Results 81 to 90 of about 6,458 (220)
MODIFICATION OF WATER POLYMER COMPOSITIONS FOR ELECTRODEPOSITION BY METALLOPORPHYRINS
It is known that coatings produced by electrodeposition, cured at high temperatures (180ºC and above).The aim of this study is reducing the energy intensity of production of polymer coatings, improving physical, mechanical properties of the polymer ...
G. N. Bespalova +5 more
doaj +1 more source
Monoclonal antibodies against Pd‐coproporphyrin I have been obtained. The antibody specificity for free as well as for conjugated Pd‐coproporphyrin I is characterized. Affinity constants are estimated for 3 monoclonal antibodies effectively interacting with free Pd‐coproporphyrin I.
Savitsky, Alexander P. +3 more
openaire +2 more sources
Sunlight‐activated hemoglobin (Hb) functions as a robust natural biocatalyst that promotes the degradation of edible oils through a dual, synergistic pathway. Photo‐excitation of Hb triggers simultaneous energy transfer, generating singlet oxygen (1O2) and electron transfer, forming highly reactive ferryl (HbFe(IV)═O) species.
Mahdi Hajimohammadi +4 more
wiley +1 more source
π-π Aggregation in metalloporphyrins: Causative factors
The strength of aggregation in PdII, NiII, Zn II, and CdII metalloporphyrins is shown by n.m.r. spectroscopy to depend upon interaction of the metal ion with the porphyrin π-system; within a selected series of 2,4-disbustituted deuteroporphyrin-IX ...
Abraham, Raymond J. +3 more
core +1 more source
Mass spectrometry of metalloporhyrins. 1. Mass spectra of octaethylporphines cobalt, nickel, copper
Mass spectra of octaethylporphyrines of cobalt, nickel, copper with electron ionization were obtained. Molecular ions with isotope peaks and the peaks formed by separation hydrogen atoms from porhyrins core have maximum intensity.
A. A. Perov +3 more
doaj
Modular Metalloprotein Nanowires With Semiconductor‐Scale Conductivity and Tunable Redox Behavior
Conductive protein nanowires are built by aligning three different metalloproteins along an ultrastable filament scaffold. The resulting micrometer‐length nanowires reach conductivities of 1.75 S cm−1. Redox behavior is set by the metalloprotein chosen, while conductivity is governed by the spacing the scaffold imposes, making both independently ...
Nga T. Lam +3 more
wiley +1 more source
Influence of the Nature of Porphyrin and Extraligand on the Stability of Zinc Extracomplexes
The mutual influence of ligands within the structure of Zn-porphyrins on the thermodynamic stability of the latter was investigated.
Oleg A. Golubchikov +4 more
doaj +1 more source
This review explores the potential of multimetallic organic framework (MMOF) composites as photocatalysts. It demonstrates the impact of the composite architecture on the photocatalytic performance and existing challenges. The paper highlights heterojunction mechanisms and the role of each partner composites in degradation, CO2 reduction, H2 production,
Youjian Chen +8 more
wiley +1 more source
DFT calculations on porphyrin, corrin, and corphin complexes of cobalt, rhodium, iron, manganese, or nickel, and QM/MM calculations on enzyme models, explore the factors controlling the availably of super‐reduced metal(I) states. True metal(I) states are seen in corrin only for cobalt, in corphin only for nickel, and not at all in porphyrin.
Radu‐Ioan Onija +3 more
wiley +1 more source
Clinically Important Features of Porphyrin and Heme Metabolism and the Porphyrias
Heme, like chlorophyll, is a primordial molecule and is one of the fundamental pigments of life. Disorders of normal heme synthesis may cause human diseases, including certain anemias (X-linked sideroblastic anemias) and porphyrias.
Siddesh Besur +3 more
doaj +1 more source

