. [PDF]
Ali A +10 more
europepmc +1 more source

