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Metal Preferences and Metallation [PDF]
The metal binding preferences of most metalloproteins do not match their metal requirements. Thus, metallation of an estimated 30% of metalloenzymes is aided by metal delivery systems, with ∼ 25% acquiring preassembled metal cofactors. The remaining ∼ 70% are presumed to compete for metals from buffered metal pools.
Foster, Andrew W.+2 more
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Metal–metal bonded compounds and metal clusters [PDF]
Preface.
Falvello, Larry R., Murillo, Carlos A.
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Metal to Orthogonal Metal Transition* [PDF]
Orthogonal metal is a new quantum metallic state that conducts electricity but acquires no Fermi surface (FS) or quasiparticles, and hence orthogonal to the established paradigm of Landau’s Fermi-liquid (FL). Such a state may hold the key of understanding the perplexing experimental observations of quantum metals that are beyond FL ...
Chen, Chuang+3 more
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Metals have always fascinated humans, for reasons ranging from practical through aesthetic to philosophical considerations. More than for other materials, this fascination can be seen to cover both the production of metals and their use. In most societies ceramics play a much more fundamental and ubiquitous role than metals, but it is only the high-end
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Intermetallic Compounds Edited by J. H. Westbrook. (Wiley Series on the Science and Technology of Materials.) Pp. xvii + 663. (New York and London: John Wiley and Sons, 1967.) 235s.
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This chapter deals with the electronic structure of metal-metal bonds in molecular systems, a diverse topic that now spans almost the entire periodic table. The field is most often associated with strong multiple bonds such as the iconic quadruple bond in [Re2Cl8]2-, and the recently discovered ultra-short Cr-Cr quintuple bonds provide a remarkable ...
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