Results 61 to 70 of about 6,221 (196)

N‐Heterocyclic Tetrylenes with a 1,1′‐Ferrocenylene Backbone and Bis(2,4,6‐triisopropylphenyl)boryl N‐Substituents

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
Ferrocene‐based N‐heterocyclic tetrylenes [Fe{(η5‐C5H4)NBTrip2}2E](E = GePb; Trip = C6H2‐2,4,6‐iPr3)exhibit long EN and short BN bonds, in agreement with increased electrophilicity due to the ‐M effect of the N‐substituents, whose stericdemand prevents coordination of 4‐(dimethylamino)pyridine (DMAP) to theplumbylene PbII atom, but allows the ...
Sneha Mullassery   +3 more
wiley   +1 more source

Influência da estrutura do catalisador a base de Zirconoceno na estereorregularidade e propriedades do polipropileno formado Influence of Zirconocene structure on polypropylene stereorregularity and properties

open access: yesPolímeros, 1997
RESUMO: Catalisadores de metalocenos com diferentes simetrias, cocatalisados por metilaluminoxanas (MAO), foram avaliados em diferentes temperaturas de polimerização do propileno.
Mário R. Meneghetti   +2 more
doaj   +1 more source

Metal Cluster Size-Dependent Activation Energies of Growth of Single-Chirality Single-Walled Carbon Nanotubes inside Metallocene-Filled Single-Walled Carbon Nanotubes

open access: yesNanomaterials, 2021
By combining in situ annealing and Raman spectroscopy measurements, the growth dynamics of nine individual-chirality inner tubes (8,8), (12,3), (13,1), (9,6), (10,4), (11,2), (11,1), (9,3) and (9,2) with diameters from ~0.8 to 1.1 nm are monitored using ...
Marianna V. Kharlamova   +1 more
doaj   +1 more source

Designing organometallic compounds for catalysis and therapy [PDF]

open access: yes, 2012
Bioorganometallic chemistry is a rapidly developing area of research. In recent years organometallic compounds have provided a rich platform for the design of effective catalysts, e.g. for olefin metathesis and transfer hydrogenation.
Abraha Habtemariam   +188 more
core   +1 more source

Metallocene Based Polyolefin Nanocomposites [PDF]

open access: yesMaterials, 2014
One of the most efficient and versatile ways to synthesize polyolefin nanocomposites is the in-situ polymerization of olefins in the presence of nano particles by metallocene catalysts. Metallocene/methylaluminoxane (MAO) catalysts are soluble in hydrocarbons and therefore they can be absorbed perfectly in solution onto the surface of particles or ...
openaire   +2 more sources

Tandem Takeoff: Powering Tomorrow with Industrial‐Grade Perovskite/Silicon Solar Cells

open access: yesAdvanced Energy Materials, Volume 16, Issue 5, 4 February 2026.
Perovskite/silicon tandem solar cells have recently achieved certified power conversion efficiencies of 34.85%, far exceeding the Shockley‐Queisser limit for single‐junction silicon and standalone perovskite cells. This review highlights the latest advances in the design, integration, and optimization of perovskite top cells for monolithic tandem ...
Maria Vasilopoulou   +19 more
wiley   +1 more source

Anti-cancer Action of Metal Complexes: Electron Transfer and Oxidative Stress? [PDF]

open access: yes, 1988
Evidence is presented in support of an electron transfer mechanism for various metal complexes possessing anti-neoplastic properties. Cyclic voltammetry was performed on several metallocenes, bis(acetato)bis(imidazole)Cu(II), and coordination compounds ...
Ames, James R.   +3 more
core   +1 more source

Epoxidised Natural Rubber (ENR)/Wollastonite Composites for Tyre Inner Liners: A Practical Replacement for Butyl Rubber in Industrial Applications

open access: yesPolymer Engineering &Science, Volume 66, Issue 2, Page 1153-1169, February 2026.
Replacing butyl rubber with ENR+Wollastonite in tyre inner‐liners. ABSTRACT This study aimed to develop epoxidised natural rubber (ENR)‐based rubber compound formulations as an alternative to butyl rubber for tyre inner liners. The effects of different vulcanization systems, designed to achieve similar curing behavior in NR‐based carcass compounds and ...
Tuba Ünügül Yavuz   +4 more
wiley   +1 more source

Analysis of the Continuous Feeding of Catalyst Particles during the Growth of Vertically Aligned Carbon Nanotubes by Aerosol-Assisted CCVD

open access: yesNanomaterials, 2022
Aerosol-assisted catalytic chemical vapor deposition (AACCVD) is a powerful one-step process to produce vertically aligned carbon nanotubes (VACNTs), characterized by the continuous supply of the catalyst precursor (metallocene). The behavior of catalyst
Celia Castro   +5 more
doaj   +1 more source

Cp* Noninnocence Leads to a Remarkably Weak C–H Bond via Metallocene Protonation [PDF]

open access: yes, 2019
Metallocenes, including their permethylated variants, are extremely important in organometallic chemistry. In particular, many are synthetically useful either as oxidants (e.g., Cp_2Fe^+) or as reductants (e.g., Cp_2Co, Cp*_2Co, and Cp*_2Cr).
Chalkley, Matthew J.   +2 more
core   +5 more sources

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