Efficient and Durable Photochemical CO2 Reduction by TiO2‐Immobilized Metal Porphyrin Catalysts
A dye‐sensitized TiO2 scaffold bearing IrP and 3d‐metalloporphyrin catalysts (M‐TCPP; M = Fe, Co, Ni, Cu) drives efficient CO2‐to‐CO conversion and H2 evolution. Robust TiO2 immobilization and rapid interfacial electron transfer within the ternary architecture underpin the markedly enhanced activities relative to the mixed homogeneous systems.
Hyeongu Kang +7 more
wiley +1 more source
X-ray Structure and Properties of the Ferrous Octaethylporphyrin Nitroxyl Complex [PDF]
The preparation and characterization of the iron octaethylporphyrin nitroxyl ion, [Fe(OEP)(NO)−], is reported. The complex was synthesized by the one-electron reduction of Fe(OEP)(NO) using anthracenide as the reducing agent. The compound was isolated as
Kundakarla, Nagabhushanam +3 more
core +3 more sources
Influence of the Nature of Porphyrin and Extraligand on the Stability of Zinc Extracomplexes
The mutual influence of ligands within the structure of Zn-porphyrins on the thermodynamic stability of the latter was investigated.
Oleg A. Golubchikov +4 more
doaj +1 more source
Ab initio electronic structure calculations of solid, solution-processed metallotetrabenzoporphyrins
An ab initio study of the electronic structures of solid metallotetrabenzoporphyrins (MTBPs) utilized in organic transistors and photovoltaics is presented.
Bradley C. J. +3 more
core +1 more source
Metal-Organic Covalent Network Chemical Vapor Deposition for Gas Separation [PDF]
The chemical vapor deposition (CVD) polymerization of metalloporphyrin building units is demonstrated to provide an easily up-scalable one-step method toward the deposition of a new class of dense and defect-free metal–organic covalent network (MOCN ...
Abetz +40 more
core +1 more source
Immobilization of metalloporphyrin on functionalized nanoporous silica [PDF]
SBA-15 nanoporous silica were prepared cooperation assembly of tetraethylorthosilicate precursor in the presence of poly (ethylene glycol)–block- poly (propylene glycol)–block- poly (ethylene glycol) copolymer surfactant and functionalized with (3 ...
Bakar, Mohd. Bakri +2 more
core
Chiral separation by enantioselective liquid–liquid extraction [PDF]
The literature on enantioselective liquid–liquid extraction (ELLE) spans more than half a century of research. Nonetheless, a comprehensive overview has not appeared during the past few decades.
Feringa, Ben L., +5 more
core +3 more sources
Clinically Important Features of Porphyrin and Heme Metabolism and the Porphyrias
Heme, like chlorophyll, is a primordial molecule and is one of the fundamental pigments of life. Disorders of normal heme synthesis may cause human diseases, including certain anemias (X-linked sideroblastic anemias) and porphyrias.
Siddesh Besur +3 more
doaj +1 more source
Antimicrobial properties of chlorophyll and hemin incorporated into the polymeric matrix of poly-N-vinylpyrrolidone [PDF]
The increase in the number of antibiotic-resistant strains of microorganisms is becoming more widespread. Metalloporphyrins are promising and modern antimicrobial agents.
Gruznov D.V. +5 more
doaj +1 more source
Supramolecular systems and their connection with metal–organic structures
Supramolecular structures with specific applications are a pillar in several areas of science. Thus, from a contemporary point of view, there are several reasons to embrace a systematic order of the supramolecular concept itself.
Rodrigo Cué-Sampedro +1 more
doaj +1 more source

