Results 41 to 50 of about 9,317 (210)

Application of the electronic spectra of porphyrins for analytical purposes: the effects of metal ions and structural distortions [PDF]

open access: yes, 2013
We investigated the UV-Vis absorption, singlet-1 and singlet-2 fluorescence, as well as the formation of several metalloporphyrins from equilibrial and kinetic aspects in aqueous solution.
Horváth, Ottó, Valicsek, Zsolt
core   +1 more source

Intermolecular interaction of photoexcited Cu(TMpy-P4) with water studied by transient resonance Raman and picosecond absorption spectroscopies [PDF]

open access: yes, 1997
photoinduced complex between Cu(TMpy-P4) and water molecules, reversibly axially coordinated to the central metal, was observed in picosecond transient absorption and nanosecond resonance Raman experiments. This complex is rapidly created (τ1 = 15 ± 5 ps)
Chirvony, Vladimir S.   +7 more
core   +2 more sources

Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs

open access: yesMolecules, 2015
Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs).
Arkaitz Fidalgo-Marijuan   +5 more
doaj   +1 more source

Covalent Organic Frameworks for Photocatalytic CO2 Reduction: Metal Integration Principles, Strategies and Functions

open access: yesAdvanced Functional Materials, EarlyView.
Covalent organic frameworks (COFs) with metals have been recognized as versatile platforms for photocatalytic CO2 reduction (CO2PRR). Herein, an overview of metal integration strategies for COFs is systematically summarized. Regulatory mechanisms and structure–activity relationships between metal integration and COF‐based CO2PRR are emphasized.
Jie He   +5 more
wiley   +1 more source

Suppressing Metal–Molecule Charge Transfer With a Phosphorus Interlayer

open access: yesAdvanced Materials Interfaces, EarlyView.
Phosphorus forms stable reconstructions with remarkable properties on various metal substrates. Here, using a spectroscopic approach, its role as an effective buffer layer on Cu(110) is demonstrated, preventing charge transfer to adsorbed Zn‐tetraphenylporphyrins (ZnTPP).
Mattia Bassotti   +7 more
wiley   +1 more source

METALLOPORPHYRINS

open access: yesJournal of Biological Chemistry, 1940
W. Mansfield Clark   +3 more
  +6 more sources

Ethnopharmacological Approaches for Therapy of Jaundice: Part I

open access: yesFrontiers in Pharmacology, 2017
Jaundice is a very common symptom especially in the developing countries. It is associated with several hepatic diseases which are still major causes of death.
Devesh Tewari   +13 more
doaj   +1 more source

New insights on microscopic properties of metal-porphyrin complexes attached to quartz crystal sensor

open access: yesScientific Reports, 2021
A quartz crystal adsorbent coated with 5,10,15,20-tetrakis(4-methylphenyl) porphyrin was used to examine the complexation phenomenon of three metallic ions [aluminum(III), iron(III) and indium(III)].
Haifa Alyousef   +4 more
doaj   +1 more source

Ruthenium-oxo and -tosylimido porphyrin complexes for epoxidation and aziridination of alkenes [PDF]

open access: yes, 1999
Dioxoruthenium(VI) porphyrins including those containing chiral porphyrinato ligands can be readily prepared by oxidation of [Ru 11(Por)(CO)(MeOH)] with PhIO or metachloroperoxybenzoic acid. Similar reactions with PhINTs gave [Ru VI(Por)(NTs) 2] isolated
Che, CM, Yu, WY
core   +1 more source

Fe/N‐Doped Carbon with Nearly Ordered Mesopores and Tunable Particle Sizes as Model Catalysts for Quantitative Evaluation of Electrocatalytic Active Sites

open access: yesAdvanced Science, EarlyView.
This study is dedicated to the design and synthesis of MOF‐derived mesoporous Fe/N‐doped carbons as model catalysts, aiming to quantitatively evaluate the utilization of active sites in the ORR. Through modulation followed by pyrolysis, we successfully prepare size‐tunable Fe/MNC‐x with doped iron atoms and mesoporous structures. The smaller Fe/MNC‐250
Hongjuan Zhang   +7 more
wiley   +1 more source

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