Synthesis of Substituted Tetrafluorocyclobutenes and Their Ring-Opening Metathesis/Ring-Closing Metathesis to Dihydrofurans Bearing a Tetrafluoroethylene Unit. [PDF]
ACS OmegaKučnirová K +3 more
europepmc +1 more source
Gold(I) Phosphine/Phosphido‐Borohydride Complexes
European Journal of Inorganic Chemistry, EarlyView.Synthesis, structure, and electrochemical characteristics of a homologous series of gold(I) complexes featuring phosphine and phosphido–borohydride ligands. A homologous series of linear, mononuclear gold(I) phosphine/phosphido‐borohydride complexes, encompassing [Au(PR3)2]+ 1, [Au(PR3)(PR2BH3)] 2 and [Au(PR2BH3)2]– 3 (R = tBu, Ad), has been prepared ...
Matthew J. G. Sinclair +3 more
wiley +1 more source
Olefin Metathesis Catalyzed by a Latent Ruthenathiete Complex. [PDF]
OrganometallicsPabarue AB +4 more
europepmc +1 more source
Hydrosilane Chemistry: From Historic First Steps to Modern Applications
European Journal of Inorganic Chemistry, EarlyView.This review covers the history of hydrosilanes, from their initial discovery to their modern applications. It highlights the pioneering work of chemists like Alfred Stock and Franz Fehér and discusses the modern ways of synthesis and use of hydrosilanes in printed electronics.
Uwe Böhme, Maik Gerwig
wiley +1 more source
Conversion of trifluoromethyls into esters along with polyether upcycling <i>via</i> cation-transfer-catalyzed C-O/C-F metathesis. [PDF]
Chem SciLi Z, Shi X, Zhang D, Wu Q.
europepmc +1 more source
A Hoveyda–Grubbs‐Type Olefin Metathesis Catalyst Bearing a Fluorinated Unsymmetrical NHC Ligand
European Journal of Inorganic Chemistry, EarlyView.A fluorinated unsymmetrical NHC ruthenium complex was synthesised and employed as a catalyst for olefin metathesis reactions. The modification of the steric and electronic properties of the NHC ligand through the introduction of fluorine substituents results in improved activity but lower selectivity compared to the analogous non‐fluorinated NHC ...
Rubina Troiano +3 more
wiley +1 more source
Toward vanadium-mediated alkyne metathesis. [PDF]
Chem SciHernandez S +4 more
europepmc +1 more source
Main Group Metals in Redox Catalysis
European Journal of Inorganic Chemistry, EarlyView.Main group metal redox catalysis is emerging as a credible alternative to transition metal chemistry. Elements from groups 13 to 15 now enable diverse catalytic manifolds, driven by ligand design and control of electronic structure. This review highlights recent advances, key design principles, and remaining challenges, positioning main group metals as
Olympia Mouriki +2 more
wiley +1 more source
Kinetic resolution of racemic planar-chiral vinylcymantrenes by molybdenum-catalyzed asymmetric metathesis dimerization. [PDF]
Beilstein J Org ChemImazu H, Izu H, Ohki Y, Ogasawara M.
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Metathesis of alkali metal amidoforane and FeCl3 in THF
, 2012 Metathesis of alkali metal amidoforane and FeCl3 in ...
张涛 +8 more
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