Results 31 to 40 of about 1,538 (201)

Recent advances in single molecule magnetism of dysprosium-metallofullerenes [PDF]

open access: yes, 2019
This article outlines the magnetic properties of single molecule magnets based on Dy-encapsulating endohedral metallofullerenes. The factors that govern these properties, such as the influence of different non-metal species in clusterfullerenes, the cage
Spree, L., Popov, A.A.
core   +1 more source

Stability Computations for Isomers of La@Cn (n = 72, 74, 76)

open access: yesMolecules, 2012
Density-functional theory calculations are presented for low-energy La@C72, La@C74 and La@C76 isomers with IPR (isolated pentagon rule) and non-IPR cages.
Ludwik Adamowicz   +5 more
doaj   +1 more source

Recent Progress on the Functionalization of Endohedral Metallofullerenes

open access: yesInorganics, 2023
Functionalization of endohedral metallofullerenes (EMFs) plays an important role in exploring the reactivity of EMFs and stabilizing missing EMFs, thus conferring tunable properties and turning EMFs into applicable materials.
Song Wang   +8 more
doaj   +1 more source

Tims and maldi tof of endohedral metallofullerenes [PDF]

open access: yes, 2004
Mass spectral studies (both TIMS – thermal ionization and MALDI TOF – matrix-assisted laser desorption time-of-flight mass spectrometry) of the endohedral metallofullerenes, Li@C60,Li2C70 and 99mTc@C70,provided detailed structural and reactivity ...
Đerić, A.   +4 more
core   +6 more sources

Four‐Centre, Multielectron Bonding in Rare‐Earth Germole Sandwich Complexes

open access: yesAngewandte Chemie, Volume 137, Issue 21, May 19, 2025.
Stepwise one‐ and two‐electron reduction of the dimeric germole‐ligated sandwich complexes [(η5‐CpGe)M(η5‐Cpttt)]2 (M = Y, Gd, Dy) produces the isostructural complex anions [{(η5‐CpGe)M(η5‐Cpttt)}2]− and [{(η5‐CpGe)M(η5‐Cpttt)}2]2−, respectively. The additional electrons populate bonding molecular orbitals extending across the {M2Ge2} rings, resulting ...
Siddhartha De   +6 more
wiley   +2 more sources

Non-Chromatographic Purification of Endohedral Metallofullerenes

open access: yes, 2017
The purification of endohedral metallofullerenes by high performance liquid chromatography is very time-consuming and expensive. A number of rapid and inexpensive non-chromatographic methods have thus been developed for large-scale purification of ...
Zhiyong Wang   +2 more
core   +1 more source

Enantioselective Synthesis of Endohedral Metallofullerenes

open access: yesJournal of the American Chemical Society, 2011
Endohedral metallofullerenes are promising materials in biomedical and material sciences. In particular, they are of interest as agents for magnetic resonance imaging (MRI), photovoltaic devices, and semimetallic components. The synthesis of chiral endofullerenes represents one step further in the potential use of these carbon allotropes; however, this
Sawai K.   +10 more
openaire   +3 more sources

Reduction of Endohedral Metallofullerenes:  A Convenient Method for Isolation

open access: yes, 2016
Isolation of the endohedral metallofullerenes is currently carried out via a multistage high-performance liquid chromatography (HPLC) method. However, this method is tedious and time-consuming work, making it difficult to obtain macroscopic quantities of
Takeshi Akasaka (1402213)   +8 more
core   +1 more source

Influence of Charge Transfer on Thermoelectric Properties of Endohedral Metallofullerene (EMF) Complexes

open access: yesEnergies, 2023
A considerable potential advantage of manufacturing electric and thermoelectric devices using endohedral metallofullerenes (EMFs) is their ability to accommodate metallic moieties inside their cavities.
Majed Alshammari   +3 more
doaj   +1 more source

Synthesis and Properties of Endohedral Metallofullerene Ligand [PDF]

open access: yesECS Meeting Abstracts, 2008
Abstract not Available.
Yokosawa, Yuya   +2 more
openaire   +1 more source

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