Results 111 to 120 of about 35,734 (288)

Bidirectional cross metathesis and ring-closing metathesis/ring opening of a C2-symmetric building block: a strategy for the synthesis of decanolide natural products

open access: yesBeilstein Journal of Organic Chemistry, 2013
Starting from the conveniently available ex-chiral pool building block (R,R)-hexa-1,5-diene-3,4-diol, the ten-membered ring lactones stagonolide E and curvulide A were synthesized using a bidirectional olefin-metathesis functionalization of the terminal ...
Bernd Schmidt, Oliver Kunz
doaj   +1 more source

Metal-Incorporated Mesoporous Silicates: Tunable Catalytic Properties and Applications

open access: yesMolecules, 2018
A relatively new class of three-dimensional ordered mesoporous silicates, KIT-6, incorporated with Earth-abundant metals such as Zr, Nb, and W (termed as M-KIT-6), show remarkable tunability of acidity and metal dispersion depending on the metal content,
Anand Ramanathan, Bala Subramaniam
doaj   +1 more source

Catalytic Carbonyl-Olefin Metathesis of Aliphatic Ketones: Iron(III) HomoDimers as Lewis Acidic Superelectrophiles

open access: yes, 2018
Catalytic carbonyl-olefin metathesis reactions have recently been developed as a powerful tool for carbon-carbon bondformation. However, currently available synthetic protocols rely exclusively on aryl ketone substrates while the corresponding aliphatic ...
Paul M., Zimmerman   +8 more
core   +1 more source

Metátese na linguagem infantil: “porfessora” é bom, “professora” é melhor

open access: yesSaber & Educar, 2013
A leitura e a escrita são ensinadas a crianças cuja linguagem oral contém ainda, muitas vezes, desvios subtis. A metátese é um desses desvios, consistindo na troca da ordem de fonemas na palavra, tal como acontece em “corcodilo”.
Rosa M. Lima
doaj  

Nitro-Grela-type complexes containing iodides – robust and selective catalysts for olefin metathesis under challenging conditions

open access: yesBeilstein Journal of Organic Chemistry, 2015
Iodide-containing nitro-Grela-type catalysts have been synthesized and applied to ring closing metathesis (RCM) and cross metathesis (CM) reactions. These new catalysts have exhibited improved efficiency in the transformation of sterically, non-demanding
Andrzej Tracz   +3 more
doaj   +1 more source

Protonation of Propene on Silica-Grafted Hydroxylated Molybdenum and Tungsten Oxide Metathesis Catalysts: A DFT Study [PDF]

open access: yesIranian Journal of Chemistry & Chemical Engineering, 2019
Theoretical assessment of the protonation reaction in the activation of propene on hydroxylated Mo(VI) and W(VI) metathesis catalysts is presented in this paper using the density functional theory calculations and five support clusters varying from ...
Mohammad Ghashghaee, Mehdi Ghambarian
doaj  

The synthesis and properties of some well-defined fluorinated polymers [PDF]

open access: yes, 1996
This thesis describes studies directed to the ring opening metathesis polymerisation (ROMP) of some fluorinated compounds using a range of well-defined initiators.
Towns, Richard Mark
core  

Late‐Stage Functionalization of Peptides on the Solid Phase

open access: yesAngewandte Chemie International Edition, EarlyView.
Peptide modifications are essential to control pharmacodynamic and pharmacokinetic properties of peptide drugs. Consequently, strategies that allow for efficient and rapid incorporation of non‐canonical modifications into peptides in parallel formats are highly sought after.
Marius Werner   +2 more
wiley   +1 more source

Sobre el sufijo occidental -ika y otras cuestiones de toponimia vasca [PDF]

open access: yesFontes Linguae Vasconum, 2011
En este trabajo analizo una serie de topónimos vascos occidentales con final en –ika (Gernika, Sondika...) a los que hasta ahora no se les había dado una explicación de conjunto, e intento relacionarlos con otros con final en –eka y –aka.
Patxi Salaberri Zaratiegi
doaj  

Phonological Processes in Kurdish Dialect of Sonqor Kolyaee [PDF]

open access: yesمطالعات زبان‌‌ها و گویش‌های غرب ایران, 2018
The present article deals with the description and explanation of some of the most important productive phonological processes in Sonqor kolyaee Kurdish dialect. Deletion, Insertion, Lenition, Metathesis, Compensatory Lengthening, Insertion and Convert /
salman khanjari   +1 more
doaj  

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