Results 41 to 50 of about 6,290 (219)
Deprotonative C(sp3)/C(sp2)–H (Multi)Silylation of (Hetero)Arenes Mediated by NaTMP
Angewandte Chemie, EarlyView.An operationally simple protocol using a strongly basic sodium amide in combination with sterically emcumbered silicon electrophiles enables the deprotonative C–H (multi)silylation of a myriad of (hetero)arenes. Mechanistic investigations highlight the pivotal role of steric and coordination effects in controlling the regioselectivity and efficiency of
David Sánchez‐Roa +6 more
wiley +2 more sources
Dibora[2]ferrocenophane: a carbene-stabilized diborene in a strained cis-configuration [PDF]
, 2016 Unsaturated bridges that link the two cyclopentadienyl ligands together in strained ansa metallocenes are rare and limited to carbon-carbon double bonds. The synthesis and isolation of a strained ferrocenophane containing an unsaturated two-boron bridge,
Braunschweig, Holger +9 more
core +1 more source
Advances in f-element cyanide chemistry [PDF]
, 2015 International audienceThis Dalton perspective gives an overview of the development of cyanide chemistry of 4f- and 5f-elements, a field which was poorly explored in contrast to the attention paid to the cyanide complexes of the d transition metals.
Berthet, Jean-Claude +2 more
core +3 more sources
Metallocene to metallocene conversion. Synthesis of an oxazoline-substituted pentamethyliridocenium cation from a ferrocenyloxazoline [PDF]
, 2016 Reaction of (S)-2-ferrocenyl-4-(1-methylethyl)oxazoline with [(CpIrCl2)-Ir-star](2) in benzonitrile with KPF6 and NaOH gave (eta(5)-(S)-2-(4-(1-methylethyl))oxazolinylcyclopentadienyl)(eta(5)-pentamethylcyclopentadienyl)-iridium(III) hexafluorophosphate (
Arrayás +31 more
core +1 more source
Nanomaterials, 2020 The paper reports the synthesis of carbon nanotubes from ethanol over group VIII (Fe, Co, Ni) catalysts derived from corresponding metallocenes. Several unexpected cooperative effects are reported, which are never observed in the case of individual ...
Aida R. Karaeva +4 more
doaj +1 more source
Nanomaterials, 2023 This review discusses the phemenology of filling, the investigation of kinetics, and the electronic properties for applications of filled single-walled carbon nanotubes (SWCNTs), and summarizes five main achievements that were obtained in processing the ...
Marianna V. Kharlamova +1 more
doaj +1 more source
Paramagnetic Solid-State NMR Study of Solid Solutions of Cobaltocene with Ferrocene and Nickelocene
MagnetochemistryThe metallocenes ferrocene (Cp2Fe, 1), nickelocene (Cp2Ni, 2), and cobaltocene (Cp2Co, 3) crystallize in the same space group (P21/a) and they have the same shape and similar size.
Gabrielle E. Harmon-Welch +2 more
doaj +1 more source
Self-contained Kondo effect in single molecules
, 2005 Kondo coupling of f and conduction electrons is a common feature of f-electron intermetallics. Similar effects should occur in carbon ring systems(metallocenes).
C. H. Booth +5 more
core +1 more source
Tuning the electrical conductivity of nanotube-encapsulated metallocene wires
, 2006 We analyze a new family of carbon nanotube-based molecular wires, formed by encapsulating metallocene molecules inside the nanotubes. Our simulations, that are based on a combination of non-equilibrium Green function techniques and density functional ...
A. R. Rocha +5 more
core +1 more source
New ionic half-metallocenes of early lanthanides [PDF]
, 2008 International audienceWe present in this study a new and one-step method allowing the preparation of an unprecedented family of stable half-lanthanidocenes.
Mortreux, André +4 more
core +4 more sources