Results 21 to 30 of about 6,290 (219)

Chemical Properties of Metallocene-Filled Carbon Nanotubes to Tailor Toxicity in Plants

open access: yesBiology and Life Sciences Forum, 2023
Metallocenes are toxic chemicals that are used for the growth of carbon nanotubes (CNTs). The study of the toxicity of metallocenes on plants is very important. It governs the issues of genetics.
Marianna V. Kharlamova
doaj   +1 more source

Ionization of Decamethylmanganocene: Insights from the DFT-Assisted Laser Spectroscopy

open access: yesMolecules, 2022
Metallocenes represent one of the most important classes of organometallics with wide prospects for practical use in various fields of chemistry, materials science, molecular electronics, and biomedicine.
Sergey Ketkov   +3 more
doaj   +1 more source

Transition Metal–(μ-Cl)–Aluminum Bonding in α-Olefin and Diene Chemistry

open access: yesMolecules, 2022
Olefin and diene transformations, catalyzed by organoaluminum-activated metal complexes, are widely used in synthetic organic chemistry and form the basis of major petrochemical processes.
Ilya E. Nifant’ev   +2 more
doaj   +1 more source

High-Efficiency Mono-Cyclopentadienyl Titanium and Rare-Earth Metal Catalysts for the Production of Syndiotactic Polystyrene

open access: yesMolecules, 2023
Syndiotactic polystyrene (SPS) refers to a type of thermoplastic material with phenyl substituents that are alternately chirally attached on both sides of an aliphatic macromolecular main chain.
Bo Wen   +5 more
doaj   +1 more source

Ti Group Metallocene-Catalyzed Synthesis of 1-Hexene Dimers and Tetramers

open access: yesMolecules, 2021
1-Hexene transformations in the catalytic systems L2MCl2–XAlBui2 (L = Cp, M = Ti, Zr, Hf; L = Ind, rac-H4C2[THInd]2, M = Zr; X = H, Bu i) and [Cp2ZrH2]2-ClAlR2 activated by MMAO-12, B(C6F5)3, or (Ph3C)[B(C6F5)4] in chlorinated solvents (CH2Cl2, CHCl3, o ...
Pavel V. Kovyazin   +5 more
doaj   +1 more source

Latest News: Reactions of Group 4 Bis(trimethylsilyl)acetylene Metallocene Complexes and Applications of the Obtained Products

open access: yesChemistryOpen, 2021
Recently published reactions of group 4 metallocene bis(trimethylsilyl)acetylene (btmsa) complexes from the last two years are reviewed. Complexes like Cp’2Ti(η2‐Me3SiC2SiMe3) and Cp2Zr(py)(η2‐Me3SiC2SiMe3) with Cp’ as Cp (cyclopentadienyl) and Cp ...
Prof. Uwe Rosenthal
doaj   +1 more source

Metallocene-Filled Single-Walled Carbon Nanotube Hybrids

open access: yesNanomaterials, 2023
In this paper, the growth mechanism, structure, growth processes, growth kinetics, and optical, vibronic and electronic properties of metallocene-filled single-walled carbon nanotubes (SWCNTs) are considered.
Marianna V. Kharlamova   +1 more
doaj   +1 more source

Metallocene Polyethylene Wax Synthesis [PDF]

open access: yesMacromolecules, 2020
Solid polymethylaluminoxane (sMAO) supported ansa-bridged permethylindenyl zirconocenes Me2SB(CpR,I*)ZrX2 ({(η5-C9Me6)Me2Si(η5-C5H3R)}ZrX2; R = H, Me, and nBu; X = Cl, Br, Me, and CH2Ph) have been ...
Lamb, JV   +4 more
openaire   +1 more source

High Vacuum Deposition of Biferrocene Thin Films on Room Temperature Substrates [PDF]

open access: yes, 2017
: Metallocenes are a promising candidate for future spintronic devices due to their versatile and tunable magnetic properties. However, single metallocenes, e.g., ferrocene, sublimate below room temperature, and therefore the implementation for future ...
Albrecht, Tim   +8 more
core   +3 more sources

Synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene [PDF]

open access: yes, 2009
Indexación: ScieloThis work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by
Adams, C.   +7 more
core   +1 more source

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