Results 21 to 30 of about 5,506 (175)

Amine, Amido, and Imido Complexes of Tantalum Supported by a Pyridine-Linked Bis(phenolate) Pincer Ligand: Ta−N π-Bonding Influences Pincer Ligand Geometry [PDF]

open access: yes, 2009
A series of tantalum imido and amido complexes supported by a pyridine-linked bis(phenolate) ligand has been synthesized. Characterization of these complexes via X-ray crystallography reveals both C_s and C_2 binding modes of the bis(phenolate)pyridine ...
Bercaw, John E.   +3 more
core   +2 more sources

UHMWPE/SBA-15 nanocomposites synthesized by in situ polymerization [PDF]

open access: yes, 2016
Different nanocomposites have been attained by in situ polymerization based on ultra-high molecular weight polyethylene (UHMWPE) and mesoporous SBA-15, this silica being used for immobilization of the FI catalyst bis [N-(3-tert-butylsalicylidene)-2,3,4,
Adewole   +60 more
core   +3 more sources

Propene-cycloolefin polymerization [PDF]

open access: yesPolyolefins Journal, 2014
Highly active metallocenes and other single site catalysts have opened up the possibility of polymerizing cycloolefins such as norbornene (N) or of copolymerizing them with ethene (E) or propene (P).
Laura Boggioni, Incoronata Tritto
doaj   +1 more source

Comparative Analysis of Ethylene/Diene Copolymerization and Ethylene/Propylene/Diene Terpolymerization Using Ansa-Zirconocene Catalyst with Alkylaluminum/Borate Activator: The Effect of Conjugated and Nonconjugated Dienes on Catalytic Behavior and Polymer Microstructure

open access: yesMolecules, 2021
The copolymerization of ethylene‒diene conjugates (butadiene (BD), isoprene (IP) and nonconjugates (5-ethylidene-2-norbornene (ENB), vinyl norbornene VNB, 4-vinylcyclohexene (VCH) and 1, 4-hexadiene (HD)), and terpolymerization of ethylene-propylene ...
Amjad Ali   +9 more
doaj   +1 more source

Zirconium and titanium complexes supported by tridentate LX2 ligands having two phenolates linked to furan, thiophene, and pyridine donors: precatalysts for propylene polymerization and oligomerization [PDF]

open access: yes, 2008
Zirconium and titanium complexes with tridentate bis(phenolate)-donor (donor = pyridine, furan and thiophene) ligands have been prepared and investigated for applications in propylene polymerization.
Agapie, Theodor   +4 more
core   +2 more sources

Homogeneous and heterogeneous oligomerization reactions of olefins with unbridged metallocene catalysts [PDF]

open access: yesPolyolefins Journal, 2019
1-Pentene, respectively 1-hexene, were reacted with 13 homogeneous metallocene catalysts to give linear oligomerization products, predominantly dimers, with selectivities above 90%.
Tanja Ritter, Helmut Alt
doaj   +1 more source

Synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene [PDF]

open access: yes, 2009
Indexación: ScieloThis work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by
Adams, C.   +7 more
core   +1 more source

Innovative catalytic systems driving sustainable olefin polymerization: Recent advances and green chemistry approaches [PDF]

open access: yesPolyolefins Journal
This mini-review addresses the burgeoning requirements for environmentally friendly processes in the polymer industry, focusing on recent progress in developing catalytic systems for sustainable olefin polymerization.
Farabi Hossain, Md Enamul Hoque
doaj   +1 more source

Cat-CrNP as new material with catalytic properties for 2-chloro-2-propen-1-ol and ethylene oligomerizations

open access: yesScientific Reports, 2021
The contemporary search for new catalysts for olefin oligomerization and polymerization is based on the study of coordinating compounds and/or organometallic compounds as post-metallocene catalysts.
Jacek Malinowski   +8 more
doaj   +1 more source

Selective ethylene trimerization by titanium complexes bearing phenoxy-imine ligands: NMR and EPR Spectroscopic studies of the reaction intermediates [PDF]

open access: yes, 2014
The catalyst systems (FI)TiCl₃/MAO (FI = phenoxyimine ligand with an additional aryl–O–CH₃ donor) display exceptionally high activity in selective ethylene trimerization.
Bryliakov, Konstantin P.   +8 more
core   +2 more sources

Home - About - Disclaimer - Privacy