Results 81 to 90 of about 9,317 (210)

Trace Detection of Metalloporphyrin-Based Coordination Polymer Particles via Modified Surface-Enhanced Raman Scattering Assisted by Surface Metallization

open access: yesInternational Journal of Analytical Chemistry, 2016
This study proposed a facile method to detect metalloporphyrin-based coordination polymer particles (Z-CPPs) in aqueous solution by modified surface-enhanced Raman scattering (SERS).
Yu Sun, Alessio Caravella
doaj   +1 more source

Metalloporphyrins inactivate caspase-3 and -8 [PDF]

open access: yes, 2005
Activation of caspases represents one of the earliest biochemical indicators for apoptotic cell death. Therefore, measurement of caspase activity is a widely used and generally accepted method to determine apoptosis in a wide range of in vivo and in ...
Blumenthal, Signe B.   +8 more
core   +1 more source

LC-MS-MS identification of drug metabolites obtained by metalloporphyrin mediated oxidation

open access: yesJournal of the Brazilian Chemical Society, 2003
In this paper we report the application of liquid chromatography-mass spectrometry (LC-MS-MS) to the identification of the products formed by oxidation of albendazole and disopyramide with metalloporphyrins in dichloroethane, using iodosylbenzene as an ...
Maurin Andrea J. M.   +4 more
doaj  

Structural Evidence for a Copper-Bound Carbonate Intermediate in the Peroxidase and Dismutase Activities of Superoxide Dismutase [PDF]

open access: yes, 2012
Copper-zinc superoxide dismutase (SOD) is of fundamental importance to our understanding of oxidative damage. Its primary function is catalysing the dismutation of superoxide to O2 and H2O2. SOD also reacts with H2O2, leading to the formation of a strong
Luis Eduardo Soares Netto   +4 more
core   +3 more sources

Schwer wiegt die Krone: Kronenethermodulation von Kobaltporphyrinen in der CO2 Elektroreduktion in Zero‐Gap Electrolyseuren

open access: yesAngewandte Chemie, Volume 138, Issue 11, 9 March 2026.
Die Implementierung von Kronenethern in den Liganden von Kobaltporphyrinen wirkt sich in mehrfacher Hinsicht positiv auf die elektrochemische CO2‐Reduktion aus: 1. Das Reduktionspotenzial wird in Gegenwart von K+ gesenkt; 2. die CO‐Erzeugung in Zero‐Gap‐Elektrolyseuren wird gesteigert und 3.
Wiebke Wiesner   +7 more
wiley   +1 more source

Cationic Mn2+/H+ exchange leading a slow solid-state transformation of a 2D porphyrinic network at ambient conditions [PDF]

open access: yes, 2017
Metalloporphyrins exhibit outstanding chemical, physical and biological properties in dissolution, however, it is a challenge to synthesize them as stable solid frameworks. Long-time stability is crucial for future applications of these materials, and we
Amayuelas López, Eder   +6 more
core   +2 more sources

Heavy is the Crown: Crown Ether Modulation of Cobalt Porphyrin CO2 Electroreduction in Zero‐Gap Electrolyzers

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 11, 9 March 2026.
The implementation of crown ethers into the ligand of cobalt porphyrins benefits the electrochemical CO2 reduction in the several ways: (1) the reduction potential is lowered in presence of K+; (2) it boosts the CO generation in Zero‐Gap Electrolyzers and (3) ensures complex stability during electrolysis.
Wiebke Wiesner   +7 more
wiley   +1 more source

Mitochondrial oxidative stress and epilepsy in SOD2 deficient mice: Attenuation by a lipophilic metalloporphyrin

open access: yesNeurobiology of Disease, 2012
Epileptic seizures are a common feature associated with inherited mitochondrial diseases. This study investigated the role of mitochondrial oxidative stress in epilepsy resulting from mitochondrial dysfunction using cross-bred mutant mice lacking ...
Li-Ping Liang   +5 more
doaj   +1 more source

Metalloporphyrin-incorporated diphosphine ligands for metal ion-binding [PDF]

open access: yes, 2014
Poster: no. P48Diphosphine ligands have been widely used in organometallic chemistry and catalysis.1 By incorporation of functional units such as metallomacrocycles, the resulting functionalized diphosphines could exhibit unusual properties or binding ...
Che, CM   +4 more
core  

Ring-opening copolymerization (ROCOP): synthesis and properties of polyesters and polycarbonates [PDF]

open access: yes, 2015
Controlled routes to prepare polyesters and polycarbonates are of interest due to the widespread application of these materials and the opportunities provided to prepare new copolymers. Furthermore, ring-opening copolymerization may enable new poly(ester–
Brooks, R   +5 more
core   +1 more source

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