Results 51 to 60 of about 6,290 (219)

Methyl 2-(4-ferrocenylbenzamido)thiophene-3-carboxylate and ethyl 2-(4-ferrocenylbenzamido)-1,3-thiazole-4-acetate, a unique ferrocen [PDF]

, 2005
The conformations and hydrogen bonding in the thiophene and thiazole title compounds, [Fe(C₅H₅)(C₂₀H₁₄NO₃S)], (I), and [Fe(C₅H₅)(C₁₉H₁₇N₂O₃S)], (II), are discussed.
Alley, Steven, Gallagher, John F., Hooper, Vincent M., Kenny, Peter T.M., Lough, Alan J.   +4 more
core   +1 more source

Six-coordinated half-metallocene catalyst for ethylene polymerization and its mechanism study

Giant
The demand for catalysts capable of enabling olefin polymerization at elevated temperatures to meet industrial requirements continues to grow. Among emerging candidates, novel six-coordinated half-metallocene catalysts, which combine the advantages of ...
Qian Li, Zifang Guo, Shuzhang Qu, Xinwei Li, Jian Chen, Yiming Wei, Cui Zheng, Zhihui Song, Yue Lan, Zhao Wen, Chaofan Yu   +10 more
doaj   +1 more source

One‐Dimensional Materials Supported in Two‐Dimensional Van der Waals Metal–Organic Frameworks with Optical Anisotropy Switching via Twist‐Engineering

Advanced Materials, EarlyView.
We introduce a molecular strategy to assemble one‐dimensional (1D) materials into two‐dimensional (2D) van der Waals metal–organic frameworks (MOFs). Crystals of [FeX(pzX)(bpy)] (X = Cl, F) form anisotropic 2D layers that can be mechanically exfoliated into thin sheets.
Eleni C. Mazarakioti, Carla Boix‐Constant, Iván Gómez‐Muñoz, Diego López‐Alcalá, Sergio Revuelta, Marco Ballabio, Vasileios Balos, José J. Baldoví, Enrique Cánovas, Josep Canet‐Ferrer, Guillermo Mínguez Espallargas, Samuel Mañas‐Valero, Eugenio Coronado   +12 more
wiley   +1 more source

Advantages of Group 4 Metallocene Bis(trimethylsilyl)acetylene Complexes as Metallocene Sources Towards Other Synthetically used Systems

ChemistryOpen, 2019
Active species for synthetic and catalytic applications are formed from well defined complexes or mixtures of compounds. For group 4 metallocenes, three pathways for the formation of the reactive complex fragment [Cp′2M] are known: (i) reductive mixtures
Prof. Dr. Uwe Rosenthal
doaj   +1 more source

Synthesis and Characterization of Cerium(IV) Metallocenes

Inorganics, 2015
By applying a salt metathesis approach between Ce(OtBu3)2(NO3)2(THF)2 and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the ...
Andrew D. Sutton, David L. Clark, Brian L. Scott, John C. Gordon   +3 more
doaj   +1 more source

Versatile Coordination of Cyclopentadienyl-Arene Ligands and Its Role in Titanium-Catalyzed Ethylene Trimerization [PDF]

