Results 61 to 70 of about 6,458 (220)

New insights into signaling pathways of salicylate and metalloporphyrins [PDF]

open access: yes, 2005
Aim of the study: I. Salicylate and heme oxygenase-1: The adhesion molecule P-selectin has been shown to be a major determinant of inflammatory responses.
Blumenthal, Signe Birgitta
core   +1 more source

Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs)

open access: yesIUCrJ, 2018
Heterogeneous catalysts are of great interest in many industrial processes for environmental reasons and, during recent years, a great effort has been devoted to obtain metal–organic frameworks (MOFs) with improved catalytic behaviour. Few supramolecular
Arkaitz Fidalgo-Marijuan   +7 more
doaj   +1 more source

Polyoxometalates in Photocatalytic CO2 Reduction: Multielectron Redox Regulation Across Molecular and Hybrid Architectures

open access: yesEcoEnergy, EarlyView.
This review focuses on multielectron redox regulation across molecular and hybrid architectures for photocatalytic CO2 reduction, covering intrinsic POM photocatalysts, photosensitizer‐assisted assemblies, POM–metal–organic complexes, and POM‐integrated semiconductors and MOF/COF heterostructures to link structural motifs with charge transport, product
Bonan Li, Xiaowen Ruan, Sai Kishore Ravi
wiley   +1 more source

d‐Orbital Electron Spin Polarization Field Inhibits Photo‐Generated Carrier Recombination for Panel Photoelectrocatalysis

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A solution‐processable sub‐nanocrystal of metal coordinated conjugated reticular oligomer with spin polarization functionality is employed as an active layer in planar photoelectrochemical water splitting. The rapid recombination of photo‐generated carriers remains a critical challenge limiting the photo‐electrocatalytic water splitting performance in ...
Ruijuan Zhang   +6 more
wiley   +1 more source

Synthesis, characterisation and magnetic behaviour of ionic metalloporphyrins: metal-tetrakis(N-octyl-4-pyridinium)-porphyrins with tetrabromoferrate(III) anions [PDF]

open access: yes, 2013
A series of magnetic, ionic-substituted tetrapyridyl metalloporphyrins, [tetrakis(N-octyl-4-pyridinium)-metal-porphyrin][tetrabromoferrate(III)] 4 (metal=iron, cobalt, manganese, copper or zinc), have been synthesised.
Zhou, Qing   +9 more
core  

Fluorescence Behavior of Water‐Soluble Porphyrins Immobilized on LTA Zeolite and Its Chlorogenic Acid Polyphenol Sensing in Coffee Wastewater

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
During coffee bean and cherry washing, contaminants are released into water, making this process a major source of water pollution. Chlorogenic acid can be efficiently detected using hybrid zeolite–porphyrin materials by measuring fluorescence quenching, achieving detection limits lower than current regulatory thresholds.
João Otávio Donizette Malafatti   +10 more
wiley   +1 more source

CO2‐to‐CO Electrochemical Conversion With an Fe(I) Porphyrin Complex in Water

open access: yesAngewandte Chemie, Volume 138, Issue 40, 28 September 2026.
Using in situ UV–vis/IR spectroelectrochemistry, we track CO2 reduction by a water‐soluble iron porphyrin. Rather than the usual [Fe0] intermediate in organic solvents, CO2 binds the electrogenerated [FeI] species and undergoes reductive C─O cleavage to stable [FeII‐CO]. This previously unexplored reaction pathway is facilitated by an aqueous H‐bonding
Andrew Howe   +5 more
wiley   +2 more sources

Fabrication of flexible composite electrodes and their application in flexible supercapacitors for wearable electronic devices

open access: yesFlexMat, EarlyView.
This review surveys current progress in composite flexible electrodes for flexible supercapacitors, emphasizing how structural engineering and material synergy enhance both mechanical compliance and electrochemical performance. It discusses fabrication strategies, emerging application scenarios, and ongoing challenges, offering updated insights that ...
Weikang Wang   +9 more
wiley   +1 more source

Ligand Binding Studies of Metalloporphyrins

open access: yes, 2014
Porphyrin molecules are found in numerous proteins important in biological processes. The porphyrin used in this project, tetraphenylprophryin (TPP), is a model compound used to study the iron-containing porphyrin found in hemoglobin responsible for ...
Sallman, Emily
core   +1 more source

Biosensors for Food Safety and Adulteration Monitoring: Applications, Smart Packaging Integration, and Pathways to Intelligent, Field‐Deployable Detection Systems

open access: yesFood Safety and Health, EarlyView.
Biosensors enable rapid, sensitive, and portable detection of pathogens, contaminants, allergens, and food adulteration. Integration with smart packaging, smartphones, IoT, and machine learning supports real‐time monitoring and intelligent decision‐making, whereas microfluidics, biodegradable materials, explainable AI, and blockchain offer pathways ...
Mohima Akther Any   +7 more
wiley   +1 more source

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