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Cyclization Strategies in Carbonyl–Olefin Metathesis: An Up-to-Date Review
MoleculesThe metathesis reaction between carbonyl compounds and olefins has emerged as a potent strategy for facilitating swift functional group interconversion and the construction of intricate organic structures through the creation of novel carbon–carbon ...
Xiaoke Zhang
doaj +1 more source
Reversibly Photoswitchable Catalysts for Olefin Metathesis Reactions
, 2021 Azobenzene-bearing photoswitchable ruthenium catalysts were developed for olefin metathesis reactions. These catalysts exhibited an on–off switching ability in ring-closing metathesis depending on UV irradiation (>99% conversion without UV vs
Junseong Lee (1510414) +11 more
core +1 more source
, 2016 Ring-closing metathesis (RCM) has emerged as a powerful synthetic tool. Depending on the unsaturated functional groups involved, ring-closing-metathesis reactions are classified into three categories: diene ring-closing metathesis, enyne ring-closing ...
D. Lee, V. R. Sabbasani
core +1 more source
, 2023 The development of highly efficient enantioselective olefin metathesis catalysts is a significant challenge. Using optically pure chiral cyclic (alkyl)(amino)carbene (ChiCAAC) ligands combined with preliminary mechanistic insights and density functional ...
Thomas Vives (3711946) +11 more
core +1 more source
Metathesis access to monocyclic iminocyclitol-based therapeutic agents
Beilstein Journal of Organic Chemistry, 2011 By focusing on recent developments on natural and non-natural azasugars (iminocyclitols), this review bolsters the case for the role of olefin metathesis reactions (RCM, CM) as key transformations in the multistep syntheses of pyrrolidine-, piperidine ...
Ileana Dragutan +5 more
doaj +1 more source
Microwave-Assisted Olefin Metathesis
, 2008 International audienceThe beneficial effect of microwave irradiation instead of classical thermal conditions in olefin metathesis reactions is illustrated through a series of literature examples of ring-closing- metathesis and cross-metathesis ...
Coquerel, Yoann +3 more
core +1 more source
New Facile Synthesis of Adamantyl Isothiocyanates
SynOpen, 2017 A series of adamantyl isothiocyanates containing different substituents in the nodal positions of adamantane or spacers between the adamantane and isothiocyanate group have been synthesised by using the reaction of the corresponding adamantyl amines with
Vladimir Burmistrov +2 more
doaj +1 more source
Highly Active Water-Soluble Olefin Metathesis Catalyst
, 2016 A novel water-soluble ruthenium olefin metathesis catalyst supported by a poly(ethylene glycol) conjugated saturated 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ligand is reported.
Soon Hyeok Hong (1373670) +1 more
core +1 more source
Unsaturated Fatty Acid Esters Metathesis Catalyzed by Silica Supported WMe5 [PDF]
, 2016 Metathesis of unsaturated fatty acid esters (FAEs) by silica supported multifunctional W-based catalyst is disclosed. This transformation represents a novel route towards unsaturated di-esters.
Talbi, Karima +3 more
core +1 more source
, 2010 Highly functionalized cage compounds have been prepared via cross-metathesis (CM) using Grubbs modified N-tolyol catalyst 7. A strategic utilization of photo-thermal metathesis and catalytic metathesis sequence for the synthesis of functionalized caged ...
SEEMA, V +11 more
core +2 more sources