Dynamic structural engineering of ferrocene-functionalized Ag<sub>20</sub> nanoclusters for enhanced CO<sub>2</sub> electroreduction performance. [PDF]
Zhu HY +7 more
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Unusual phenomena of ethylene homopolymerization catalyzed by α-diimine nickel emerging in a microflow platform. [PDF]
Zhang Z, Li T, Dong Y, Lu Y.
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Homogeneous Non-Metallocene Group 4 Metals Ligated with [N,N] Bidentate Ligand(s) for Olefin Polymerization. [PDF]
Wen Z, Wu C, Chen J, Qu S, Li X, Wang W.
europepmc +1 more source
Ammonium Tetrakis(pentafluorophenyl)borate: Preparation and Application in Olefin Coordination Polymerization as the Cocatalyst Compound. [PDF]
Wei Y +6 more
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“Oscillating” Metallocene Catalysts: How Do They Oscillate?
Based on the results of a series of propylene polymns. using oscillating metallocene catalysts of type [(2-Ar-indenyl)2ZrCl2] (Ar = C6H5 or 3,5-(t-Bu)2-4-MeO-C6H2) with various cocatalysts (MAO, TIBAl), the oscillating behavior of the zirconocenes is discussed with respect to the rac/meso stereochem. outcome of the obtained polypropylenes.
BUSICO, VINCENZO +5 more
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Polymerization of propene by post‐metallocene catalysts
AbstractIn the last few years several non‐metallocene catalysts have been disclosed as efficient catalysts for the stereospecific polymerization of propene.In this paper we summarize some recent literature data and some new results concerning the stereochemical mechanism of propene polymerization promoted by late transition metal systems and group 4 ...
LAMBERTI, Marina +4 more
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Metallocene catalysts for olefin polymerization
Coordination Chemistry Reviews, 1999Abstract The discovery of metallocene methylaluminoxane (MAO) catalysts has opened a frontier in the area of organometallic chemistry, polymer synthesis and processing. A great number of different titanocenes and zirconocenes have been synthesized that give tailored polymers of totally different structures, let control polymer tacticity, molecular ...
exaly +3 more sources
Polymerization of allylbenzene with metallocene catalysts
Homopolymerization of allylbenzene was carried out with various metallocene/methylaluminoxane (MAO) catalysts. Different polymerization behavior was observed depending upon the catalysts empolyed. rac-Et(Ind)2ZrCl2 and rac-Me2Si(Ind)2ZrCl2 gave semicrystalline polyallylbenzenes while i-Pr(CpFlu)ZrCl2 and CpTiCl3 did not give any polymeric product.
Doo-Jin Byun +3 more
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Metallocene Catalysts for Olefin Oligomerization
Macromolecular Symposia, 2006AbstractMetallocene complexes with a cocatalyst such as methylalumoxane, MAO can be used as catalysts in the dimerization or oligomerization of olefins (alkenes) including the (co‐/hydro‐)oligomerization of ethene, of the α‐olefins propene, 1‐butene, 1‐pentene, 1‐hexene, and higher α‐olefins, branched α‐olefins, cyclic olefins and α,ω‐dienes.
Christoph Janiak
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Kinetic and Mechanistic Aspects of Metallocene Polymerization Catalysts
AbstractFor Abstract see ChemInform Abstract in Full Text.
Bochmann, Manfred
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