, 2009
Cationic titanium(IV) complexes with ansa-(η5-cyclopentadienyl,η6-arene) ligands were synthesized and characterized by X-ray crystallography. The strength of the metal-arene interaction in these systems was studied by variable-temperature NMR ...
Adams J. R., Agapie T., Antonelli D., Barrios-Landeros F., Bart S. C., Bernskoetter W. H., Blackmore K. J., Blok A. N. J., Blok A. N. J., Bouwkamp M. W., Bouwkamp M. W., Brackemeyer T., Braunstein P., Brintzinger H. H., Burckhardt U., Butenschön H., Calderazzo F., Casarin M., Chatt J., Clearfield A., Cohen S. A., Cuenca T., Dapprich S., De Bruin T., De Bruin T. J. M., De Bruin T. J. M., Decker S. A., Deckers P. J. W., Deckers P. J. W., Deckers P. J. W., Dewar J. S., Dias H. V. R., Diefenbach A., Erker G., Espinet P., Fachinetti G., Fachinetti G., Frenking G., Frenking G., Fryzuk M. D., Gillis D. J., Graham T. W., Green J. C., Grotjahn D. B., Guo Z., Guram A. S., Hagadorn J. R., Hagen H., Haneline M. R., Hanna T. E., Hayes P. G., Howard W. A., Howard W. A., Huang J. L., Hubig S. M., Jang J. H., Jeffrey J. C., Jung M. E., Kalodimos C. G., Kerschner J. L., Kerschner J. L., Kissounko D., Kool L. B., Kuriyama M., Lancaster S., Lauher J. W., Lee H., Lentz M. R., Licht E. H., Lockwood M. A., Lupinetti A. J., Marsella J., Montag M., Moxham G. L., Müller C., Negishi E. I., Nifant’ev I. E., Otten E., Overett M. J., Ozerov O. V., Pampaloni G., Pool J. A., Procopio L. J., Rosenthal U., Rosenthal U., Sassmannshausen J., Sassmannshausen J., Siemeling U., Sikora D., Sikora D. J., Singewald E. T., Singewald E. T., Singewald E. T., Slone C. S., Smith J., Spek A. L., Stanciu C., Stone K. J., Szilagyi R. K., Tobisch S., Tobisch S., Tobisch S., Traylor T. G., Van der Sluis P., Van Raaij E. U., Wass D. F., Werner H., Wu T., Zachmanoglou C. E.   +108 more
core   +4 more sources

Synthesis and Chemistry of Chiral Metallocenes

Molecules, 2005
n ...
Oleksiy Vassylyev
doaj   +1 more source

A base-free synthetic route to anti-bimetallic lanthanide pentalene complexes [PDF]

, 2017
We report the synthesis and structural characterisation of three homobimetallic complexes featuring divalent lanthanide metals (Ln = Yb, Eu and Sm) bridged by the silylated pentalene ligand [1,4-{SiiPr3}2C8H4]2− (= Pn†).
Alexander F. R. Kilpatrick, Ashley, Avdeef, Balazs, Berg, Blessing, Boncella, Bunel, Burns, Cloke, Cloke, Coles, Compton, Connelly, Deacon, Deacon, Deacon, Edelmann, Edelstein, Edelstein, Evans, Evans, Evans, Evans, Evans, Evans, Evans, Evans, Evans, Evans, Evans, Evans, Evans, Evans, F. Geoffrey N. Cloke, Farrugia, Feng, Fukuda, Geiger, Geiger, Green, Hanusa, Hitchcock, Hitchcock, Hosoya, Ishikawa, Jiang, Keates, Kobayashi, Kuehl, Kuuloja, Le Roy, Le Roy, Magnani, Manriquez, Marks, Mason, Molander, Morss, Nonat, Oelckers, Orchard, Ostfeld, Otwinowski, Portilla, Rabe, Schubert, Schultz, Schumann, Schwartz, Shannon, Summerscales, Summerscales, Summerscales, Summerscales, Tilley, Tilley, Tilley, Tilley, Tsuji, Van Vleck, Veauthier, Washburn, Watson   +83 more
core   +1 more source

Photoelectron spectra of metallocenes

Journal of Electron Spectroscopy and Related Phenomena, 1980
Abstract The He(II) spectra of the unsubstituted metallocenes {M(η-C5H5)2}, M  V, Cr, Mn, Fe, Co, Ni and Ru, and of {Mn(η-C5H4Me)2} are reported; both He(I) and He(II) spectra of some decamethylmetallocenes {M(η-C5Me5)2}, where M  Mg, V, Cr, Mn, Fe, Co and Ni, are also given.
Cauletti, C, Green, J, Kelly, M, Powell, P, Vantilborg, J, Robbins, J, Smart, J   +6 more
openaire   +2 more sources

Titanocene / cyclodextrin supramolecular systems: a theoretical approach

Chemistry Central Journal, 2012
Background Recently, various metallocenes were synthesized and analyzed by biological activity point of view (such as antiproliferative properties): ruthenocenes, cobaltoceniums, titanocenes, zirconocenes, vanadocenes, niobocenes, molibdocenes etc.
Riviş Adrian, Hădărugă Nicoleta G, Gârban Zeno, Hădărugă Daniel I   +3 more
doaj   +1 more source